Recent developments in carbon‐based electrodes surface modification for zinc bromine flow battery

Abstract Zinc‐bromine flow batteries (ZBFBs) hold promise as energy storage systems for facilitating the efficient utilisation of renewable energy due to their low cost, high energy density, safety features, and long cycle life. However, challenges such as uneven zinc deposition leading to zinc dend...

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Main Authors: Yanhong Li, Xiaoyun Sun, Lin Meng, Xingxing Wang, Boxue Ouyang, Deren Wang, Chenyu Zhao, Haochen Hu
Format: Article
Language:English
Published: Wiley 2024-12-01
Series:IET Energy Systems Integration
Subjects:
Online Access:https://doi.org/10.1049/esi2.12161
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author Yanhong Li
Xiaoyun Sun
Lin Meng
Xingxing Wang
Boxue Ouyang
Deren Wang
Chenyu Zhao
Haochen Hu
author_facet Yanhong Li
Xiaoyun Sun
Lin Meng
Xingxing Wang
Boxue Ouyang
Deren Wang
Chenyu Zhao
Haochen Hu
author_sort Yanhong Li
collection DOAJ
description Abstract Zinc‐bromine flow batteries (ZBFBs) hold promise as energy storage systems for facilitating the efficient utilisation of renewable energy due to their low cost, high energy density, safety features, and long cycle life. However, challenges such as uneven zinc deposition leading to zinc dendrite formation on the negative electrode and parasitic hydrogen evolution reaction during charging pose risks of membrane puncturing and short circuits, thereby limiting energy density improvements. Additionally, the sluggish and non‐reversible Br2/Br− redox reaction hampers battery power density enhancements. Given that electrode properties significantly influence the rate and reversibility of these redox reactions, modifications to the negative and positive electrodes are crucial. While inert carbon‐based electrodes are favoured for their corrosion resistance and conductivity, their hydrophobic nature and low electrochemical activity restrain the performance of ZBFBs. The authors present a comprehensive review of recent advancements in both negative and positive electrode modifications in ZBFBs. It also puts forward future research directions aimed at overcoming existing challenges, with the ultimate objective of promoting the efficient utilisation of ZBFBs.
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publisher Wiley
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series IET Energy Systems Integration
spelling doaj-art-8c54441358f7457d91726c435de302d52025-01-29T05:18:54ZengWileyIET Energy Systems Integration2516-84012024-12-016S166868310.1049/esi2.12161Recent developments in carbon‐based electrodes surface modification for zinc bromine flow batteryYanhong Li0Xiaoyun Sun1Lin Meng2Xingxing Wang3Boxue Ouyang4Deren Wang5Chenyu Zhao6Haochen Hu7China Huadian Engineering Co., Ltd. Beijing ChinaInstitute for Advanced Materials and Technology University of Science and Technology Beijing ChinaJiangsu Heng'an Energy Storage Technology Co., Ltd. Beijing ChinaChina Huadian Engineering Co., Ltd. Beijing ChinaChina Huadian Engineering Co., Ltd. Beijing ChinaInstitute for Advanced Materials and Technology University of Science and Technology Beijing ChinaChina Huadian Engineering Co., Ltd. Beijing ChinaInstitute for Advanced Materials and Technology University of Science and Technology Beijing ChinaAbstract Zinc‐bromine flow batteries (ZBFBs) hold promise as energy storage systems for facilitating the efficient utilisation of renewable energy due to their low cost, high energy density, safety features, and long cycle life. However, challenges such as uneven zinc deposition leading to zinc dendrite formation on the negative electrode and parasitic hydrogen evolution reaction during charging pose risks of membrane puncturing and short circuits, thereby limiting energy density improvements. Additionally, the sluggish and non‐reversible Br2/Br− redox reaction hampers battery power density enhancements. Given that electrode properties significantly influence the rate and reversibility of these redox reactions, modifications to the negative and positive electrodes are crucial. While inert carbon‐based electrodes are favoured for their corrosion resistance and conductivity, their hydrophobic nature and low electrochemical activity restrain the performance of ZBFBs. The authors present a comprehensive review of recent advancements in both negative and positive electrode modifications in ZBFBs. It also puts forward future research directions aimed at overcoming existing challenges, with the ultimate objective of promoting the efficient utilisation of ZBFBs.https://doi.org/10.1049/esi2.12161energy management systemssmart power grids
spellingShingle Yanhong Li
Xiaoyun Sun
Lin Meng
Xingxing Wang
Boxue Ouyang
Deren Wang
Chenyu Zhao
Haochen Hu
Recent developments in carbon‐based electrodes surface modification for zinc bromine flow battery
IET Energy Systems Integration
energy management systems
smart power grids
title Recent developments in carbon‐based electrodes surface modification for zinc bromine flow battery
title_full Recent developments in carbon‐based electrodes surface modification for zinc bromine flow battery
title_fullStr Recent developments in carbon‐based electrodes surface modification for zinc bromine flow battery
title_full_unstemmed Recent developments in carbon‐based electrodes surface modification for zinc bromine flow battery
title_short Recent developments in carbon‐based electrodes surface modification for zinc bromine flow battery
title_sort recent developments in carbon based electrodes surface modification for zinc bromine flow battery
topic energy management systems
smart power grids
url https://doi.org/10.1049/esi2.12161
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