The influence of composition of binary solvent CH<sub>3</sub>CN-H<sub>2</sub>O on the kinetics of oxidation of cyclohexene by p-BENZOQUINONES in solutions of cationic palladium(II) complexes

The influence of composition of binary solvent CH<sub>3</sub>CN-H<sub>2</sub>O on the kinetics of oxidation of cyclohexene by p-BENZOQUINONES in solutions of cationic palladium(II) complexes

During the study of cyclohexene oxidation by p-benzoquinones into cyclohexanone in water-organic solutions of cationic complexes of palladium(II) it was demonstrated that the initial reaction rate R0 depends complicatedly on water molar fraction for three studied solvents: acetonitrile (AN), dimethy...

Full description

Saved in:

Bibliographic Details
Main Authors:	D. S. Zakharova, A. N. Semenyako, O. A. Chertkova, A. V. Frolkova, E. A. Katsman, L. G. Bruk, O. N. Temkin
Format:	Article
Language:	Russian
Published:	MIREA - Russian Technological University 2015-06-01
Series:	Тонкие химические технологии
Subjects:	cyclohexene oxidation, cyclohexanone, palladium complexes, acetonitrile, phase equilibrium.
Online Access:	https://www.finechem-mirea.ru/jour/article/view/240
Tags:	Add Tag No Tags, Be the first to tag this record!

Similar Items

Epoxidation of cyclohexene with cyclohexyl hydroperoxide
by: E. A. Kurganova, et al.
Published: (2024-01-01)

CATIONIC PD(II) COMPLEXES CATALYTICALLY ACTIVE IN THE OXIDATION OF OLEFINS : MECHANISMS OF THE FORMATION IN WATER -ACETONITRILE -CHLORIC ACID MEDIUM
by: D. S. Zakharova, et al.
Published: (2016-04-01)

The conjugated process of carbon monoxide oxidation and cyclohexene hydrocarboxylation to cyclohexanecarboxylic acid
by: E. A. Timashova, et al.
Published: (2014-06-01)

The state of palladium and copper on the surface of freshly prepared low temperature carbon monoxide oxidadation catalyst PdCl<sub>2</sub>-CuCl<sub>2/γ</sub>-Al<sub>2</sub>O<sub>3</sub>
by: D. N. Titov, et al.
Published: (2010-06-01)

Synthesis of nanoparticles of Y(OH)CO<sub>3</sub> and Y<sub>2</sub>O<sub>3</sub> using liquid interfaces and modification of their surface by palladium
by: E. A. Mischihina, et al.
Published: (2011-12-01)

Tuning the Activity of NbOPO<sub>4</sub> with NiO for the Selective Conversion of Cyclohexanone as a Model Intermediate of Lignin Pyrolysis Bio-Oils
by: Abarasi Hart, et al.
Published: (2025-08-01)

Methods of synthesis of metallaboranes with polyhedral cage [MB<sub>9</sub>H<sub>9</sub>], M=Ni, Pd
by: A. Yu. Bykov, et al.
Published: (2012-12-01)

Catalytic performance of organically templated nano nickel incorporated-rice husk silica in hydroconversion of cyclohexene and dehydrogenation of ethanol
by: Salah A. Hassan, et al.
Published: (2013-06-01)

Kinetics characteristics of dissolving PdCl<sub>2</sub> in water-chlorid solutions
by: A. V. Krylov, et al.
Published: (2014-12-01)

Linear free energy relationships in theoretical NMR <sup>13</sup>С spectra of sin-[(1-R-η<sup>3</sup> -C<sub>3</sub>H<sub>4</sub>)Pd(Me<sub>2</sub>C=O)<sub>2</sub>]<sup>+</sup> complexes
by: M. H. Elhussien, et al.
Published: (2010-06-01)

Calibration of hydroxyacetonitrile (HOCH<sub>2</sub>CN) and methyl isocyanate (CH<sub>3</sub>NCO) isomers using I<sup>−</sup> chemical ionization mass spectrometry (CIMS)
by: Z. Finewax, et al.
Published: (2024-12-01)

Investigation of the geometry and electronic structure of endohedral complexes Pd<sub>n</sub>@C<sub>60</sub>, n=1,…,4, by quantum chemistry methods
by: G. E. Gal’pern, et al.
Published: (2011-12-01)

Hybrid Materials—Mg<sub>3</sub>Al-LDH/Ionic Liquids/Chitosan Used in the Recovery Process of Pd Ions from Aqueous Solutions
by: Emilia Milos, et al.
Published: (2024-12-01)

Palladium iodide catalyzed oxidative carbonylations
by: Bartolo Gabriele
Published: (2024-12-01)

HOF•CH<sub>3</sub>CN—The Most Potent Oxygen Transfer Agent for a Large Variety of Organic Molecules
by: Shlomo Rozen
Published: (2025-03-01)

Ionization of CF<sub>3</sub>CH<sub>2</sub>F by Protons and Photons
by: Carlos E. Ferreira, et al.
Published: (2025-06-01)

Advances in Group-10 Transition Metal Dichalcogenide PdSe<sub>2</sub>-Based Photodetectors: Outlook and Perspectives
by: Tawsif Ibne Alam, et al.
Published: (2024-09-01)

Analysis of Biomolecular Changes in HeLa Cervical Cancer Cell Line Induced by Interaction with [Pd(dach)Cl<sub>2</sub>]
by: Vanja Ralić, et al.
Published: (2025-01-01)

Non-empirical calculations of minimal energetic ways of addition of H<sub>2</sub>F<sub>2</sub> and H<sub>2</sub>Cl<sub>2</sub> molecules to acetylene and methylacetylene molecules
by: Yu. B. Kirillov, et al.
Published: (2012-12-01)

