Innovative Integration of Citric Acid Leaching and Electrodialysis for Selective Lithium Recovery from NMC Cathode Material
With the growing demand for metals driven by technological advancements and population growth, recycling lithium-ion batteries has become vital for protecting the environment and recovering valuable materials. Developing sustainable recycling technologies is now more essential than ever. This paper...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2025-05-01
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| Series: | Metals |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2075-4701/15/6/598 |
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| Summary: | With the growing demand for metals driven by technological advancements and population growth, recycling lithium-ion batteries has become vital for protecting the environment and recovering valuable materials. Developing sustainable recycling technologies is now more essential than ever. This paper focuses on using electrodialysis to process a leach solution of LiNi<sub>0.33</sub>Mn<sub>0.33</sub>Co<sub>0.33</sub>O<sub>2</sub> (NMC 111) cathode materials leached with citric acid. This study demonstrates that the complexing properties of citrate anions contribute to the efficient separation of Li from Ni, Co, and Mn by electrodialysis. This is achieved by promoting the formation of anionic species for Ni, Co, and Mn while maintaining Li in its cationic form. The leach solution was produced under the following optimal experimental conditions to reach a final pH of 5 and high leaching efficiency: a citric acid concentration of 1 mol L<sup>−1</sup>, a leaching temperature of 45 °C, a leaching time of 5 h, a liquid/solid ratio of 100 g/L, and 8 vol.% H<sub>2</sub>O<sub>2</sub>. These conditions resulted in leaching efficiencies of 89.3% for Ni, 95.1% for Co, 77.1% for Mn, and 92.9% for Li. This solution led to the formation of a lithium-rich supernatant and a precipitate. The supernatant was then used as the feed solution for electrodialysis. Pure lithium was successfully separated with a faradic efficiency of 71.4% with a commercial cation-exchange membrane. This strategy enables selective lithium recovery while minimizing membrane fouling during the process. |
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| ISSN: | 2075-4701 |