Mechanical Response of FeNiCrCoAl High-Entropy Alloys at the Nanoscale: Predictions from Molecular Dynamics

The mechanical response of high-entropy alloys (HEAs), specifically the FeNiCrCoAl HEA, was studied at both bulk and nanoparticle scales using molecular dynamics simulations. These simulations were performed using the LAMMPS software with an Embedded Atom Method (EAM) potential. The results show tha...

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Main Authors: Ernesto Amaro, Joaly Delgado-Alvarez, Jairo Andrés Martínez-Uribe, Sergio Mejía-Rosales
Format: Article
Language:English
Published: MDPI AG 2025-04-01
Series:Nanomaterials
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Online Access:https://www.mdpi.com/2079-4991/15/9/652
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author Ernesto Amaro
Joaly Delgado-Alvarez
Jairo Andrés Martínez-Uribe
Sergio Mejía-Rosales
author_facet Ernesto Amaro
Joaly Delgado-Alvarez
Jairo Andrés Martínez-Uribe
Sergio Mejía-Rosales
author_sort Ernesto Amaro
collection DOAJ
description The mechanical response of high-entropy alloys (HEAs), specifically the FeNiCrCoAl HEA, was studied at both bulk and nanoparticle scales using molecular dynamics simulations. These simulations were performed using the LAMMPS software with an Embedded Atom Method (EAM) potential. The results show that Bulk HEAs exhibited enhanced hardening and plasticity, while in nanoparticles, distinct deformation patterns were observed, including nanotwin formation, V-shaped stacking fault planes, and intermittent dislocation activity due to free surface effects. The crystallographic orientation with respect to the compression significantly affected the deformation mechanisms, with the [100] direction favoring progressive hardening, while the [110] and [111] directions exhibited different stacking fault and dislocation dynamics. A detailed analysis using von Mises stress and dislocation analysis provided insights into the effects of scale on mechanical properties.
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series Nanomaterials
spelling doaj-art-89f91893810e4e5080ca71cb8b6544692025-08-20T02:59:15ZengMDPI AGNanomaterials2079-49912025-04-0115965210.3390/nano15090652Mechanical Response of FeNiCrCoAl High-Entropy Alloys at the Nanoscale: Predictions from Molecular DynamicsErnesto Amaro0Joaly Delgado-Alvarez1Jairo Andrés Martínez-Uribe2Sergio Mejía-Rosales3Facultad de Ciencias Físico-Matemáticas, Universidad Autónoma de Nuevo León, San Nicolás de los Garza 66455, NL, MexicoFacultad de Ciencias Físico-Matemáticas, Universidad Autónoma de Nuevo León, San Nicolás de los Garza 66455, NL, MexicoCentro de Investigación en Ciencias Físico-Matemáticas (CICFIM), Facultad de Ciencias Físico-Matemáticas, Universidad Autónoma de Nuevo León, San Nicolás de los Garza 66455, NL, MexicoCentro de Investigación en Ciencias Físico-Matemáticas (CICFIM), Facultad de Ciencias Físico-Matemáticas, Universidad Autónoma de Nuevo León, San Nicolás de los Garza 66455, NL, MexicoThe mechanical response of high-entropy alloys (HEAs), specifically the FeNiCrCoAl HEA, was studied at both bulk and nanoparticle scales using molecular dynamics simulations. These simulations were performed using the LAMMPS software with an Embedded Atom Method (EAM) potential. The results show that Bulk HEAs exhibited enhanced hardening and plasticity, while in nanoparticles, distinct deformation patterns were observed, including nanotwin formation, V-shaped stacking fault planes, and intermittent dislocation activity due to free surface effects. The crystallographic orientation with respect to the compression significantly affected the deformation mechanisms, with the [100] direction favoring progressive hardening, while the [110] and [111] directions exhibited different stacking fault and dislocation dynamics. A detailed analysis using von Mises stress and dislocation analysis provided insights into the effects of scale on mechanical properties.https://www.mdpi.com/2079-4991/15/9/652FeNiCrCoAl high-entropy alloysdislocation dynamicsstress–strain behaviorsimulated STEM micrographsmechanical properties at the nanoscale
spellingShingle Ernesto Amaro
Joaly Delgado-Alvarez
Jairo Andrés Martínez-Uribe
Sergio Mejía-Rosales
Mechanical Response of FeNiCrCoAl High-Entropy Alloys at the Nanoscale: Predictions from Molecular Dynamics
Nanomaterials
FeNiCrCoAl high-entropy alloys
dislocation dynamics
stress–strain behavior
simulated STEM micrographs
mechanical properties at the nanoscale
title Mechanical Response of FeNiCrCoAl High-Entropy Alloys at the Nanoscale: Predictions from Molecular Dynamics
title_full Mechanical Response of FeNiCrCoAl High-Entropy Alloys at the Nanoscale: Predictions from Molecular Dynamics
title_fullStr Mechanical Response of FeNiCrCoAl High-Entropy Alloys at the Nanoscale: Predictions from Molecular Dynamics
title_full_unstemmed Mechanical Response of FeNiCrCoAl High-Entropy Alloys at the Nanoscale: Predictions from Molecular Dynamics
title_short Mechanical Response of FeNiCrCoAl High-Entropy Alloys at the Nanoscale: Predictions from Molecular Dynamics
title_sort mechanical response of fenicrcoal high entropy alloys at the nanoscale predictions from molecular dynamics
topic FeNiCrCoAl high-entropy alloys
dislocation dynamics
stress–strain behavior
simulated STEM micrographs
mechanical properties at the nanoscale
url https://www.mdpi.com/2079-4991/15/9/652
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AT jairoandresmartinezuribe mechanicalresponseoffenicrcoalhighentropyalloysatthenanoscalepredictionsfrommoleculardynamics
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