Physicochemical properties of the complex oxides in Sm-Ba-Me-Cu-O (Me = Fe, Co) systems

The present work was focused on the studies of crystal structure, oxygen nonstoichiometry, thermal expansion of SmBaCo2−xCuxO6-δ and SmBaFe2−xCuxO6-δ. Values of the oxygen content in complex oxides SmBaCo2‑xCuxО6‑δ were determined over a wide temperature range in air using high temperature thermogra...

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Main Authors: N. E. Volkova, K. M. Deryabina, L. Ya. Gavrilova, V. A. Cherepanov
Format: Article
Language:English
Published: Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina 2015-05-01
Series:Chimica Techno Acta
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Online Access:https://chimicatechnoacta.ru/article/view/1125
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author N. E. Volkova
K. M. Deryabina
L. Ya. Gavrilova
V. A. Cherepanov
author_facet N. E. Volkova
K. M. Deryabina
L. Ya. Gavrilova
V. A. Cherepanov
author_sort N. E. Volkova
collection DOAJ
description The present work was focused on the studies of crystal structure, oxygen nonstoichiometry, thermal expansion of SmBaCo2−xCuxO6-δ and SmBaFe2−xCuxO6-δ. Values of the oxygen content in complex oxides SmBaCo2‑xCuxО6‑δ were determined over a wide temperature range in air using high temperature thermogravimetry and iodometric titration. Also, chemical stability with respect to Ce0.8Sm0.2O1.9 and Zr0.85Y0.15O1.93 two common solid electrolyte materials used for SOFCs was evaluated.
format Article
id doaj-art-93b53a18a1fe47b0a592d646bfd01f0d
institution Kabale University
issn 2411-1414
language English
publishDate 2015-05-01
publisher Uralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. Elʹcina
record_format Article
series Chimica Techno Acta
spelling doaj-art-93b53a18a1fe47b0a592d646bfd01f0d2024-12-25T09:36:56ZengUralʹskij federalʹnyj universitet imeni pervogo Prezidenta Rossii B.N. ElʹcinaChimica Techno Acta2411-14142015-05-012214715710.15826/chimtech.2015.2.2.0161241Physicochemical properties of the complex oxides in Sm-Ba-Me-Cu-O (Me = Fe, Co) systemsN. E. Volkova0K. M. Deryabina1L. Ya. Gavrilova2V. A. Cherepanov3Уральский федеральный университет, ЕкатеринбургУральский федеральный университет, ЕкатеринбургУральский федеральный университет, ЕкатеринбургУральский федеральный университет, ЕкатеринбургThe present work was focused on the studies of crystal structure, oxygen nonstoichiometry, thermal expansion of SmBaCo2−xCuxO6-δ and SmBaFe2−xCuxO6-δ. Values of the oxygen content in complex oxides SmBaCo2‑xCuxО6‑δ were determined over a wide temperature range in air using high temperature thermogravimetry and iodometric titration. Also, chemical stability with respect to Ce0.8Sm0.2O1.9 and Zr0.85Y0.15O1.93 two common solid electrolyte materials used for SOFCs was evaluated.https://chimicatechnoacta.ru/article/view/1125слоистые перовскитоподобные соединениятермогравиметрические исследованиякоэффициенты термического расширения
spellingShingle N. E. Volkova
K. M. Deryabina
L. Ya. Gavrilova
V. A. Cherepanov
Physicochemical properties of the complex oxides in Sm-Ba-Me-Cu-O (Me = Fe, Co) systems
Chimica Techno Acta
слоистые перовскитоподобные соединения
термогравиметрические исследования
коэффициенты термического расширения
title Physicochemical properties of the complex oxides in Sm-Ba-Me-Cu-O (Me = Fe, Co) systems
title_full Physicochemical properties of the complex oxides in Sm-Ba-Me-Cu-O (Me = Fe, Co) systems
title_fullStr Physicochemical properties of the complex oxides in Sm-Ba-Me-Cu-O (Me = Fe, Co) systems
title_full_unstemmed Physicochemical properties of the complex oxides in Sm-Ba-Me-Cu-O (Me = Fe, Co) systems
title_short Physicochemical properties of the complex oxides in Sm-Ba-Me-Cu-O (Me = Fe, Co) systems
title_sort physicochemical properties of the complex oxides in sm ba me cu o me fe co systems
topic слоистые перовскитоподобные соединения
термогравиметрические исследования
коэффициенты термического расширения
url https://chimicatechnoacta.ru/article/view/1125
work_keys_str_mv AT nevolkova physicochemicalpropertiesofthecomplexoxidesinsmbamecuomefecosystems
AT kmderyabina physicochemicalpropertiesofthecomplexoxidesinsmbamecuomefecosystems
AT lyagavrilova physicochemicalpropertiesofthecomplexoxidesinsmbamecuomefecosystems
AT vacherepanov physicochemicalpropertiesofthecomplexoxidesinsmbamecuomefecosystems