ELLIPSOMETRY, RAMAN SPECTROSCOPY AND SOI- NANOWIRE BIOSENSOR IN DIAGNOSIS OF COLORECTALCANCER

Differences in the rate constants of specific interactions between serum tumor M2-pyruvate kinase (Tumor M2-PK) and highly specific monoclonal antibodies deposited on the surface of biochips were found in colorectal cancer patients using surface plasmon resonance enhanced ellipsometry. Scanning elli...

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Main Authors: M. V. Kruchinina, Ya. I. Prudnikova, S. A. Kurilovich, A. A. Gromov, V. N. Kruchinin, V. V. Atuchin, O. V. Naumova, E. V. Spesivtsev, V. A. Volodin, S. E. Peltek, G. V. Shuvalov, V. M. Generalov
Format: Article
Language:Russian
Published: Russian Academy of Sciences, Tomsk National Research Medical Center 2017-09-01
Series:Сибирский онкологический журнал
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Online Access:https://www.siboncoj.ru/jour/article/view/568
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author M. V. Kruchinina
Ya. I. Prudnikova
S. A. Kurilovich
A. A. Gromov
V. N. Kruchinin
V. V. Atuchin
O. V. Naumova
E. V. Spesivtsev
V. A. Volodin
S. E. Peltek
G. V. Shuvalov
V. M. Generalov
author_facet M. V. Kruchinina
Ya. I. Prudnikova
S. A. Kurilovich
A. A. Gromov
V. N. Kruchinin
V. V. Atuchin
O. V. Naumova
E. V. Spesivtsev
V. A. Volodin
S. E. Peltek
G. V. Shuvalov
V. M. Generalov
author_sort M. V. Kruchinina
collection DOAJ
description Differences in the rate constants of specific interactions between serum tumor M2-pyruvate kinase (Tumor M2-PK) and highly specific monoclonal antibodies deposited on the surface of biochips were found in colorectal cancer patients using surface plasmon resonance enhanced ellipsometry. Scanning ellipsometry revealed a significant increase in the biomolecular layer thickness caused by antigen-antibody reaction in patients with hepatic and extra-hepatic metastases compared to that in healthy subjects (p<0.001–0.042).The specificity of the interaction was confirmed by fluorescence optical spectrometry. The Raman spectra of serum samples revealed differences in the intensity of peaks appeared at 1005–1520 cm-1 in the same groups of patients (p<0.0001–0.05) with a predictive accuracy of 90 % for early-stage disease. The pilot experiments with a nanowire biosensor based on SOI (silicon on insulator), for example Tumor M2-PK, were carried out. High sensitivity (10-13–10-15M) and specificity in identifying antigens in serum samples of patients with colorectal cancer were demonstrated. The results obtained were useful for detecting early-stage disease, metastases and recurrence as well as for monitoring the quality of treatment in colorectal cancer patients.
