PREPARATION AND MOLECULAR STRUCTURE OF BIS (TETRAMETHYLETHYLENEDIAMINE) COPPER(I) DICHLORO CUPRATE(I) , [Cu (TMEDA) ] [CuC1 ]
A complex of N, N, N', N', -tetramethylated ethylenediamine, TMEDA, with CuCI is prepared. The crystal and molecular structure of this complex is characterized by a single-crystal X-ray diffraction study. The complex is found to contain [Cu (TMEDA) ] cation which is nearly tetrahedral and...
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| Format: | Article |
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| Language: | English |
| Published: |
University of Tehran
1993-12-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
| Online Access: | https://jsciences.ut.ac.ir/article_31296_14d48a6cead1e47b33d5255bd2333d1c.pdf |
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| Summary: | A complex of N, N, N', N', -tetramethylated ethylenediamine, TMEDA, with CuCI is prepared. The crystal and molecular structure of this complex is characterized
by a single-crystal X-ray diffraction study. The complex is found to contain [Cu
(TMEDA) ] cation which is nearly tetrahedral and the [CuCI ) anion is linear which
Cu lies on a center of symmetry. Crystals are monoclinic space group P2 / n with four molecules/ unit cell of dimensions a = 9.240 (4), b = 14.930 (3), c = 14.288 (5) ? and
B= 97.02 (3)?. The final R value is 0.045 for 3808 reflections measured. |
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| ISSN: | 1016-1104 2345-6914 |