Structure and thermal stability of phosphorus-iodonium ylids

Structure and thermal stability of phosphorus-iodonium ylids

Hypervalent iodine(III) reagents have become indispensable tools in organic synthesis, but gaps remain in the functionalities they can transfer. In this study, a fundamental understanding of the thermal stability of phosphorus-iodonium ylids is obtained through X-ray diffraction, differential scanni...

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Bibliographic Details
Main Authors: Andrew Greener, Stephen P. Argent, Coby J. Clarke, Miriam L. O’Duill
Format: Article
Language:English
Published: Beilstein-Institut 2024-11-01
Series:Beilstein Journal of Organic Chemistry
Subjects:
hypervalent iodine
reagent development
structural analysis
thermal stability
thermogravimetric analysis
Online Access:https://doi.org/10.3762/bjoc.20.245
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Summary:Hypervalent iodine(III) reagents have become indispensable tools in organic synthesis, but gaps remain in the functionalities they can transfer. In this study, a fundamental understanding of the thermal stability of phosphorus-iodonium ylids is obtained through X-ray diffraction, differential scanning calorimetry (DSC) and thermogravimetric analysis (TGA). Insights into the structural factors affecting thermal stability and potential decomposition pathways will enable the future design and development of new reagents.
ISSN:1860-5397

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