Interaction of the anion [2-B<sub>10</sub>H<sub>9</sub>O(CH<sub>2</sub>)<sub>4</sub>O]− with secondary amines
by: E. Yu. Matveev, et al.
Published: (2022-11-01)

Friction and Wear Properties of MoCN, MoCN+MoS<sub>2</sub> and MoCN+CFilms in Wide Temperature Range
by: BAO Bi-xia, QIAN Jian-guo, LI Shu-xin, PU Ji-bin, MAO Chun-long, MAO Jin-gen, CHEN Shan-jun
Published: (2021-08-01)

Synthesis, Structural Characterization, and Hydrogen Release of Al-Based Amidoboranes Derived from MAlH<sub>4</sub> (Li, Na)-BH<sub>3</sub>NH<sub>2</sub>CH<sub>2</sub>CH<sub>2</sub>NH<sub>2</sub>BH<sub>3</sub>
by: Ting Zhang, et al.
Published: (2025-03-01)

An Organic–Inorganic Hybrid Semiconducting Quantum Spin Liquid Candidate: (BEDT-TTF)<sub>3</sub>[Cu<sub>2</sub>(μ-C<sub>2</sub>O<sub>4</sub>)<sub>3</sub>·CH<sub>3</sub>CH<sub>2</sub>OH·1.2H<sub>2</sub>O]
by: Bin Zhang, et al.
Published: (2025-02-01)

Diffusion of N<sub>2</sub>/CH<sub>4</sub>/CO<sub>2</sub> in Heptane-Containing Nanoblind Ends
by: Yiran Wang, et al.
Published: (2024-10-01)

Impact of Pore Structure and Hydrate Distribution on CO<sub>2</sub>-CH<sub>4</sub> Replacement in CH<sub>4</sub> Hydrate: A Pore-Scale Numerical Analysis
by: Yingfei Wang, et al.
Published: (2025-05-01)

Eddy-covariance fluxes of CO<sub>2</sub>, CH<sub>4</sub> and N<sub>2</sub>O in a drained peatland forest after clear-cutting
by: O.-P. Tikkasalo, et al.
Published: (2025-03-01)

Temperature Dependence of H<sub>2</sub>/Air and CH<sub>4</sub>/Air Deflagrations
by: Rafał Porowski, et al.
Published: (2025-07-01)

Effect of K<sub>3</sub>[Fe(CN)<sub>6</sub>] Concentration on the Structure and DegradationPerformance of Sulfur - Modified Fe<sub>3</sub>O<sub>4</sub> Coating Prepared by PEO
by: ZHOU Yang, ZHANG Xiao, XIA Qi-xing, CHEN Chang-ju, YAO Zhong-ping
Published: (2021-08-01)

Features of calculation of material balance of rectification complex with florentine vessel
by: A. V. Frolkova, et al.
Published: (2015-08-01)

Effect of Stabilizer on Electroless Palladium Plating on Circuit Boards
by: ZHAO Chao, LIU Guang-ming, WEN Ming-li, YANG Yi-hua, CHEN Wei, PENG Xiao-ying, TIAN Ji-hong
Published: (2021-08-01)

Evaluation of APTES-Functionalized Zinc Oxide Nanoparticles for Adsorption of CH<sub>4</sub> and CO<sub>2</sub>
by: Luis A. Montejo-Mesa, et al.
Published: (2024-11-01)

CH<sub>3</sub>OH<sup>•+</sup> + CH<sub>4</sub> Reaction: Mechanistic Insights and Reaction Rates for Astrochemical and Atmospheric Environments
by: Mauro Satta, et al.
Published: (2025-02-01)

Investigate the Performance of Prussian White K<sub>2</sub>Fe[Fe(CN)<sub>6</sub>] Cathode for Potassium-Ion Battery
by: Van Hoang Luan, et al.
Published: (2025-05-01)

Unveiling Electrochemical Frontiers: Enhanced Hydrazine Sensing with Na<sub>3</sub>[Fe(CN)<sub>5</sub>(PZT)] Modified Electrodes
by: Kalil Cristhian Figueiredo Toledo, et al.
Published: (2025-03-01)

UAV-based in situ measurements of CO<sub>2</sub> and CH<sub>4</sub> fluxes over complex natural ecosystems
by: A. Bolek, et al.
Published: (2024-09-01)

QEPAS Sensor for Simultaneous Measurements of H<sub>2</sub>O, CH<sub>4</sub>, and C<sub>2</sub>H<sub>2 </sub> Using Different QTFs
by: Qinduan Zhang, et al.
Published: (2018-01-01)

Global CH<sub>4</sub> fluxes derived from JAXA/GOSAT lower-tropospheric partial column data and the CarbonTracker Europe-CH<sub>4</sub> atmospheric inverse model
by: A. Tsuruta, et al.
Published: (2025-07-01)

Positive and Negative Exchange Bias in <i>N</i>-, <i>P</i>- and <i>Q</i>-Type Ferri-Magnets of Niccolite Metal Formates [CH<sub>3</sub>NH<sub>2</sub>CH<sub>3</sub>]<sub>n</sub>[Cr<sup>III</sup><sub>1−x</sub>Fe<sup>III</sup><sub>x</sub>Fe<sup>II</sup>(HCO<sub>2</sub>)<sub>6</sub>]<sub>n</sub>
by: Yu Zhou, et al.
Published: (2025-02-01)

Tracing elevated abundance of CH<sub>2</sub>Cl<sub>2</sub> in the subarctic upper troposphere to the Asian Summer Monsoon
by: M. Jesswein, et al.
Published: (2025-07-01)

Investigation of increasing the recovery rate of refi palladium powder from waste solutions
by: A. S. Khasanov, et al.
Published: (2020-04-01)