Rediscovering selectively etched single-walled TiO2 nanotubes: a review to reignite interest

Since the emergence of anodic TiO2 nanotubes in the early 1980s, extensive efforts have been devoted to understanding their structure, formation mechanisms, and applications, particularly the widely investigated double-walled structures, which have found utility across various photoelectrochemical a...

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Main Authors: Yilan Zeng, Martin Motola
Format: Article
Language:English
Published: Elsevier 2025-05-01
Series:Chemical Engineering Journal Advances
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2666821125000493
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author Yilan Zeng
Martin Motola
author_facet Yilan Zeng
Martin Motola
author_sort Yilan Zeng
collection DOAJ
description Since the emergence of anodic TiO2 nanotubes in the early 1980s, extensive efforts have been devoted to understanding their structure, formation mechanisms, and applications, particularly the widely investigated double-walled structures, which have found utility across various photoelectrochemical and catalytic domains. However, a specific derivative known as selectively etched single-walled TiO2 nanotubes (SE SW-TNTs) remains relatively underexplored, despite their superior inner wall accessibility, unique morphology, and photoelectrochemical capabilities. These properties make SE SW-TNTs highly promising for applications in photocatalysis, energy conversion and electrochemical devices. This review aims to revisit the significance of SE SW-TNTs, outlining the strategies for their preparation, comparing their physicochemical features with double-walled counterparts, and critically discussing the progress and limitations of their functional implementation. By compiling and analysing recent advances, we hope to shed light on this overlooked nanostructure and provide guidance for future development in this field.
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spelling doaj-art-8bf3ef1eb5904b49b474ac6632972bc22025-08-20T03:08:32ZengElsevierChemical Engineering Journal Advances2666-82112025-05-012210075210.1016/j.ceja.2025.100752Rediscovering selectively etched single-walled TiO2 nanotubes: a review to reignite interestYilan Zeng0Martin Motola1Department of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University Bratislava, Mlynska Dolina, Ilkovicova 6, 842 15 Bratislava, Slovakia; Department of Environmental Ecology and Landscape Management, Faculty of Natural Sciences, Comenius University Bratislava, Mlynska Dolina, Ilkovicova 6, 842 15 Bratislava, SlovakiaDepartment of Inorganic Chemistry, Faculty of Natural Sciences, Comenius University Bratislava, Mlynska Dolina, Ilkovicova 6, 842 15 Bratislava, Slovakia; Center for Nanotechnology and Advanced Materials, Faculty of Mathematics, Physics and Informatics, Comenius University Bratislava, Mlynska Dolina, 842 48 Bratislava, Slovakia; Corresponding author.Since the emergence of anodic TiO2 nanotubes in the early 1980s, extensive efforts have been devoted to understanding their structure, formation mechanisms, and applications, particularly the widely investigated double-walled structures, which have found utility across various photoelectrochemical and catalytic domains. However, a specific derivative known as selectively etched single-walled TiO2 nanotubes (SE SW-TNTs) remains relatively underexplored, despite their superior inner wall accessibility, unique morphology, and photoelectrochemical capabilities. These properties make SE SW-TNTs highly promising for applications in photocatalysis, energy conversion and electrochemical devices. This review aims to revisit the significance of SE SW-TNTs, outlining the strategies for their preparation, comparing their physicochemical features with double-walled counterparts, and critically discussing the progress and limitations of their functional implementation. By compiling and analysing recent advances, we hope to shed light on this overlooked nanostructure and provide guidance for future development in this field.http://www.sciencedirect.com/science/article/pii/S2666821125000493Electrochemical anodic oxidationTiO2 nanotube layersDouble-walledSingle-walledInner shellOuter shell
spellingShingle Yilan Zeng
Martin Motola
Rediscovering selectively etched single-walled TiO2 nanotubes: a review to reignite interest
Chemical Engineering Journal Advances
Electrochemical anodic oxidation
TiO2 nanotube layers
Double-walled
Single-walled
Inner shell
Outer shell
title Rediscovering selectively etched single-walled TiO2 nanotubes: a review to reignite interest
title_full Rediscovering selectively etched single-walled TiO2 nanotubes: a review to reignite interest
title_fullStr Rediscovering selectively etched single-walled TiO2 nanotubes: a review to reignite interest
title_full_unstemmed Rediscovering selectively etched single-walled TiO2 nanotubes: a review to reignite interest
title_short Rediscovering selectively etched single-walled TiO2 nanotubes: a review to reignite interest
title_sort rediscovering selectively etched single walled tio2 nanotubes a review to reignite interest
topic Electrochemical anodic oxidation
TiO2 nanotube layers
Double-walled
Single-walled
Inner shell
Outer shell
url http://www.sciencedirect.com/science/article/pii/S2666821125000493
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