Characterization of the interfacial interaction of PCC nano powder with tallow fatty acids for HDPE compounding

Mugar Precipitated Calcium Carbonate (MPCC) Nano-Powders were synthesized using a solution approach and coated with tallow fatty acid to enhance their compatibility with high-density polyethylene (HDPE) composites. The coated MPCC (MCPCC) nanoparticles were incorporated into HDPE to improve interfac...

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Main Authors: Chernet Merkneh, Getinet Asrat Mengesha, Shimelis Lemma, Gebisa Bekele
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Results in Materials
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Online Access:http://www.sciencedirect.com/science/article/pii/S2590048X25000354
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author Chernet Merkneh
Getinet Asrat Mengesha
Shimelis Lemma
Gebisa Bekele
author_facet Chernet Merkneh
Getinet Asrat Mengesha
Shimelis Lemma
Gebisa Bekele
author_sort Chernet Merkneh
collection DOAJ
description Mugar Precipitated Calcium Carbonate (MPCC) Nano-Powders were synthesized using a solution approach and coated with tallow fatty acid to enhance their compatibility with high-density polyethylene (HDPE) composites. The coated MPCC (MCPCC) nanoparticles were incorporated into HDPE to improve interfacial interaction, tensile strength, and toughness. The study investigated the effects of varying MPCC weight percentages (0–40 %) and the role of the tallow fatty acid coating in optimizing composite properties. Thermal, structural, and morphological analyses, including TGA, XRD, FTIR, DLS, and SEM, were conducted to evaluate the dispersion and interfacial interactions between MPCC and the HDPE matrix. The results demonstrated that the tallow coating significantly improved the mechanical properties of the composites. Notably, the coated MPCC nanoparticles enhanced tensile strength and toughness compared to uncoated counterparts, with the coating also contributing to better thermal stability. The research highlights the innovative use of tallow fatty acid as a coating agent to improve filler-matrix compatibility, a distinction from previous studies that often rely on synthetic or non-biodegradable coatings. This approach not only enhances the mechanical and thermal properties of HDPE composites but also offers a sustainable alternative for industrial applications. Further optimization of coating processes and particle size distribution could lead to even greater improvements in composite performance.
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issn 2590-048X
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publishDate 2025-06-01
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spelling doaj-art-9101a3ffdec84810a60c48546d3b0c142025-08-20T02:05:36ZengElsevierResults in Materials2590-048X2025-06-012610069010.1016/j.rinma.2025.100690Characterization of the interfacial interaction of PCC nano powder with tallow fatty acids for HDPE compoundingChernet Merkneh0Getinet Asrat Mengesha1Shimelis Lemma2Gebisa Bekele3Department of Materials Science and Engineering, Beijing University of Chemical Technology, ChinaDepartment of Materials Science and Engineering, Adama Science and Technology University, Ethiopia; Corresponding author.Department of Materials Science and Engineering, Adama Science and Technology University, EthiopiaDepartment of Materials Science and Engineering, Adama Science and Technology University, EthiopiaMugar Precipitated Calcium Carbonate (MPCC) Nano-Powders were synthesized using a solution approach and coated with tallow fatty acid to enhance their compatibility with high-density polyethylene (HDPE) composites. The coated MPCC (MCPCC) nanoparticles were incorporated into HDPE to improve interfacial interaction, tensile strength, and toughness. The study investigated the effects of varying MPCC weight percentages (0–40 %) and the role of the tallow fatty acid coating in optimizing composite properties. Thermal, structural, and morphological analyses, including TGA, XRD, FTIR, DLS, and SEM, were conducted to evaluate the dispersion and interfacial interactions between MPCC and the HDPE matrix. The results demonstrated that the tallow coating significantly improved the mechanical properties of the composites. Notably, the coated MPCC nanoparticles enhanced tensile strength and toughness compared to uncoated counterparts, with the coating also contributing to better thermal stability. The research highlights the innovative use of tallow fatty acid as a coating agent to improve filler-matrix compatibility, a distinction from previous studies that often rely on synthetic or non-biodegradable coatings. This approach not only enhances the mechanical and thermal properties of HDPE composites but also offers a sustainable alternative for industrial applications. Further optimization of coating processes and particle size distribution could lead to even greater improvements in composite performance.http://www.sciencedirect.com/science/article/pii/S2590048X25000354Calcium carbonateTallowCompositeFillersFatty acids
spellingShingle Chernet Merkneh
Getinet Asrat Mengesha
Shimelis Lemma
Gebisa Bekele
Characterization of the interfacial interaction of PCC nano powder with tallow fatty acids for HDPE compounding
Results in Materials
Calcium carbonate
Tallow
Composite
Fillers
Fatty acids
title Characterization of the interfacial interaction of PCC nano powder with tallow fatty acids for HDPE compounding
title_full Characterization of the interfacial interaction of PCC nano powder with tallow fatty acids for HDPE compounding
title_fullStr Characterization of the interfacial interaction of PCC nano powder with tallow fatty acids for HDPE compounding
title_full_unstemmed Characterization of the interfacial interaction of PCC nano powder with tallow fatty acids for HDPE compounding
title_short Characterization of the interfacial interaction of PCC nano powder with tallow fatty acids for HDPE compounding
title_sort characterization of the interfacial interaction of pcc nano powder with tallow fatty acids for hdpe compounding
topic Calcium carbonate
Tallow
Composite
Fillers
Fatty acids
url http://www.sciencedirect.com/science/article/pii/S2590048X25000354
work_keys_str_mv AT chernetmerkneh characterizationoftheinterfacialinteractionofpccnanopowderwithtallowfattyacidsforhdpecompounding
AT getinetasratmengesha characterizationoftheinterfacialinteractionofpccnanopowderwithtallowfattyacidsforhdpecompounding
AT shimelislemma characterizationoftheinterfacialinteractionofpccnanopowderwithtallowfattyacidsforhdpecompounding
AT gebisabekele characterizationoftheinterfacialinteractionofpccnanopowderwithtallowfattyacidsforhdpecompounding