Preparation of Ni Doped ZnO-TiO2 Composites and Their Enhanced Photocatalytic Activity

Herein, Ni doped ZnO-TiO2 composites were prepared by facile sol-gel approach and were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), UV-visible diffuse reflectance spectroscopy (UV-Vis DRS), X-ray photoelectron spectroscopy (XPS), and photoluminescence spectroscop...

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Bibliographic Details
Main Authors: Xiaowen Zou, Xiaoli Dong, Limei Wang, Hongchao Ma, Xinxin Zhang, Xiufang Zhang
Format: Article
Language:English
Published: Wiley 2014-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2014/893158
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Summary:Herein, Ni doped ZnO-TiO2 composites were prepared by facile sol-gel approach and were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), UV-visible diffuse reflectance spectroscopy (UV-Vis DRS), X-ray photoelectron spectroscopy (XPS), and photoluminescence spectroscopy (PL). The results indicated that the Ni ions can be incorporated into the lattice of TiO2 structure and replace Ti. The introduction of Ni expanded light absorption of TiO2 to visible region, increased amount of surface hydroxyl groups and physically adsorbed oxygen (as the electronic scavenges), and then enhanced separation rate of photogenerated carriers. The photodegradation test of reactive brilliant blue (KN-R) under simulated solar light indicated that Ni doped ZnO-TiO2 composites have better photocatalytic activities, as compared to those of TiO2 and ZnO-TiO2.
ISSN:1110-662X
1687-529X