Crystal structure of p-xylene@silicalite-1
The crystal structure of a highly loaded complex of silicalite-1 (SL-1) with eight molecules of p-xylene per unit cell has been solved by single-crystal X-ray diffraction. In the crystal, four symmetrical Si24O48·2C8H10 subunits per unit cell are observed. The p-xylene molecules sit at two different...
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International Union of Crystallography
2025-01-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | https://journals.iucr.org/paper?S2056989024011642 |
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| _version_ | 1841557935539355648 |
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| author | In-Chul Hwang |
| author_facet | In-Chul Hwang |
| author_sort | In-Chul Hwang |
| collection | DOAJ |
| description | The crystal structure of a highly loaded complex of silicalite-1 (SL-1) with eight molecules of p-xylene per unit cell has been solved by single-crystal X-ray diffraction. In the crystal, four symmetrical Si24O48·2C8H10 subunits per unit cell are observed. The p-xylene molecules sit at two different positions within the SL-1 channels. The first molecule is located at the intersection of the sinusoidal and straight channels, while the second guest molecule is positioned in the center of the double ten-membered ring (10-MR) of the sinusoidal channel. |
| format | Article |
| id | doaj-art-8d43ca5463ee47feac02048101ec9a03 |
| institution | Kabale University |
| issn | 2056-9890 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj-art-8d43ca5463ee47feac02048101ec9a032025-01-06T09:23:11ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902025-01-0181161010.1107/S2056989024011642tx2091Crystal structure of p-xylene@silicalite-1In-Chul Hwang0School of Chemical and Biological Engineering, Seoul National University, 1, Gwanak-ro, Gwanak-gu, Seoul 08826, South KoreaThe crystal structure of a highly loaded complex of silicalite-1 (SL-1) with eight molecules of p-xylene per unit cell has been solved by single-crystal X-ray diffraction. In the crystal, four symmetrical Si24O48·2C8H10 subunits per unit cell are observed. The p-xylene molecules sit at two different positions within the SL-1 channels. The first molecule is located at the intersection of the sinusoidal and straight channels, while the second guest molecule is positioned in the center of the double ten-membered ring (10-MR) of the sinusoidal channel.https://journals.iucr.org/paper?S2056989024011642silicalite-1p-xylenezeolitecrystal structure |
| spellingShingle | In-Chul Hwang Crystal structure of p-xylene@silicalite-1 Acta Crystallographica Section E: Crystallographic Communications silicalite-1 p-xylene zeolite crystal structure |
| title | Crystal structure of p-xylene@silicalite-1 |
| title_full | Crystal structure of p-xylene@silicalite-1 |
| title_fullStr | Crystal structure of p-xylene@silicalite-1 |
| title_full_unstemmed | Crystal structure of p-xylene@silicalite-1 |
| title_short | Crystal structure of p-xylene@silicalite-1 |
| title_sort | crystal structure of p xylene silicalite 1 |
| topic | silicalite-1 p-xylene zeolite crystal structure |
| url | https://journals.iucr.org/paper?S2056989024011642 |
| work_keys_str_mv | AT inchulhwang crystalstructureofpxylenesilicalite1 |