The role of pH in aqueous photocatalytic oxidation of β-estradiol

Experimental studies of aqueous photocatalytic oxidation (PCO) of β-estradiol in TiO2 suspensions were undertaken. The dependence of PCO efficiency and adsorption of β-estradiol on pH was studied. It was found that both the adsorption of β-estradiol and the PCO efficiency increased practically linea...

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Main Authors: Tatyana Malygina, Sergei Preis, Juha Kallas
Format: Article
Language:English
Published: Wiley 2005-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/S1110662X05000280
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author Tatyana Malygina
Sergei Preis
Juha Kallas
author_facet Tatyana Malygina
Sergei Preis
Juha Kallas
author_sort Tatyana Malygina
collection DOAJ
description Experimental studies of aqueous photocatalytic oxidation (PCO) of β-estradiol in TiO2 suspensions were undertaken. The dependence of PCO efficiency and adsorption of β-estradiol on pH was studied. It was found that both the adsorption of β-estradiol and the PCO efficiency increased practically linearly with increasing concentration of OH-ions. The predominant role of direct β-estradiol oxidation with positively charged holes was thus indirectly confirmed.
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institution Kabale University
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spelling doaj-art-8f0d351802d04fa888a818057856d1922025-02-03T06:08:23ZengWileyInternational Journal of Photoenergy1110-662X2005-01-017418719110.1155/S1110662X05000280The role of pH in aqueous photocatalytic oxidation of β-estradiolTatyana Malygina0Sergei Preis1Juha Kallas2Department of Chemical Technology, Lappeenranta University of Technology, P.O. Box 20, Lappeenranta 53851, FinlandDepartment of Chemical Technology, Lappeenranta University of Technology, P.O. Box 20, Lappeenranta 53851, FinlandDepartment of Chemical Technology, Lappeenranta University of Technology, P.O. Box 20, Lappeenranta 53851, FinlandExperimental studies of aqueous photocatalytic oxidation (PCO) of β-estradiol in TiO2 suspensions were undertaken. The dependence of PCO efficiency and adsorption of β-estradiol on pH was studied. It was found that both the adsorption of β-estradiol and the PCO efficiency increased practically linearly with increasing concentration of OH-ions. The predominant role of direct β-estradiol oxidation with positively charged holes was thus indirectly confirmed.http://dx.doi.org/10.1155/S1110662X05000280
spellingShingle Tatyana Malygina
Sergei Preis
Juha Kallas
The role of pH in aqueous photocatalytic oxidation of β-estradiol
International Journal of Photoenergy
title The role of pH in aqueous photocatalytic oxidation of β-estradiol
title_full The role of pH in aqueous photocatalytic oxidation of β-estradiol
title_fullStr The role of pH in aqueous photocatalytic oxidation of β-estradiol
title_full_unstemmed The role of pH in aqueous photocatalytic oxidation of β-estradiol
title_short The role of pH in aqueous photocatalytic oxidation of β-estradiol
title_sort role of ph in aqueous photocatalytic oxidation of β estradiol
url http://dx.doi.org/10.1155/S1110662X05000280
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AT tatyanamalygina roleofphinaqueousphotocatalyticoxidationofbestradiol
AT sergeipreis roleofphinaqueousphotocatalyticoxidationofbestradiol
AT juhakallas roleofphinaqueousphotocatalyticoxidationofbestradiol