Thermal Measurements on Polymeric Epoxy-Expandable Graphite Material

Combustion measurements, such as heat release rate, critical flux, time-to-ignition, ignition temperature, thermal inertia, and kinematics—activation energy as well as preexponential factor—on epoxy polymer (Prime™ 20LV) with expandable graphite (EG) inorganic filler of different weight percentage c...

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Main Authors: Joseph Asante, Fortunate Modiba, Bonex Mwakikunga
Format: Article
Language:English
Published: Wiley 2016-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2016/1792502
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author Joseph Asante
Fortunate Modiba
Bonex Mwakikunga
author_facet Joseph Asante
Fortunate Modiba
Bonex Mwakikunga
author_sort Joseph Asante
collection DOAJ
description Combustion measurements, such as heat release rate, critical flux, time-to-ignition, ignition temperature, thermal inertia, and kinematics—activation energy as well as preexponential factor—on epoxy polymer (Prime™ 20LV) with expandable graphite (EG) inorganic filler of different weight percentage composites, are conducted using the Dual Cone Calorimeter, the thermogravimetric analysis (TGA), and Linseis (Germany) THB100 Transient Hot Bridge thermal conductivity analyser. The results indicate that increasing the amount of EG in polymer composite leads to reduction in the critical flux, the time-to-ignition, the ignition temperature, the thermal inertia, the average thermal conductivity, and the activation energy (from 159.1 ± 2.3 to 145.9 ± 3.1 kJ/mol for neat epoxy to 3 wt.% EG-epoxy) of the composite samples. There is, however, an increase in the heat of gasification with increasing EG content.
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issn 1687-9422
1687-9430
language English
publishDate 2016-01-01
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series International Journal of Polymer Science
spelling doaj-art-8a9b683cca8c4f3d92f0f0626fbc89f72025-08-20T02:09:24ZengWileyInternational Journal of Polymer Science1687-94221687-94302016-01-01201610.1155/2016/17925021792502Thermal Measurements on Polymeric Epoxy-Expandable Graphite MaterialJoseph Asante0Fortunate Modiba1Bonex Mwakikunga2Department of Physics, Tshwane University of Technology, P.O. Box x680, Pretoria 0001, South AfricaDepartment of Physics, Tshwane University of Technology, P.O. Box x680, Pretoria 0001, South AfricaDST/CSIR National Centre for Nano-Structured Materials, Material Science and Manufacturing (MSM), Council for Scientific and Industrial Research, P.O. Box 395, Pretoria 0001, South AfricaCombustion measurements, such as heat release rate, critical flux, time-to-ignition, ignition temperature, thermal inertia, and kinematics—activation energy as well as preexponential factor—on epoxy polymer (Prime™ 20LV) with expandable graphite (EG) inorganic filler of different weight percentage composites, are conducted using the Dual Cone Calorimeter, the thermogravimetric analysis (TGA), and Linseis (Germany) THB100 Transient Hot Bridge thermal conductivity analyser. The results indicate that increasing the amount of EG in polymer composite leads to reduction in the critical flux, the time-to-ignition, the ignition temperature, the thermal inertia, the average thermal conductivity, and the activation energy (from 159.1 ± 2.3 to 145.9 ± 3.1 kJ/mol for neat epoxy to 3 wt.% EG-epoxy) of the composite samples. There is, however, an increase in the heat of gasification with increasing EG content.http://dx.doi.org/10.1155/2016/1792502
spellingShingle Joseph Asante
Fortunate Modiba
Bonex Mwakikunga
Thermal Measurements on Polymeric Epoxy-Expandable Graphite Material
International Journal of Polymer Science
title Thermal Measurements on Polymeric Epoxy-Expandable Graphite Material
title_full Thermal Measurements on Polymeric Epoxy-Expandable Graphite Material
title_fullStr Thermal Measurements on Polymeric Epoxy-Expandable Graphite Material
title_full_unstemmed Thermal Measurements on Polymeric Epoxy-Expandable Graphite Material
title_short Thermal Measurements on Polymeric Epoxy-Expandable Graphite Material
title_sort thermal measurements on polymeric epoxy expandable graphite material
url http://dx.doi.org/10.1155/2016/1792502
work_keys_str_mv AT josephasante thermalmeasurementsonpolymericepoxyexpandablegraphitematerial
AT fortunatemodiba thermalmeasurementsonpolymericepoxyexpandablegraphitematerial
AT bonexmwakikunga thermalmeasurementsonpolymericepoxyexpandablegraphitematerial