Effect of degassing on scaling in hypersaline system: Tuzla geothermal field, Turkey

Abstract A serious issue with geothermal power plants is the loss of production and decline in power plant efficiency. Scaling, also known as mineral precipitation, is one of the frequently-observed issue that causes this loss and decreasing efficiency. It is heavily observed in the production wells...

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Main Authors: Serhat Tonkul, Laurent André, Alper Baba, Mustafa M. Demir, Simona Regenspurg, Katrin Kieling
Format: Article
Language:English
Published: SpringerOpen 2025-01-01
Series:Geothermal Energy
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Online Access:https://doi.org/10.1186/s40517-024-00320-7
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author Serhat Tonkul
Laurent André
Alper Baba
Mustafa M. Demir
Simona Regenspurg
Katrin Kieling
author_facet Serhat Tonkul
Laurent André
Alper Baba
Mustafa M. Demir
Simona Regenspurg
Katrin Kieling
author_sort Serhat Tonkul
collection DOAJ
description Abstract A serious issue with geothermal power plants is the loss of production and decline in power plant efficiency. Scaling, also known as mineral precipitation, is one of the frequently-observed issue that causes this loss and decreasing efficiency. It is heavily observed in the production wells when the geothermal fluid rises from the depths due to a change in the fluid’s physical and chemical properties. Scaling issue in geothermal power plants result in significant output losses and lower plant effectiveness. In rare instances, it might even result in the power plant being shut down. The chemistry of the geothermal fluid, non-condensable gases, pH, temperature and pressure changes in the process from production to reinjection, power plant type and design, and sometimes the materials used can also play an active role in the scaling that will occur in a geothermal system. ICP–MS was used to evaluate the chemical properties of the fluids. On the other hand, XRD, XRF and SEM were used to investigate the chemical and mineralogical compositions of the scale samples in analytical methods. For the numerical approach, PhreeqC and GWELL codes were used to follow the chemical reactivity of the geothermal fluid in Tuzla production well. The novelty of this study is to determine potential degassing point and to characterize the mineralogical assemblage formed in the well because of the fluid composition, temperature and pressure variations. During production, geothermal fluids degas in the wellbore. This causes a drastic modification of the chemistry of the Tuzla fluids. This is why it is focused the calculations on the nature of the minerals that are able to precipitate inside the well. According to simulation results, the degassing point is estimated to be about 105 m depth, consistent with the field observations. If a small quantity of precipitated minerals is predicted before the boiling point, degassing significantly changes the fluid chemistry, and the model predicts the deposition of calcite along with smaller elements including galena, barite, and quartz. The simulation results are consistent with the mineral composition of scaling collected in the well.
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issn 2195-9706
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spelling doaj-art-8a8326fa5ce747989d594f1ec0ee41392025-01-19T12:16:58ZengSpringerOpenGeothermal Energy2195-97062025-01-0113113010.1186/s40517-024-00320-7Effect of degassing on scaling in hypersaline system: Tuzla geothermal field, TurkeySerhat Tonkul0Laurent André1Alper Baba2Mustafa M. Demir3Simona Regenspurg4Katrin Kieling5Department of Environmental Engineering, İzmir Institute of TechnologyBRGMDepartment of International Water Resources, İzmir Institute of TechnologyDepartment of Material Science and Engineering, İzmir Institute of TechnologyHelmholtz-Zentrum Potsdam, Deutsches GeoForschungsZentrum GFZHelmholtz-Zentrum Potsdam, Deutsches GeoForschungsZentrum GFZAbstract A serious issue with geothermal power plants is the loss of production and decline in power plant efficiency. Scaling, also known as mineral precipitation, is one of the frequently-observed issue that causes this loss and decreasing efficiency. It is heavily observed in the production wells when the geothermal fluid rises from the depths due to a change in the fluid’s physical and chemical properties. Scaling issue in geothermal power plants result in significant output losses and lower plant effectiveness. In rare instances, it might even result in the power plant being shut down. The chemistry of the geothermal fluid, non-condensable gases, pH, temperature and pressure changes in the process from production to reinjection, power plant type and design, and sometimes the materials used can also play an active role in the scaling that will occur in a geothermal system. ICP–MS was used to evaluate the chemical properties of the fluids. On the other hand, XRD, XRF and SEM were used to investigate the chemical and mineralogical compositions of the scale samples in analytical methods. For the numerical approach, PhreeqC and GWELL codes were used to follow the chemical reactivity of the geothermal fluid in Tuzla production well. The novelty of this study is to determine potential degassing point and to characterize the mineralogical assemblage formed in the well because of the fluid composition, temperature and pressure variations. During production, geothermal fluids degas in the wellbore. This causes a drastic modification of the chemistry of the Tuzla fluids. This is why it is focused the calculations on the nature of the minerals that are able to precipitate inside the well. According to simulation results, the degassing point is estimated to be about 105 m depth, consistent with the field observations. If a small quantity of precipitated minerals is predicted before the boiling point, degassing significantly changes the fluid chemistry, and the model predicts the deposition of calcite along with smaller elements including galena, barite, and quartz. The simulation results are consistent with the mineral composition of scaling collected in the well.https://doi.org/10.1186/s40517-024-00320-7Geothermal energyCO2 degassingScales characterizationsGeochemical modelling
spellingShingle Serhat Tonkul
Laurent André
Alper Baba
Mustafa M. Demir
Simona Regenspurg
Katrin Kieling
Effect of degassing on scaling in hypersaline system: Tuzla geothermal field, Turkey
Geothermal Energy
Geothermal energy
CO2 degassing
Scales characterizations
Geochemical modelling
title Effect of degassing on scaling in hypersaline system: Tuzla geothermal field, Turkey
title_full Effect of degassing on scaling in hypersaline system: Tuzla geothermal field, Turkey
title_fullStr Effect of degassing on scaling in hypersaline system: Tuzla geothermal field, Turkey
title_full_unstemmed Effect of degassing on scaling in hypersaline system: Tuzla geothermal field, Turkey
title_short Effect of degassing on scaling in hypersaline system: Tuzla geothermal field, Turkey
title_sort effect of degassing on scaling in hypersaline system tuzla geothermal field turkey
topic Geothermal energy
CO2 degassing
Scales characterizations
Geochemical modelling
url https://doi.org/10.1186/s40517-024-00320-7
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