KINETICS OF THE HYDROLYSIS OF CASSAVA STARCH BY GLUCOAMYLASE AND A GRANULAR STARCH HYDROLYZING ENZYME

Kinetic studies of the enzymatic hydrolysis of cassava starch have been carried out using glucoamylase and granular starch hydrolyzing enzyme (GSHE) as StargenTM 002. The enzymatic hydrolysis of cassava starch was conducted at pH 4 by employing slurry concentrations of 25-300 g·L-1, temperatures 30-...

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Main Authors: HARGONO HARGONO, BAKTI JOS, ANDRI CAHYO KUMORO
Format: Article
Language:English
Published: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2018-12-01
Series:Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
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Online Access:http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201804&vol=4&aid=4799
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author HARGONO HARGONO
BAKTI JOS
ANDRI CAHYO KUMORO
author_facet HARGONO HARGONO
BAKTI JOS
ANDRI CAHYO KUMORO
author_sort HARGONO HARGONO
collection DOAJ
description Kinetic studies of the enzymatic hydrolysis of cassava starch have been carried out using glucoamylase and granular starch hydrolyzing enzyme (GSHE) as StargenTM 002. The enzymatic hydrolysis of cassava starch was conducted at pH 4 by employing slurry concentrations of 25-300 g·L-1, temperatures 30-60 C and 0.5-1.5 % (w/w) of enzymes glucoamylase and StargenTM 002. Higher temperatures accelerated the enzymatic reaction using glucoamylase, while the similar effect levelled of at 40 °C for hydrolysis using StargenTM 002. The cassava starch concentrations of 200 and 250 g‧L-1 were found as the critical substrate concentrations for lower (glucoamylase 0.5 and 1 %) and higher (glucoamylase 1.5 %) enzyme concentrations used, respectively. Based on the Lineweaver-Burk plot for cassava starch hydrolysis using glucoamylase, the maximum reaction rates, Vmax for 0.5, 1.0 and 1.5 % (w/w) glucoamylase were 3.55, 5.78 and 9 g‧L-1‧h-1, while the Michaelis-Menten constants, Km were 140.35, 140.75 and 152.10 g‧L-1. Accordingly, the maximum reaction rates, Vmax for 0.5, 1 and 1.5 % (w/w) of StargenTM 002 were 7.19, 11.6 and 18.18 g‧L-1‧h-1, respectively. While the Michaelis-Menten constants, Km obtained at those enzyme concentrations were respectively 160.86, 161.31 and 160.85 g‧L-1. It is an indication that the rate of starch hydrolysis using StargenTM 002 is faster than glucoamylase.
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publishDate 2018-12-01
publisher Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
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spelling doaj-art-8b19a9577eee415da78bdef55e0affa52025-08-20T02:11:18ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauScientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry1582-540X1582-540X2018-12-01194443454KINETICS OF THE HYDROLYSIS OF CASSAVA STARCH BY GLUCOAMYLASE AND A GRANULAR STARCH HYDROLYZING ENZYMEHARGONO HARGONO0 BAKTI JOS1ANDRI CAHYO KUMORO2Diponegoro University, Faculty of Engineering, Department of Chemical Engineering, Jl. Prof. H. Soedarto, S.H., Semarang 50275, Indonesia Diponegoro University, Faculty of Engineering, Department of Chemical Engineering, Jl. Prof. H. Soedarto, S.H., Semarang 50275, Indonesia Diponegoro University, Faculty of Engineering, Department of Chemical Engineering, Jl. Prof. H. Soedarto, S.H., Semarang 50275, Indonesia Kinetic studies of the enzymatic hydrolysis of cassava starch have been carried out using glucoamylase and granular starch hydrolyzing enzyme (GSHE) as StargenTM 002. The enzymatic hydrolysis of cassava starch was conducted at pH 4 by employing slurry concentrations of 25-300 g·L-1, temperatures 30-60 C and 0.5-1.5 % (w/w) of enzymes glucoamylase and StargenTM 002. Higher temperatures accelerated the enzymatic reaction using glucoamylase, while the similar effect levelled of at 40 °C for hydrolysis using StargenTM 002. The cassava starch concentrations of 200 and 250 g‧L-1 were found as the critical substrate concentrations for lower (glucoamylase 0.5 and 1 %) and higher (glucoamylase 1.5 %) enzyme concentrations used, respectively. Based on the Lineweaver-Burk plot for cassava starch hydrolysis using glucoamylase, the maximum reaction rates, Vmax for 0.5, 1.0 and 1.5 % (w/w) glucoamylase were 3.55, 5.78 and 9 g‧L-1‧h-1, while the Michaelis-Menten constants, Km were 140.35, 140.75 and 152.10 g‧L-1. Accordingly, the maximum reaction rates, Vmax for 0.5, 1 and 1.5 % (w/w) of StargenTM 002 were 7.19, 11.6 and 18.18 g‧L-1‧h-1, respectively. While the Michaelis-Menten constants, Km obtained at those enzyme concentrations were respectively 160.86, 161.31 and 160.85 g‧L-1. It is an indication that the rate of starch hydrolysis using StargenTM 002 is faster than glucoamylase.http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201804&vol=4&aid=4799cassavaenzyme kineticsglucoamylaseGSHEhydrolysis
spellingShingle HARGONO HARGONO
BAKTI JOS
ANDRI CAHYO KUMORO
KINETICS OF THE HYDROLYSIS OF CASSAVA STARCH BY GLUCOAMYLASE AND A GRANULAR STARCH HYDROLYZING ENZYME
Scientific Study & Research: Chemistry & Chemical Engineering, Biotechnology, Food Industry
cassava
enzyme kinetics
glucoamylase
GSHE
hydrolysis
title KINETICS OF THE HYDROLYSIS OF CASSAVA STARCH BY GLUCOAMYLASE AND A GRANULAR STARCH HYDROLYZING ENZYME
title_full KINETICS OF THE HYDROLYSIS OF CASSAVA STARCH BY GLUCOAMYLASE AND A GRANULAR STARCH HYDROLYZING ENZYME
title_fullStr KINETICS OF THE HYDROLYSIS OF CASSAVA STARCH BY GLUCOAMYLASE AND A GRANULAR STARCH HYDROLYZING ENZYME
title_full_unstemmed KINETICS OF THE HYDROLYSIS OF CASSAVA STARCH BY GLUCOAMYLASE AND A GRANULAR STARCH HYDROLYZING ENZYME
title_short KINETICS OF THE HYDROLYSIS OF CASSAVA STARCH BY GLUCOAMYLASE AND A GRANULAR STARCH HYDROLYZING ENZYME
title_sort kinetics of the hydrolysis of cassava starch by glucoamylase and a granular starch hydrolyzing enzyme
topic cassava
enzyme kinetics
glucoamylase
GSHE
hydrolysis
url http://pubs.ub.ro/?pg=revues&rev=cscc6&num=201804&vol=4&aid=4799
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