Effect of Zn/Al Layered Double Hydroxide Containing 2-Hydroxy-4-n-octoxy-benzophenone on UV Aging Resistance of Asphalt
UV radiation is a main factor to reduce the service life of asphalt pavement due to the UV aging of asphalt binder. To obtain enhanced UV aging resistance, an organic UV absorber called 2-hydroxy-4-n-octoxy-benzophenone (HNOB) had been intercalated into an inorganic UV absorber called Zn/Al layered...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2015-01-01
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| Series: | Advances in Materials Science and Engineering |
| Online Access: | http://dx.doi.org/10.1155/2015/739831 |
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| Summary: | UV radiation is a main factor to reduce the service life of asphalt pavement due to the UV aging of asphalt binder. To obtain enhanced UV aging resistance, an organic UV absorber called 2-hydroxy-4-n-octoxy-benzophenone (HNOB) had been intercalated into an inorganic UV absorber called Zn/Al layered double hydroxide (LDH) to play a combined anti-UV role in asphalt binder. Fourier transform infrared spectroscopy revealed that HNOB anions have been intercalated into the interlayer galleries of Zn/Al-LDH containing HNOB anions (Zn/Al-HNOB−-LDH). X-ray diffraction results of Zn/Al-LDH containing CO32− anions (Zn/Al-CO32--LDH) and Zn/Al-CO32--LDH/styrene-butadiene-styrene (SBS) modified asphalt disclosed that asphalt molecules entered into LDH interlayer galleries to form an expanded phase structure. UV-Vis absorbance patterns showed that Zn/Al-HNOB−-LDH has a better capacity of blocking UV light due to the synergetic effect of HNOB and Zn/Al-LDH. The chemical fractions analysis, conventional physical tests, and rheological tests of SBS modified asphalt, Zn/Al-CO32--LDH/SBS modified asphalt, and Zn/Al-HNOB−-LDH/SBS modified asphalt before and after UV aging testified that Zn/Al-HNOB−-LDH can improve the UV aging resistance of SBS modified asphalt more significantly. |
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| ISSN: | 1687-8434 1687-8442 |