Powder X-ray line diffraction pattern profiling of anatase-quartz binary oxide: A crystallographic investigation
High-crystalline binary oxide of TiO2 and SiO2 was successfully synthesized using a simple, unique method involving titanium isopropoxide, silicon tetraethoxide and isopropyl alcohol (IP). The resulting crystalline preferred oriented powder was analyzed using X-ray diffraction (XRD). Rietveld refine...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Elsevier
2025-07-01
|
| Series: | Next Materials |
| Subjects: | |
| Online Access: | http://www.sciencedirect.com/science/article/pii/S2949822825000899 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1850240082105073664 |
|---|---|
| author | Allah Rakha Aidid Md. Khalid Hossain Shishir Md. Ashikur Rahaman Md. Tarikul Islam Mubashira Mukta Md. Ashraful Alam |
| author_facet | Allah Rakha Aidid Md. Khalid Hossain Shishir Md. Ashikur Rahaman Md. Tarikul Islam Mubashira Mukta Md. Ashraful Alam |
| author_sort | Allah Rakha Aidid |
| collection | DOAJ |
| description | High-crystalline binary oxide of TiO2 and SiO2 was successfully synthesized using a simple, unique method involving titanium isopropoxide, silicon tetraethoxide and isopropyl alcohol (IP). The resulting crystalline preferred oriented powder was analyzed using X-ray diffraction (XRD). Rietveld refinement showed that the titania-silica (TS) crystalline binary oxide consisted of anatase and quartz phases with a composition of 49.40 % crystalline anatase and 50.60 % crystalline quartz. The pure titania-silica binary oxide (TSBO) had detailed lattice parameters: for anatase, α=β=γ=90.0°, a=b=3.7856 Å, c=9.5159 Å, lattice strain of 0.079 %, lattice volume of 136.372 ų and specific surface area of 20.0 m²/g with tetragonal crystal structure. For quartz, the parameters were α= β=90.0°, γ=120.0°, a=b=4.9143 Å, c=5.4059 Å, lattice strain of 0.012 %, lattice volume of 113.063 ų and specific surface area of 12.5 m²/g with hexagonal crystal structure. The most intense diffractions were associated with the (101) plane at 2θ=25.289° for anatase and the (101) plane at 2θ=26.634° for quartz. The synthesized material exhibited peak in UV absorbance at 324.50 nm (0.783 a.u.) caused blue shift explored nano-size contribution and optical band gap of 3.071 eV. The zeta potential for +55.33 to −65.93 mV showed good stability of TSBO. The crystallographic data verified the successful synthesis of pure TSBO contributing to advancements in nanotechnology. |
| format | Article |
| id | doaj-art-95552e6f64644ffa903b948dfe16e54c |
| institution | OA Journals |
| issn | 2949-8228 |
| language | English |
| publishDate | 2025-07-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Next Materials |
| spelling | doaj-art-95552e6f64644ffa903b948dfe16e54c2025-08-20T02:00:56ZengElsevierNext Materials2949-82282025-07-01810057110.1016/j.nxmate.2025.100571Powder X-ray line diffraction pattern profiling of anatase-quartz binary oxide: A crystallographic investigationAllah Rakha Aidid0Md. Khalid Hossain Shishir1Md. Ashikur Rahaman2Md. Tarikul Islam3Mubashira Mukta4Md. Ashraful Alam5Department of Applied Chemistry and Chemical Engineering, Islamic University, Kushtia 7003, BangladeshDepartment of Applied Chemistry and Chemical Engineering, Islamic University, Kushtia 7003, BangladeshDepartment of Applied Chemistry and Chemical Engineering, Islamic University, Kushtia 7003, BangladeshDepartment of Applied Chemistry and Chemical Engineering, Islamic University, Kushtia 7003, BangladeshDepartment of Applied Chemistry and Chemical Engineering, Islamic University, Kushtia 7003, BangladeshInstitute of Glass and Ceramic Research and Testing (IGCRT), Bangladesh