Investigations and optimization of CO2 capture using a new composite of montmorillonite and choline-chloride-urea in a continuous fixed bed; breakthrough and RSM modeling
This article presents a comprehensive study of CO2 capture using a new composite of Montmorillonite and Choline-Chloride-Urea in a continous fixed-bed adsorption system. The results revealed superior performance of a surface-activated mesoporous support compared to the unmodified solid support. The...
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Elsevier
2024-12-01
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Series: | Case Studies in Chemical and Environmental Engineering |
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Online Access: | http://www.sciencedirect.com/science/article/pii/S2666016424002895 |
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author | Aminreza Ansari Shahrokh Shahhosseini |
author_facet | Aminreza Ansari Shahrokh Shahhosseini |
author_sort | Aminreza Ansari |
collection | DOAJ |
description | This article presents a comprehensive study of CO2 capture using a new composite of Montmorillonite and Choline-Chloride-Urea in a continous fixed-bed adsorption system. The results revealed superior performance of a surface-activated mesoporous support compared to the unmodified solid support. The breakthrough curves, adsorption capacities, regenerability, and CO2/N2 selectivity of the developed nano-caly adsorbent were also studied for the first time. The ANOVA analysis indicated highly significant effects of gas flow rate and CO2 vol. % on breakthrough-time and adsorption capacity. The kinetic mathematical models were applied for breakthrough curve analysis. Clark model fitted to the experimental data better than others. |
format | Article |
id | doaj-art-9099367b60554f409e2bd34b00c45d45 |
institution | Kabale University |
issn | 2666-0164 |
language | English |
publishDate | 2024-12-01 |
publisher | Elsevier |
record_format | Article |
series | Case Studies in Chemical and Environmental Engineering |
spelling | doaj-art-9099367b60554f409e2bd34b00c45d452024-12-02T05:06:03ZengElsevierCase Studies in Chemical and Environmental Engineering2666-01642024-12-0110100895Investigations and optimization of CO2 capture using a new composite of montmorillonite and choline-chloride-urea in a continuous fixed bed; breakthrough and RSM modelingAminreza Ansari0Shahrokh Shahhosseini1School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, 16765-193, IranCorresponding author.; School of Chemical, Petroleum and Gas Engineering, Iran University of Science and Technology, Tehran, 16765-193, IranThis article presents a comprehensive study of CO2 capture using a new composite of Montmorillonite and Choline-Chloride-Urea in a continous fixed-bed adsorption system. The results revealed superior performance of a surface-activated mesoporous support compared to the unmodified solid support. The breakthrough curves, adsorption capacities, regenerability, and CO2/N2 selectivity of the developed nano-caly adsorbent were also studied for the first time. The ANOVA analysis indicated highly significant effects of gas flow rate and CO2 vol. % on breakthrough-time and adsorption capacity. The kinetic mathematical models were applied for breakthrough curve analysis. Clark model fitted to the experimental data better than others.http://www.sciencedirect.com/science/article/pii/S2666016424002895Breakthrough-timeCO2 adsorption capacityDeep eutectic solventContinuous-fixed-bedMontmorillonite |
spellingShingle | Aminreza Ansari Shahrokh Shahhosseini Investigations and optimization of CO2 capture using a new composite of montmorillonite and choline-chloride-urea in a continuous fixed bed; breakthrough and RSM modeling Case Studies in Chemical and Environmental Engineering Breakthrough-time CO2 adsorption capacity Deep eutectic solvent Continuous-fixed-bed Montmorillonite |
title | Investigations and optimization of CO2 capture using a new composite of montmorillonite and choline-chloride-urea in a continuous fixed bed; breakthrough and RSM modeling |
title_full | Investigations and optimization of CO2 capture using a new composite of montmorillonite and choline-chloride-urea in a continuous fixed bed; breakthrough and RSM modeling |
title_fullStr | Investigations and optimization of CO2 capture using a new composite of montmorillonite and choline-chloride-urea in a continuous fixed bed; breakthrough and RSM modeling |
title_full_unstemmed | Investigations and optimization of CO2 capture using a new composite of montmorillonite and choline-chloride-urea in a continuous fixed bed; breakthrough and RSM modeling |
title_short | Investigations and optimization of CO2 capture using a new composite of montmorillonite and choline-chloride-urea in a continuous fixed bed; breakthrough and RSM modeling |
title_sort | investigations and optimization of co2 capture using a new composite of montmorillonite and choline chloride urea in a continuous fixed bed breakthrough and rsm modeling |
topic | Breakthrough-time CO2 adsorption capacity Deep eutectic solvent Continuous-fixed-bed Montmorillonite |
url | http://www.sciencedirect.com/science/article/pii/S2666016424002895 |
work_keys_str_mv | AT aminrezaansari investigationsandoptimizationofco2captureusinganewcompositeofmontmorilloniteandcholinechlorideureainacontinuousfixedbedbreakthroughandrsmmodeling AT shahrokhshahhosseini investigationsandoptimizationofco2captureusinganewcompositeofmontmorilloniteandcholinechlorideureainacontinuousfixedbedbreakthroughandrsmmodeling |