Acidity Enhancement through Homoconjugation: Selective Introduction of Sodium into Olefinic Positions
When treated with butyllithium and sodium tert-butoxide, both norbornadiene and norbornene undergo a hydrogen/sodium-exchange at the 2-position. The diene, however, reacts approximately 30 times faster. Bicyclo[3.2.0]hepta-2,6-diene is also more readily metalated than bicyclo[3.2.0]hept-6-ene and i...
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| Main Authors: | , , , |
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| Format: | Article |
| Language: | deu |
| Published: |
Swiss Chemical Society
1985-08-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9674 |
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