Influence of substitution for on the microwave dielectric properties of Mg2Al4Snx ceramics

The Mg2Al4[Formula: see text]Snx[Formula: see text] ([Formula: see text]) ceramics were successfully synthesized via the solid-state reaction method. The XRD results show that the main phase of the ceramics is Mg2Al4Si5[Formula: see text]. When [Formula: see text], there is a second phase of Al2SiO5...

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Main Authors: Junbo Guo, Xiangpeng Wang, Yang Song, Leijun Yao, Chuanshi Min, Xiao Li, Fanshuo Wang, Yuanming Lai
Format: Article
Language:English
Published: World Scientific Publishing 2024-12-01
Series:Journal of Advanced Dielectrics
Subjects:
Online Access:https://www.worldscientific.com/doi/10.1142/S2010135X24400137
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author Junbo Guo
Xiangpeng Wang
Yang Song
Leijun Yao
Chuanshi Min
Xiao Li
Fanshuo Wang
Yuanming Lai
author_facet Junbo Guo
Xiangpeng Wang
Yang Song
Leijun Yao
Chuanshi Min
Xiao Li
Fanshuo Wang
Yuanming Lai
author_sort Junbo Guo
collection DOAJ
description The Mg2Al4[Formula: see text]Snx[Formula: see text] ([Formula: see text]) ceramics were successfully synthesized via the solid-state reaction method. The XRD results show that the main phase of the ceramics is Mg2Al4Si5[Formula: see text]. When [Formula: see text], there is a second phase of Al2SiO5. With the increase of x, the content of [Formula: see text] gradually increased, the Al2SiO5 phase disappeared, and the SnO2 and MgAl2O4 phases appeared. In addition, the cell volume of the ceramic changes with the increase of x, which indicates that partial [Formula: see text] successfully enters the lattice with ion substitution and lattice distortion. The relative density and [Formula: see text] are highly correlated. The quality factor (Qf) is not only affected by the relative density but also by the symmetry of the [Si4Al2] ring. The bond strength as an evaluation of the stability of the crystal structure determines the magnitude of [Formula: see text]. Good microwave dielectric properties were achieved for samples at [Formula: see text] with sintering at 1400∘C: [Formula: see text], [Formula: see text][Formula: see text]GHz and [Formula: see text][Formula: see text]ppm/∘C, demonstrating that Mg2Al4[Formula: see text][Formula: see text][Formula: see text] ceramics are an ideal candidate for microwave electronics.
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record_format Article
series Journal of Advanced Dielectrics
spelling doaj-art-8fda2cef009e4c8692c39d33e0b4a4c72025-08-20T02:38:59ZengWorld Scientific PublishingJournal of Advanced Dielectrics2010-135X2010-13682024-12-01140610.1142/S2010135X24400137Influence of substitution for on the microwave dielectric properties of Mg2Al4Snx ceramicsJunbo Guo0Xiangpeng Wang1Yang Song2Leijun Yao3Chuanshi Min4Xiao Li5Fanshuo Wang6Yuanming Lai7China Anneng Group Third Engineering Bureau Co., Ltd., Chengdu 610036, P. R. ChinaKey Laboratory of Earth Exploration and Information Technology of Ministry of Education, Chengdu University of Technology, Chengdu 610059, P. R. ChinaChina Anneng Group Third Engineering Bureau Co., Ltd., Chengdu 610036, P. R. ChinaChina Anneng Group Third Engineering Bureau Co., Ltd., Chengdu 610036, P. R. ChinaYa’an Zhengxing White Marble Co., Ltd., Ya’an 625701, P. R. ChinaSchool of Mechanical and Electrical Engineering, Chengdu University of Technology, Chengdu 610059, P. R. ChinaSchool of Mechanical and Electrical Engineering, Chengdu University of Technology, Chengdu 610059, P. R. ChinaSchool of Mechanical and Electrical Engineering, Chengdu University of Technology, Chengdu 610059, P. R. ChinaThe Mg2Al4[Formula: see text]Snx[Formula: see text] ([Formula: see text]) ceramics were successfully synthesized via the solid-state reaction method. The XRD results show that the main phase of the ceramics is Mg2Al4Si5[Formula: see text]. When [Formula: see text], there is a second phase of Al2SiO5. With the increase of x, the content of [Formula: see text] gradually increased, the Al2SiO5 phase disappeared, and the SnO2 and MgAl2O4 phases appeared. In addition, the cell volume of the ceramic changes with the increase of x, which indicates that partial [Formula: see text] successfully enters the lattice with ion substitution and lattice distortion. The relative density and [Formula: see text] are highly correlated. The quality factor (Qf) is not only affected by the relative density but also by the symmetry of the [Si4Al2] ring. The bond strength as an evaluation of the stability of the crystal structure determines the magnitude of [Formula: see text]. Good microwave dielectric properties were achieved for samples at [Formula: see text] with sintering at 1400∘C: [Formula: see text], [Formula: see text][Formula: see text]GHz and [Formula: see text][Formula: see text]ppm/∘C, demonstrating that Mg2Al4[Formula: see text][Formula: see text][Formula: see text] ceramics are an ideal candidate for microwave electronics.https://www.worldscientific.com/doi/10.1142/S2010135X24400137Microwave dielectric ceramicslow dielectric constantcordierite
spellingShingle Junbo Guo
Xiangpeng Wang
Yang Song
Leijun Yao
Chuanshi Min
Xiao Li
Fanshuo Wang
Yuanming Lai
Influence of substitution for on the microwave dielectric properties of Mg2Al4Snx ceramics
Journal of Advanced Dielectrics
Microwave dielectric ceramics
low dielectric constant
cordierite
title Influence of substitution for on the microwave dielectric properties of Mg2Al4Snx ceramics
title_full Influence of substitution for on the microwave dielectric properties of Mg2Al4Snx ceramics
title_fullStr Influence of substitution for on the microwave dielectric properties of Mg2Al4Snx ceramics
title_full_unstemmed Influence of substitution for on the microwave dielectric properties of Mg2Al4Snx ceramics
title_short Influence of substitution for on the microwave dielectric properties of Mg2Al4Snx ceramics
title_sort influence of substitution for on the microwave dielectric properties of mg2al4snx ceramics
topic Microwave dielectric ceramics
low dielectric constant
cordierite
url https://www.worldscientific.com/doi/10.1142/S2010135X24400137
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