Mitigation of Acid Mine Drainage Using Blended Waste Rock in Near-Equatorial Climates—Geochemical Analysis and Column Leaching Tests

Acid mine drainage (AMD), wherein acidic water is generated from pyrite-containing waste rock, can be mitigated by encapsulating pyritic waste rock with cover materials to restrict the inflow of oxygen and water. However, acidic water inevitably forms during the construction of waste rock dumps befo...

Full description

Saved in:
Bibliographic Details
Main Authors: Akihiro Hamanaka, Takashi Sasaoka, Hideki Shimada, Shinji Matsumoto, Ginting Jalu Kusuma, Mokhamad Candra Nugraha Deni
Format: Article
Language:English
Published: MDPI AG 2024-11-01
Series:Physchem
Subjects:
Online Access:https://www.mdpi.com/2673-7167/4/4/33
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1846103154985271296
author Akihiro Hamanaka
Takashi Sasaoka
Hideki Shimada
Shinji Matsumoto
Ginting Jalu Kusuma
Mokhamad Candra Nugraha Deni
author_facet Akihiro Hamanaka
Takashi Sasaoka
Hideki Shimada
Shinji Matsumoto
Ginting Jalu Kusuma
Mokhamad Candra Nugraha Deni
author_sort Akihiro Hamanaka
collection DOAJ
description Acid mine drainage (AMD), wherein acidic water is generated from pyrite-containing waste rock, can be mitigated by encapsulating pyritic waste rock with cover materials to restrict the inflow of oxygen and water. However, acidic water inevitably forms during the construction of waste rock dumps before applying cover materials. Considering that the presence of waste rock containing carbonate minerals contributes to acid neutralization, a mixture of carbonate minerals and pyritic waste rock can be utilized to reduce AMD generation before the completion of the cover system as a temporary management strategy. This paper examines waste rock management using blending scenarios. Kinetic NAG and column leaching tests were employed to evaluate the blending ratio necessary to prevent acidic water generation. Geochemical analyses were conducted on rock and leachate samples, including pH and temperature measurements, XRD and XRF analyses, and Ion Chromatography. Consequently, the pH and temperature measurement results obtained during the kinetic NAG test are valuable for expressing the balance between acid generation and acid neutralization by the mixture material. Furthermore, the column leaching test demonstrated that the pH of the leachate remained neutral when the acid generation and acid neutralization reactions were well balanced. Blending waste rocks is an effective method for AMD reduction during the construction of waste rock dumps.
format Article
id doaj-art-8f62b5c5855a400c891f95f3735e9c19
institution Kabale University
issn 2673-7167
language English
publishDate 2024-11-01
publisher MDPI AG
record_format Article
series Physchem
spelling doaj-art-8f62b5c5855a400c891f95f3735e9c192024-12-27T14:47:29ZengMDPI AGPhyschem2673-71672024-11-014447048210.3390/physchem4040033Mitigation of Acid Mine Drainage Using Blended Waste Rock in Near-Equatorial Climates—Geochemical Analysis and Column Leaching TestsAkihiro Hamanaka0Takashi Sasaoka1Hideki Shimada2Shinji Matsumoto3Ginting Jalu Kusuma4Mokhamad Candra Nugraha Deni5Department of Earth Resources Engineering, Faculty of Engineering, Kyushu University, Fukuoka 8190395, JapanDepartment of Earth Resources Engineering, Faculty of Engineering, Kyushu University, Fukuoka 8190395, JapanDepartment of Earth Resources Engineering, Faculty of Engineering, Kyushu University, Fukuoka 8190395, JapanGeological Survey of Japan, National Institute of Advanced Industrial Science and Technology (AIST), Tsukuba 3058567, JapanDepartment of Mining Engineering, Faculty of Mining and Petroleum Engineering, Institut Teknologi Bandung, Bandung 40132, IndonesiaEnvironmental Engineering, Faculty of Civil Engineering and Planning, National Institute of Technology, Bandung 40124, IndonesiaAcid mine drainage (AMD), wherein acidic water is generated from pyrite-containing waste rock, can be mitigated by encapsulating pyritic waste rock with cover materials to restrict the inflow of oxygen and water. However, acidic water inevitably forms during the construction of waste rock dumps before applying cover materials. Considering that the presence of waste rock containing carbonate minerals contributes to acid neutralization, a mixture of carbonate minerals and pyritic waste rock can be utilized to reduce AMD generation before the completion of the cover system as a temporary management strategy. This paper examines waste rock management using blending scenarios. Kinetic NAG and column leaching tests were employed to evaluate the blending ratio necessary to prevent acidic water generation. Geochemical analyses were conducted on rock and leachate samples, including pH and temperature measurements, XRD and XRF analyses, and Ion Chromatography. Consequently, the pH and temperature measurement results obtained during the kinetic NAG test are valuable for expressing the balance between acid generation and acid neutralization by the mixture material. Furthermore, the column leaching test demonstrated that the pH of the leachate remained neutral when the acid generation and acid neutralization reactions were well balanced. Blending waste rocks is an effective method for AMD reduction during the construction of waste rock dumps.https://www.mdpi.com/2673-7167/4/4/33acid producingacid neutralizingblendingdry coverencapsulation
spellingShingle Akihiro Hamanaka
Takashi Sasaoka
Hideki Shimada
Shinji Matsumoto
Ginting Jalu Kusuma
Mokhamad Candra Nugraha Deni
Mitigation of Acid Mine Drainage Using Blended Waste Rock in Near-Equatorial Climates—Geochemical Analysis and Column Leaching Tests
Physchem
acid producing
acid neutralizing
blending
dry cover
encapsulation
title Mitigation of Acid Mine Drainage Using Blended Waste Rock in Near-Equatorial Climates—Geochemical Analysis and Column Leaching Tests
title_full Mitigation of Acid Mine Drainage Using Blended Waste Rock in Near-Equatorial Climates—Geochemical Analysis and Column Leaching Tests
title_fullStr Mitigation of Acid Mine Drainage Using Blended Waste Rock in Near-Equatorial Climates—Geochemical Analysis and Column Leaching Tests
title_full_unstemmed Mitigation of Acid Mine Drainage Using Blended Waste Rock in Near-Equatorial Climates—Geochemical Analysis and Column Leaching Tests
title_short Mitigation of Acid Mine Drainage Using Blended Waste Rock in Near-Equatorial Climates—Geochemical Analysis and Column Leaching Tests
title_sort mitigation of acid mine drainage using blended waste rock in near equatorial climates geochemical analysis and column leaching tests
topic acid producing
acid neutralizing
blending
dry cover
encapsulation
url https://www.mdpi.com/2673-7167/4/4/33
work_keys_str_mv AT akihirohamanaka mitigationofacidminedrainageusingblendedwasterockinnearequatorialclimatesgeochemicalanalysisandcolumnleachingtests
AT takashisasaoka mitigationofacidminedrainageusingblendedwasterockinnearequatorialclimatesgeochemicalanalysisandcolumnleachingtests
AT hidekishimada mitigationofacidminedrainageusingblendedwasterockinnearequatorialclimatesgeochemicalanalysisandcolumnleachingtests
AT shinjimatsumoto mitigationofacidminedrainageusingblendedwasterockinnearequatorialclimatesgeochemicalanalysisandcolumnleachingtests
AT gintingjalukusuma mitigationofacidminedrainageusingblendedwasterockinnearequatorialclimatesgeochemicalanalysisandcolumnleachingtests
AT mokhamadcandranugrahadeni mitigationofacidminedrainageusingblendedwasterockinnearequatorialclimatesgeochemicalanalysisandcolumnleachingtests