Metal–Ligand Cooperation in Dihydrogen Activation by a Cationic Metallogermylene: Enhanced Activity from Tungsten to Molybdenum

Metal–Ligand Cooperation in Dihydrogen Activation by a Cationic Metallogermylene: Enhanced Activity from Tungsten to Molybdenum

Dihydrogen activation by metallogermylenes was investigated experimentally and theoretically. A neutral NHC-coordinated chlorometallogermylene was synthesized and converted to a cationic base-free metallogermylene of molybdenum via chloride abstraction. The cationic molybdogermylene showed enhanced...

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Bibliographic Details
Main Authors: Rikiya Matsumoto, Koichi Nagata, Ryo Nakamura, Takahito Watanabe, Hisako Hashimoto
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Molecules
Subjects:
metallotetrylene
germylene
dihydrogen activation
metal–ligand cooperation
Online Access:https://www.mdpi.com/1420-3049/29/24/5974
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