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spelling doaj-art-8bd755f18fc4497c8605a0135f340e4a2025-08-20T03:56:24ZrusRussian Academy of Sciences, Tomsk National Research Medical CenterСибирский онкологический журнал1814-48612312-31682017-09-01164324110.21294/1814-4861-2017-16-4-32-41466ELLIPSOMETRY, RAMAN SPECTROSCOPY AND SOI- NANOWIRE BIOSENSOR IN DIAGNOSIS OF COLORECTALCANCERM. V. Kruchinina0Ya. I. Prudnikova1S. A. Kurilovich2A. A. Gromov3V. N. Kruchinin4V. V. Atuchin5O. V. Naumova6E. V. Spesivtsev7V. A. Volodin8S. E. Peltek9G. V. Shuvalov10V. M. Generalov11Research Institute of Internal and Preventive Medicine ‑ Branch of the Institute of Cytology and Genetics; Siberian Scientific Research Institute for Metrology, ROSSTANDART.Research Institute of Internal and Preventive Medicine ‑ Branch of the Institute of Cytology and Genetics.Research Institute of Internal and Preventive Medicine ‑ Branch of the Institute of Cytology and Genetics.Research Institute of Internal and Preventive Medicine ‑ Branch of the Institute of Cytology and Genetics.Rzhanov Institute of Semiconductor Physics, SB RAS.Rzhanov Institute of Semiconductor Physics, SB RAS; Novosibirsk State University, Novosibirsk.Rzhanov Institute of Semiconductor Physics, SB RAS.Rzhanov Institute of Semiconductor Physics, SB RAS.Rzhanov Institute of Semiconductor Physics, SB RAS.Institute of Cytology and Genetics, SB RAS.Siberian Scientific Research Institute for Metrology, ROSSTANDART.State Research Center of Virology and Biotechnology «VECTOR».Differences in the rate constants of specific interactions between serum tumor M2-pyruvate kinase (Tumor M2-PK) and highly specific monoclonal antibodies deposited on the surface of biochips were found in colorectal cancer patients using surface plasmon resonance enhanced ellipsometry. Scanning ellipsometry revealed a significant increase in the biomolecular layer thickness caused by antigen-antibody reaction in patients with hepatic and extra-hepatic metastases compared to that in healthy subjects (p<0.001–0.042).The specificity of the interaction was confirmed by fluorescence optical spectrometry. The Raman spectra of serum samples revealed differences in the intensity of peaks appeared at 1005–1520 cm-1 in the same groups of patients (p<0.0001–0.05) with a predictive accuracy of 90 % for early-stage disease. The pilot experiments with a nanowire biosensor based on SOI (silicon on insulator), for example Tumor M2-PK, were carried out. High sensitivity (10-13–10-15M) and specificity in identifying antigens in serum samples of patients with colorectal cancer were demonstrated. The results obtained were useful for detecting early-stage disease, metastases and recurrence as well as for monitoring the quality of treatment in colorectal cancer patients.https://www.siboncoj.ru/jour/article/view/568diagnosiscolorectal cancerellipsometrysurface plasmon resonancefluorescence optical spectrometryraman spectroscopysoi nanowire biosensortumor m2 pyruvate kinase
spellingShingle M. V. Kruchinina
Ya. I. Prudnikova
S. A. Kurilovich
A. A. Gromov
V. N. Kruchinin
V. V. Atuchin
O. V. Naumova
E. V. Spesivtsev
V. A. Volodin
S. E. Peltek
G. V. Shuvalov
V. M. Generalov
ELLIPSOMETRY, RAMAN SPECTROSCOPY AND SOI- NANOWIRE BIOSENSOR IN DIAGNOSIS OF COLORECTALCANCER
Сибирский онкологический журнал
diagnosis
colorectal cancer
ellipsometry
surface plasmon resonance
fluorescence optical spectrometry
raman spectroscopy
soi nanowire biosensor
tumor m2 pyruvate kinase
title ELLIPSOMETRY, RAMAN SPECTROSCOPY AND SOI- NANOWIRE BIOSENSOR IN DIAGNOSIS OF COLORECTALCANCER
title_full ELLIPSOMETRY, RAMAN SPECTROSCOPY AND SOI- NANOWIRE BIOSENSOR IN DIAGNOSIS OF COLORECTALCANCER
title_fullStr ELLIPSOMETRY, RAMAN SPECTROSCOPY AND SOI- NANOWIRE BIOSENSOR IN DIAGNOSIS OF COLORECTALCANCER
title_full_unstemmed ELLIPSOMETRY, RAMAN SPECTROSCOPY AND SOI- NANOWIRE BIOSENSOR IN DIAGNOSIS OF COLORECTALCANCER
title_short ELLIPSOMETRY, RAMAN SPECTROSCOPY AND SOI- NANOWIRE BIOSENSOR IN DIAGNOSIS OF COLORECTALCANCER
title_sort ellipsometry raman spectroscopy and soi nanowire biosensor in diagnosis of colorectalcancer
topic diagnosis
colorectal cancer
ellipsometry
surface plasmon resonance
fluorescence optical spectrometry
raman spectroscopy
soi nanowire biosensor
tumor m2 pyruvate kinase
url https://www.siboncoj.ru/jour/article/view/568
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