Bone‐Induced Nanocomposite Coating with a “Sandwich” Structure

Abstract Infection‐induced bone defects present significant challenges in clinical bone regeneration, frequently leading to poor bone induction, recurring infections, and complications such as pain and chronic inflammation. This study introduces a novel Ti/Lignin‐Ag@PLL composite coating with a “san...

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Main Authors: Yushuang Guan, Guoming Zou, Henigul osman, Dong Zhang, Tianyou Zhou, Wenguo Cui, Yingbo Wang
Format: Article
Language:English
Published: Wiley-VCH 2024-12-01
Series:Advanced Materials Interfaces
Subjects:
Online Access:https://doi.org/10.1002/admi.202400164
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author Yushuang Guan
Guoming Zou
Henigul osman
Dong Zhang
Tianyou Zhou
Wenguo Cui
Yingbo Wang
author_facet Yushuang Guan
Guoming Zou
Henigul osman
Dong Zhang
Tianyou Zhou
Wenguo Cui
Yingbo Wang
author_sort Yushuang Guan
collection DOAJ
description Abstract Infection‐induced bone defects present significant challenges in clinical bone regeneration, frequently leading to poor bone induction, recurring infections, and complications such as pain and chronic inflammation. This study introduces a novel Ti/Lignin‐Ag@PLL composite coating with a “sandwich” structure, designed to integrate pro‐adhesion, photothermal‐photodynamic antibacterial, and osteogenic properties. The Ti/Lignin‐Ag@PLL composite coating is fabricated using self‐assembly technology, in which Ag+ is reduced to silver nanoparticles (Ag‐NPs) by lignin, followed by Polylysine (PLL) grafting. Photothermal conversion efficiency is evaluated under near‐infrared (NIR) laser irradiation, while antibacterial activity is tested against E. coli and S. aureus. Biocompatibility is also assessed using vascular endothelial cells (VECs) and osteoblasts (OBs). The results indicate that the Ti/Lignin‐Ag@PLL coating demonstrates a 31% photothermal conversion efficiency and nearly 100% antibacterial efficacy against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) under NIR irradiation for 10 min. Without irradiation, the antibacterial rates are 85% and 94%, respectively, after 24 h. Additionally, the coating significantly promotes cell adhesion, proliferation, and osteogenesis, as evidenced by the upregulation of Runx2 and Collagen I. This study uniquely contributes to the development of a multifunctional composite coating that effectively combines robust antibacterial properties with enhanced osteogenic potential, offering a promising solution for bone tissue repair and infection prevention.
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spelling doaj-art-95dbffd4db554478a8d6cc0140352dd52025-08-20T02:32:12ZengWiley-VCHAdvanced Materials Interfaces2196-73502024-12-011136n/an/a10.1002/admi.202400164Bone‐Induced Nanocomposite Coating with a “Sandwich” StructureYushuang Guan0Guoming Zou1Henigul osman2Dong Zhang3Tianyou Zhou4Wenguo Cui5Yingbo Wang6College of Chemical Engineering Xinjiang Normal University 102 Xinyi Road Urumqi 830054 P. R. ChinaCollege of Chemical Engineering Xinjiang Normal University 102 Xinyi Road Urumqi 830054 P. R. ChinaCollege of Chemical Engineering Xinjiang Normal University 102 Xinyi Road Urumqi 830054 P. R. ChinaCollege of Chemical Engineering Xinjiang Normal University 102 Xinyi Road Urumqi 830054 P. R. ChinaCollege of Control Engineering Xinjiang Institute of Engineering 1350 Aidinghu Road Urumqi 830023 P. R. ChinaDepartment of Orthopaedics, Shanghai Institute of Traumatology and Orthopaedics Ruijin Hospital Shanghai Jiao Tong University School of Medicine 197 Ruijin 2nd Road Shanghai 200025 P. R. ChinaCollege of Chemical Engineering Xinjiang Normal University 102 Xinyi Road Urumqi 830054 P. R. ChinaAbstract Infection‐induced bone defects present significant challenges in clinical bone regeneration, frequently leading to poor bone induction, recurring infections, and complications such as pain and chronic inflammation. This study introduces a novel Ti/Lignin‐Ag@PLL composite coating with a “sandwich” structure, designed to integrate pro‐adhesion, photothermal‐photodynamic antibacterial, and osteogenic properties. The Ti/Lignin‐Ag@PLL composite coating is fabricated using self‐assembly technology, in which Ag+ is reduced to silver nanoparticles (Ag‐NPs) by lignin, followed by Polylysine (PLL) grafting. Photothermal conversion efficiency is evaluated under near‐infrared (NIR) laser irradiation, while antibacterial activity is tested against E. coli and S. aureus. Biocompatibility is also assessed using vascular endothelial cells (VECs) and osteoblasts (OBs). The results indicate that the Ti/Lignin‐Ag@PLL coating demonstrates a 31% photothermal conversion efficiency and nearly 100% antibacterial efficacy against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus) under NIR irradiation for 10 min. Without irradiation, the antibacterial rates are 85% and 94%, respectively, after 24 h. Additionally, the coating significantly promotes cell adhesion, proliferation, and osteogenesis, as evidenced by the upregulation of Runx2 and Collagen I. This study uniquely contributes to the development of a multifunctional composite coating that effectively combines robust antibacterial properties with enhanced osteogenic potential, offering a promising solution for bone tissue repair and infection prevention.https://doi.org/10.1002/admi.202400164adhesionbone inductioncomposite coatingphotothermal‐photodynamic antibacterialtitanium metal
spellingShingle Yushuang Guan
Guoming Zou
Henigul osman
Dong Zhang
Tianyou Zhou
Wenguo Cui
Yingbo Wang
Bone‐Induced Nanocomposite Coating with a “Sandwich” Structure
Advanced Materials Interfaces
adhesion
bone induction
composite coating
photothermal‐photodynamic antibacterial
titanium metal
title Bone‐Induced Nanocomposite Coating with a “Sandwich” Structure
title_full Bone‐Induced Nanocomposite Coating with a “Sandwich” Structure
title_fullStr Bone‐Induced Nanocomposite Coating with a “Sandwich” Structure
title_full_unstemmed Bone‐Induced Nanocomposite Coating with a “Sandwich” Structure
title_short Bone‐Induced Nanocomposite Coating with a “Sandwich” Structure
title_sort bone induced nanocomposite coating with a sandwich structure
topic adhesion
bone induction
composite coating
photothermal‐photodynamic antibacterial
titanium metal
url https://doi.org/10.1002/admi.202400164
work_keys_str_mv AT yushuangguan boneinducednanocompositecoatingwithasandwichstructure
AT guomingzou boneinducednanocompositecoatingwithasandwichstructure
AT henigulosman boneinducednanocompositecoatingwithasandwichstructure
AT dongzhang boneinducednanocompositecoatingwithasandwichstructure
AT tianyouzhou boneinducednanocompositecoatingwithasandwichstructure
AT wenguocui boneinducednanocompositecoatingwithasandwichstructure
AT yingbowang boneinducednanocompositecoatingwithasandwichstructure