Practical Guidance for Obtaining Optimum cis-Selectivities in Wittig Reactions with Triphenylphosphonio-alkanides

Attention is drawn to the crucial role played by the base, the solvent, and the temperature in determining the stereochemical outcome of «salt-free» olefination reactions. Under optimized conditions unprecedented cis-selectivities are observed. 

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Bibliographic Details
Main Authors: Manfred Schlosser, Bruno Schaub, Jose de Oliveira-Neto, Suruliappa Jeganathan
Format: Article
Language:deu
Published: Swiss Chemical Society 1986-08-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9741
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