Effect of Combined Addition of La and Sm on Mechanical Properties, Microstructure Evolution, and Electrochemical Behavior of Mg-3Zn-1Mn/Sn-0.5Ca Alloy

The effects of the composite addition of La and Sm elements on the microstructural evolution, mechanical properties, and electrochemical behaviors of Mg-3Zn-1Mn/Sn-0.5Ca (wt.%) alloys are systematically investigated. The findings reveal that the Mg-3Zn-1Mn-0.5Ca alloy exhibits excellent ductility, a...

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Main Authors: Ke Hu, Shuanghai Li, Junjie Huang, Xiaoming Guo, Tingting Tian, Xiao Liu, Zheng Jia
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Metals
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Online Access:https://www.mdpi.com/2075-4701/14/11/1252
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Summary:The effects of the composite addition of La and Sm elements on the microstructural evolution, mechanical properties, and electrochemical behaviors of Mg-3Zn-1Mn/Sn-0.5Ca (wt.%) alloys are systematically investigated. The findings reveal that the Mg-3Zn-1Mn-0.5Ca alloy exhibits excellent ductility, achieving 26% elongation, whereas the Mg-3Zn-1Sn-0.5Ca alloy demonstrates good comprehensive mechanical properties. The addition of La and Sm results in a degree of grain refinement in both alloys and significantly bolsters the strength of the Mg-3Zn-1Mn-0.5Ca alloy, but it has a less pronounced effect on the mechanical properties of the Mg-3Zn-1Sn-0.5Ca alloy. Furthermore, the addition of La-Sm significantly improves the corrosion resistance of both alloys. Electrochemical impedance spectroscopy (EIS) analysis reveals that all four alloys form a double-capacitance loop morphology in 3.5% NaCl, indicating the formation of a protective film during the corrosion process. Among them, the Mg-3Zn-1Mn-0.5Ca-1La-0.5Sm alloy exhibits the largest capacitance loop radius, which is consistent with its polarization curve, indicating the best corrosion resistance. At the corrosion potential of −1.382V, the corrosion current is 8.97 μA·cm<sup>−2</sup>.
ISSN:2075-4701