Formation and Optical Properties of Ag Nanoparticles in CaB4O7–Ag2O and CaB4O7–Gd2O3–Ag2O Tetraborate Glasses

Formation of Ag nanoparticles (NPs) in the near-surface layer of CaB4O7–Ag2O and CaB4O7 –Gd2O3–Ag2O glasses by annealing in vacuum or in air is reported. It is concluded that annealing in vacuum does not necessary require the presence of reducing ions. Intensive plasmon absorption bands peaked at 40...

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Main Authors: V.T. Adamiv, Ya.V. Burak, R.V. Gamernyk, R.M. Dutka, I.M. Teslyuk
Format: Article
Language:English
Published: Sumy State University 2014-11-01
Series:Журнал нано- та електронної фізики
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Online Access:http://jnep.sumdu.edu.ua/download/numbers/2014/4/articles/jnep_2014_V6_04033.pdf
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author V.T. Adamiv
Ya.V. Burak
R.V. Gamernyk
R.M. Dutka
I.M. Teslyuk
author_facet V.T. Adamiv
Ya.V. Burak
R.V. Gamernyk
R.M. Dutka
I.M. Teslyuk
author_sort V.T. Adamiv
collection DOAJ
description Formation of Ag nanoparticles (NPs) in the near-surface layer of CaB4O7–Ag2O and CaB4O7 –Gd2O3–Ag2O glasses by annealing in vacuum or in air is reported. It is concluded that annealing in vacuum does not necessary require the presence of reducing ions. Intensive plasmon absorption bands peaked at 403, 406 and 413.3 nm were observed in the absorption spectra of glasses with Ag NPs. Average radius of nanoparticles was calculated from the plasmon band half width and falls within 1.3-3.3 nm. It is concluded that calculated from normalized transmission spectra and absorption spectra the non-linear refractive index n2 increases due to the plasmon resonance in Ag NPs.
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publisher Sumy State University
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series Журнал нано- та електронної фізики
spelling doaj-art-953b618945cf4767bd96a339f685e1722025-08-20T01:58:41ZengSumy State UniversityЖурнал нано- та електронної фізики2077-67722014-11-016404033-104033-7Formation and Optical Properties of Ag Nanoparticles in CaB4O7–Ag2O and CaB4O7–Gd2O3–Ag2O Tetraborate GlassesV.T. Adamiv0Ya.V. Burak1R.V. Gamernyk2R.M. Dutka3I.M. Teslyuk4Institute of Physical Optics, 23, Dragomanov Str., 7900 Lviv, UkraineInstitute of Physical Optics, 23, Dragomanov Str., 7900 Lviv, UkraineIvan Franko National University, 8, Kyryl and Methodiy Str., 79005 Lviv, UkraineInstitute of Physical Optics, 23, Dragomanov Str., 7900 Lviv, UkraineInstitute of Physical Optics, 23, Dragomanov Str., 7900 Lviv, UkraineFormation of Ag nanoparticles (NPs) in the near-surface layer of CaB4O7–Ag2O and CaB4O7 –Gd2O3–Ag2O glasses by annealing in vacuum or in air is reported. It is concluded that annealing in vacuum does not necessary require the presence of reducing ions. Intensive plasmon absorption bands peaked at 403, 406 and 413.3 nm were observed in the absorption spectra of glasses with Ag NPs. Average radius of nanoparticles was calculated from the plasmon band half width and falls within 1.3-3.3 nm. It is concluded that calculated from normalized transmission spectra and absorption spectra the non-linear refractive index n2 increases due to the plasmon resonance in Ag NPs.http://jnep.sumdu.edu.ua/download/numbers/2014/4/articles/jnep_2014_V6_04033.pdfTetraborate glassAg nanoparticlesPlasmon resonanceNonlinear refractive inde
spellingShingle V.T. Adamiv
Ya.V. Burak
R.V. Gamernyk
R.M. Dutka
I.M. Teslyuk
Formation and Optical Properties of Ag Nanoparticles in CaB4O7–Ag2O and CaB4O7–Gd2O3–Ag2O Tetraborate Glasses
Журнал нано- та електронної фізики
Tetraborate glass
Ag nanoparticles
Plasmon resonance
Nonlinear refractive inde
title Formation and Optical Properties of Ag Nanoparticles in CaB4O7–Ag2O and CaB4O7–Gd2O3–Ag2O Tetraborate Glasses
title_full Formation and Optical Properties of Ag Nanoparticles in CaB4O7–Ag2O and CaB4O7–Gd2O3–Ag2O Tetraborate Glasses
title_fullStr Formation and Optical Properties of Ag Nanoparticles in CaB4O7–Ag2O and CaB4O7–Gd2O3–Ag2O Tetraborate Glasses
title_full_unstemmed Formation and Optical Properties of Ag Nanoparticles in CaB4O7–Ag2O and CaB4O7–Gd2O3–Ag2O Tetraborate Glasses
title_short Formation and Optical Properties of Ag Nanoparticles in CaB4O7–Ag2O and CaB4O7–Gd2O3–Ag2O Tetraborate Glasses
title_sort formation and optical properties of ag nanoparticles in cab4o7 ag2o and cab4o7 gd2o3 ag2o tetraborate glasses
topic Tetraborate glass
Ag nanoparticles
Plasmon resonance
Nonlinear refractive inde
url http://jnep.sumdu.edu.ua/download/numbers/2014/4/articles/jnep_2014_V6_04033.pdf
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