Council of Scientific and Industrial Research (BCSIR), Dhaka 1205, Bangladesh; Corresponding author.High-crystalline binary oxide of TiO2 and SiO2 was successfully synthesized using a simple, unique method involving titanium isopropoxide, silicon tetraethoxide and isopropyl alcohol (IP). The resulting crystalline preferred oriented powder was analyzed using X-ray diffraction (XRD). Rietveld refinement showed that the titania-silica (TS) crystalline binary oxide consisted of anatase and quartz phases with a composition of 49.40 % crystalline anatase and 50.60 % crystalline quartz. The pure titania-silica binary oxide (TSBO) had detailed lattice parameters: for anatase, α=β=γ=90.0°, a=b=3.7856 Å, c=9.5159 Å, lattice strain of 0.079 %, lattice volume of 136.372 ų and specific surface area of 20.0 m²/g with tetragonal crystal structure. For quartz, the parameters were α= β=90.0°, γ=120.0°, a=b=4.9143 Å, c=5.4059 Å, lattice strain of 0.012 %, lattice volume of 113.063 ų and specific surface area of 12.5 m²/g with hexagonal crystal structure. The most intense diffractions were associated with the (101) plane at 2θ=25.289° for anatase and the (101) plane at 2θ=26.634° for quartz. The synthesized material exhibited peak in UV absorbance at 324.50 nm (0.783 a.u.) caused blue shift explored nano-size contribution and optical band gap of 3.071 eV. The zeta potential for +55.33 to −65.93 mV showed good stability of TSBO. The crystallographic data verified the successful synthesis of pure TSBO contributing to advancements in nanotechnology.http://www.sciencedirect.com/science/article/pii/S2949822825000899Anatase-QuartzBinary oxideCrystallinityPowder X-rayWPPF method |
| spellingShingle | Allah Rakha Aidid Md. Khalid Hossain Shishir Md. Ashikur Rahaman Md. Tarikul Islam Mubashira Mukta Md. Ashraful Alam Powder X-ray line diffraction pattern profiling of anatase-quartz binary oxide: A crystallographic investigation Next Materials Anatase-Quartz Binary oxide Crystallinity Powder X-ray WPPF method |
| title | Powder X-ray line diffraction pattern profiling of anatase-quartz binary oxide: A crystallographic investigation |
| title_full | Powder X-ray line diffraction pattern profiling of anatase-quartz binary oxide: A crystallographic investigation |
| title_fullStr | Powder X-ray line diffraction pattern profiling of anatase-quartz binary oxide: A crystallographic investigation |
| title_full_unstemmed | Powder X-ray line diffraction pattern profiling of anatase-quartz binary oxide: A crystallographic investigation |
| title_short | Powder X-ray line diffraction pattern profiling of anatase-quartz binary oxide: A crystallographic investigation |
| title_sort | powder x ray line diffraction pattern profiling of anatase quartz binary oxide a crystallographic investigation |
| topic | Anatase-Quartz Binary oxide Crystallinity Powder X-ray WPPF method |
| url | http://www.sciencedirect.com/science/article/pii/S2949822825000899 |
| work_keys_str_mv | AT allahrakhaaidid powderxraylinediffractionpatternprofilingofanatasequartzbinaryoxideacrystallographicinvestigation AT mdkhalidhossainshishir powderxraylinediffractionpatternprofilingofanatasequartzbinaryoxideacrystallographicinvestigation AT mdashikurrahaman powderxraylinediffractionpatternprofilingofanatasequartzbinaryoxideacrystallographicinvestigation AT mdtarikulislam powderxraylinediffractionpatternprofilingofanatasequartzbinaryoxideacrystallographicinvestigation AT mubashiramukta powderxraylinediffractionpatternprofilingofanatasequartzbinaryoxideacrystallographicinvestigation AT mdashrafulalam powderxraylinediffractionpatternprofilingofanatasequartzbinaryoxideacrystallographicinvestigation |