Thermodynamic Assessment of High Entropy (Fe-Mn) Binary Alloy System Using Calphad Method

This paper reports thermodynamic calculations and predictions of Meta stable binary alloy Fe-Mn system using Calphad approach. Thermodynamic analysis involves calculation of phase diagram, Gibbs energy of mixing, excess Gibbs energies, thermodynamic molar activities, and coefficient of activities,...

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Main Authors: Waseem Ullah shah, A.G MAMALIS mamalis, HAI QING YIN YIN, Dil Faraz Khan
Format: Article
Language:English
Published: Elsevier 2022-03-01
Series:Kuwait Journal of Science
Online Access:https://journalskuwait.org/kjs/index.php/KJS/article/view/11303
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author Waseem Ullah shah
A.G MAMALIS mamalis
HAI QING YIN YIN
Dil Faraz Khan
author_facet Waseem Ullah shah
A.G MAMALIS mamalis
HAI QING YIN YIN
Dil Faraz Khan
author_sort Waseem Ullah shah
collection DOAJ
description This paper reports thermodynamic calculations and predictions of Meta stable binary alloy Fe-Mn system using Calphad approach. Thermodynamic analysis involves calculation of phase diagram, Gibbs energy of mixing, excess Gibbs energies, thermodynamic molar activities, and coefficient of activities, partial and integral values of enthalpy for Co-Fe alloy system at three elevated temperatures 1200K, 1225K, and 1250K. The alloy reports positive deviation from vegard,s law and corresponding good negative deviation from Rout’s law ideal Gibbs curve. Predicted by results that the ferromagnetic state of Mn-Fe alloy is the most stable and ground state. Investigated results reports many magnetic based moments of atoms. For Mn and Fe system, their measured phase equilibria shows activity curve data for solid in almost ideal behavior, but somehow small positive deviation from ideality
format Article
id doaj-art-95b681bdc35e42a89d680cd9f2deee4b
institution OA Journals
issn 2307-4108
2307-4116
language English
publishDate 2022-03-01
publisher Elsevier
record_format Article
series Kuwait Journal of Science
spelling doaj-art-95b681bdc35e42a89d680cd9f2deee4b2025-08-20T02:30:32ZengElsevierKuwait Journal of Science2307-41082307-41162022-03-0149210.48129/kjs.11303Thermodynamic Assessment of High Entropy (Fe-Mn) Binary Alloy System Using Calphad MethodWaseem Ullah shah0A.G MAMALIS mamalis1HAI QING YIN YIN2Dil Faraz Khan3universiry of science and technology bannu,28100,pakistannanotechnology and engineering centeruniversity of science and technology beijing chinaDept. of Physics, University of Science and Technology Bannu, 28100, KPK, Pakistan This paper reports thermodynamic calculations and predictions of Meta stable binary alloy Fe-Mn system using Calphad approach. Thermodynamic analysis involves calculation of phase diagram, Gibbs energy of mixing, excess Gibbs energies, thermodynamic molar activities, and coefficient of activities, partial and integral values of enthalpy for Co-Fe alloy system at three elevated temperatures 1200K, 1225K, and 1250K. The alloy reports positive deviation from vegard,s law and corresponding good negative deviation from Rout’s law ideal Gibbs curve. Predicted by results that the ferromagnetic state of Mn-Fe alloy is the most stable and ground state. Investigated results reports many magnetic based moments of atoms. For Mn and Fe system, their measured phase equilibria shows activity curve data for solid in almost ideal behavior, but somehow small positive deviation from ideality https://journalskuwait.org/kjs/index.php/KJS/article/view/11303
spellingShingle Waseem Ullah shah
A.G MAMALIS mamalis
HAI QING YIN YIN
Dil Faraz Khan
Thermodynamic Assessment of High Entropy (Fe-Mn) Binary Alloy System Using Calphad Method
Kuwait Journal of Science
title Thermodynamic Assessment of High Entropy (Fe-Mn) Binary Alloy System Using Calphad Method
title_full Thermodynamic Assessment of High Entropy (Fe-Mn) Binary Alloy System Using Calphad Method
title_fullStr Thermodynamic Assessment of High Entropy (Fe-Mn) Binary Alloy System Using Calphad Method
title_full_unstemmed Thermodynamic Assessment of High Entropy (Fe-Mn) Binary Alloy System Using Calphad Method
title_short Thermodynamic Assessment of High Entropy (Fe-Mn) Binary Alloy System Using Calphad Method
title_sort thermodynamic assessment of high entropy fe mn binary alloy system using calphad method
url https://journalskuwait.org/kjs/index.php/KJS/article/view/11303
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AT agmamalismamalis thermodynamicassessmentofhighentropyfemnbinaryalloysystemusingcalphadmethod
AT haiqingyinyin thermodynamicassessmentofhighentropyfemnbinaryalloysystemusingcalphadmethod
AT dilfarazkhan thermodynamicassessmentofhighentropyfemnbinaryalloysystemusingcalphadmethod