Synthesis and Spectroscopic Studies of some Divalent Metall Ion Complexes of 3-(4-hydroxyphenyl)-2-(3-(4-nitrobenzoyl) thioureido) propanoic acid
3-(4-hydroxyphenyl)-2-(3-(4-nitrobenzoyl) thioureido) propanoic acid (HNP) a new ligand was synthesized by reaction of Tyrosine with (4-Nitrobenzoyl isothiocyanate) by using acetone as a solvent. The prepared ligand (HNP) has been characterized by elemental analysis (CHNS), infrared (FT-IR), electro...
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University of Baghdad, College of Science for Women
2017-09-01
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| Series: | مجلة بغداد للعلوم |
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| Online Access: | http://www.csw-journal.org/show-articles.php?id_article=1997 |
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| author | Basima M. Sarhan Ban Z. Neema |
| author_facet | Basima M. Sarhan Ban Z. Neema |
| author_sort | Basima M. Sarhan |
| collection | DOAJ |
| description | 3-(4-hydroxyphenyl)-2-(3-(4-nitrobenzoyl) thioureido) propanoic acid (HNP) a new ligand was synthesized by reaction of Tyrosine with (4-Nitrobenzoyl isothiocyanate) by using acetone as a solvent. The prepared ligand (HNP) has been characterized by elemental analysis (CHNS), infrared (FT-IR), electronic spectral (Ultraviolet visible) and(1H,13C-Nuclear Magnetic Resonance) spectra. Some Divalent metal ion complexes of (HNP) were prepared and spectroscopic studies by Fourier transform infrared (FTIR), electronic spectral(UV-Vis), molar conductance, magnetic susceptibility and atomic absorption. The results measured showed the formula of six prepared complexes were [M (HNP)2] (M+2 = Manganese, Cobalt, Nickel, Znic, Cadmium and Mercury),from the obtained data tetrahedral structure suggested for all complexes, except Copper complex has a square planer geometry |
| format | Article |
| id | doaj-art-9584f96f16164d569abd4d146e9bfcaf |
| institution | Kabale University |
| issn | 2078-8665 2411-7986 |
| language | English |
| publishDate | 2017-09-01 |
| publisher | University of Baghdad, College of Science for Women |
| record_format | Article |
| series | مجلة بغداد للعلوم |
| spelling | doaj-art-9584f96f16164d569abd4d146e9bfcaf2025-08-20T03:57:04ZengUniversity of Baghdad, College of Science for Womenمجلة بغداد للعلوم2078-86652411-79862017-09-0114358859610.21123/bsj.2017.14.3.0588Synthesis and Spectroscopic Studies of some Divalent Metall Ion Complexes of 3-(4-hydroxyphenyl)-2-(3-(4-nitrobenzoyl) thioureido) propanoic acidBasima M. Sarhan 0Ban Z. Neema 1Department of chemistry, Collage of Education for Pure Sciences\ Ibn-AL-Hatham, University of Baghdad, Baghdad, IraqDepartment of chemistry, Collage of Education for Pure Sciences\ Ibn-AL-Hatham, University of Baghdad, Baghdad, Iraq3-(4-hydroxyphenyl)-2-(3-(4-nitrobenzoyl) thioureido) propanoic acid (HNP) a new ligand was synthesized by reaction of Tyrosine with (4-Nitrobenzoyl isothiocyanate) by using acetone as a solvent. The prepared ligand (HNP) has been characterized by elemental analysis (CHNS), infrared (FT-IR), electronic spectral (Ultraviolet visible) and(1H,13C-Nuclear Magnetic Resonance) spectra. Some Divalent metal ion complexes of (HNP) were prepared and spectroscopic studies by Fourier transform infrared (FTIR), electronic spectral(UV-Vis), molar conductance, magnetic susceptibility and atomic absorption. The results measured showed the formula of six prepared complexes were [M (HNP)2] (M+2 = Manganese, Cobalt, Nickel, Znic, Cadmium and Mercury),from the obtained data tetrahedral structure suggested for all complexes, except Copper complex has a square planer geometryhttp://www.csw-journal.org/show-articles.php?id_article=1997TyrosineDivalent Metal Ion4-Nitrobenzoyl isothiocyanate |
| spellingShingle | Basima M. Sarhan Ban Z. Neema Synthesis and Spectroscopic Studies of some Divalent Metall Ion Complexes of 3-(4-hydroxyphenyl)-2-(3-(4-nitrobenzoyl) thioureido) propanoic acid مجلة بغداد للعلوم Tyrosine Divalent Metal Ion 4-Nitrobenzoyl isothiocyanate |
| title | Synthesis and Spectroscopic Studies of some Divalent Metall Ion Complexes of 3-(4-hydroxyphenyl)-2-(3-(4-nitrobenzoyl) thioureido) propanoic acid |
| title_full | Synthesis and Spectroscopic Studies of some Divalent Metall Ion Complexes of 3-(4-hydroxyphenyl)-2-(3-(4-nitrobenzoyl) thioureido) propanoic acid |
| title_fullStr | Synthesis and Spectroscopic Studies of some Divalent Metall Ion Complexes of 3-(4-hydroxyphenyl)-2-(3-(4-nitrobenzoyl) thioureido) propanoic acid |
| title_full_unstemmed | Synthesis and Spectroscopic Studies of some Divalent Metall Ion Complexes of 3-(4-hydroxyphenyl)-2-(3-(4-nitrobenzoyl) thioureido) propanoic acid |
| title_short | Synthesis and Spectroscopic Studies of some Divalent Metall Ion Complexes of 3-(4-hydroxyphenyl)-2-(3-(4-nitrobenzoyl) thioureido) propanoic acid |
| title_sort | synthesis and spectroscopic studies of some divalent metall ion complexes of 3 4 hydroxyphenyl 2 3 4 nitrobenzoyl thioureido propanoic acid |
| topic | Tyrosine Divalent Metal Ion 4-Nitrobenzoyl isothiocyanate |
| url | http://www.csw-journal.org/show-articles.php?id_article=1997 |
| work_keys_str_mv | AT basimamsarhan synthesisandspectroscopicstudiesofsomedivalentmetallioncomplexesof34hydroxyphenyl234nitrobenzoylthioureidopropanoicacid AT banzneema synthesisandspectroscopicstudiesofsomedivalentmetallioncomplexesof34hydroxyphenyl234nitrobenzoylthioureidopropanoicacid |