Gas-phase observations of accretion products from stabilized Criegee intermediates in terpene ozonolysis with two dicarboxylic acids
<p>Criegee intermediates (CIs), formed from the ozonolysis of alkenes, are highly reactive species with diverse reaction pathways, with important roles in atmospheric chemistry. This study focuses on the formation of accretion products through reactions of thermally stabilized CIs (sCIs) from...
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Copernicus Publications
2025-05-01
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| Series: | Atmospheric Chemistry and Physics |
| Online Access: | https://acp.copernicus.org/articles/25/4655/2025/acp-25-4655-2025.pdf |
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| author | Y. Luo L. Franzon J. Zhang N. Sarnela N. M. Donahue T. Kurtén M. Ehn |
| author_facet | Y. Luo L. Franzon J. Zhang N. Sarnela N. M. Donahue T. Kurtén M. Ehn |
| author_sort | Y. Luo |
| collection | DOAJ |
| description | <p>Criegee intermediates (CIs), formed from the ozonolysis of alkenes, are highly reactive species with diverse reaction pathways, with important roles in atmospheric chemistry. This study focuses on the formation of accretion products through reactions of thermally stabilized CIs (sCIs) from the ozonolysis of three different terpenes (<span class="inline-formula"><i>α</i></span>-pinene, <span class="inline-formula"><i>β</i></span>-pinene, and <span class="inline-formula"><i>β</i></span>-caryophyllene) with malonic and oxalic acids. Our experimental results demonstrate that these reactions efficiently produce the expected accretion products, though with apparent variations in yields depending on the specific terpene and acid involved. To our knowledge, this is the first study to report direct gas-phase observations of expected adducts from several different terpene-derived sCIs and carboxylic acids, paving the way for a better understanding of the importance and atmospheric implications of these reactions, especially in terms of the aerosol-forming capabilities of these large product molecules.</p> |
| format | Article |
| id | doaj-art-8c2a18d67c86485fbea6d07efd47d428 |
| institution | OA Journals |
| issn | 1680-7316 1680-7324 |
| language | English |
| publishDate | 2025-05-01 |
| publisher | Copernicus Publications |
| record_format | Article |
| series | Atmospheric Chemistry and Physics |
| spelling | doaj-art-8c2a18d67c86485fbea6d07efd47d4282025-08-20T02:10:38ZengCopernicus PublicationsAtmospheric Chemistry and Physics1680-73161680-73242025-05-01254655466410.5194/acp-25-4655-2025Gas-phase observations of accretion products from stabilized Criegee intermediates in terpene ozonolysis with two dicarboxylic acidsY. Luo0L. Franzon1J. Zhang2N. Sarnela3N. M. Donahue4T. Kurtén5M. Ehn6Institute for Atmospheric and Earth System Research (INAR), University of Helsinki, Helsinki, 00014, FinlandDepartment of Chemistry, University of Helsinki, Helsinki, 00014, FinlandInstitute for Atmospheric and Earth System Research (INAR), University of Helsinki, Helsinki, 00014, FinlandInstitute for Atmospheric and Earth System Research (INAR), University of Helsinki, Helsinki, 00014, FinlandCenter for Atmospheric Particle Studies, Carnegie Mellon University, Pittsburgh, Pennsylvania 15213, United StatesDepartment of Chemistry, University of Helsinki, Helsinki, 00014, FinlandInstitute for Atmospheric and Earth System Research (INAR), University of Helsinki, Helsinki, 00014, Finland<p>Criegee intermediates (CIs), formed from the ozonolysis of alkenes, are highly reactive species with diverse reaction pathways, with important roles in atmospheric chemistry. This study focuses on the formation of accretion products through reactions of thermally stabilized CIs (sCIs) from the ozonolysis of three different terpenes (<span class="inline-formula"><i>α</i></span>-pinene, <span class="inline-formula"><i>β</i></span>-pinene, and <span class="inline-formula"><i>β</i></span>-caryophyllene) with malonic and oxalic acids. Our experimental results demonstrate that these reactions efficiently produce the expected accretion products, though with apparent variations in yields depending on the specific terpene and acid involved. To our knowledge, this is the first study to report direct gas-phase observations of expected adducts from several different terpene-derived sCIs and carboxylic acids, paving the way for a better understanding of the importance and atmospheric implications of these reactions, especially in terms of the aerosol-forming capabilities of these large product molecules.</p>https://acp.copernicus.org/articles/25/4655/2025/acp-25-4655-2025.pdf |
| spellingShingle | Y. Luo L. Franzon J. Zhang N. Sarnela N. M. Donahue T. Kurtén M. Ehn Gas-phase observations of accretion products from stabilized Criegee intermediates in terpene ozonolysis with two dicarboxylic acids Atmospheric Chemistry and Physics |
| title | Gas-phase observations of accretion products from stabilized Criegee intermediates in terpene ozonolysis with two dicarboxylic acids |
| title_full | Gas-phase observations of accretion products from stabilized Criegee intermediates in terpene ozonolysis with two dicarboxylic acids |
| title_fullStr | Gas-phase observations of accretion products from stabilized Criegee intermediates in terpene ozonolysis with two dicarboxylic acids |
| title_full_unstemmed | Gas-phase observations of accretion products from stabilized Criegee intermediates in terpene ozonolysis with two dicarboxylic acids |
| title_short | Gas-phase observations of accretion products from stabilized Criegee intermediates in terpene ozonolysis with two dicarboxylic acids |
| title_sort | gas phase observations of accretion products from stabilized criegee intermediates in terpene ozonolysis with two dicarboxylic acids |
| url | https://acp.copernicus.org/articles/25/4655/2025/acp-25-4655-2025.pdf |
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