Regioselictivity in styrene oxide epoxide cycle cleavage by ethylenediamines in different solvents

The results of styrene oxide epoxide cycle cleavage by diamines were summarized. The effect of solvent on regioselectivity in the reaction of N,N-diethylene diamine was studied. It was established that the ratio of products correlates well with polarity parameters ЕТ and АN of pure solvents.

Saved in:
Bibliographic Details
Main Authors: A. H. Mohammed, E. Ya. Borisova, V. V. Egorova, A. V. Krylov, N. Yu. Borisova
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2011-10-01
Series:Тонкие химические технологии
Subjects:
Online Access:https://www.finechem-mirea.ru/jour/article/view/802
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1849253165732462592
author A. H. Mohammed
E. Ya. Borisova
V. V. Egorova
A. V. Krylov
N. Yu. Borisova
author_facet A. H. Mohammed
E. Ya. Borisova
V. V. Egorova
A. V. Krylov
N. Yu. Borisova
author_sort A. H. Mohammed
collection DOAJ
description The results of styrene oxide epoxide cycle cleavage by diamines were summarized. The effect of solvent on regioselectivity in the reaction of N,N-diethylene diamine was studied. It was established that the ratio of products correlates well with polarity parameters ЕТ and АN of pure solvents.
format Article
id doaj-art-898c76a9d2fc4996b5d9d24a14a0fcb8
institution Kabale University
issn 2410-6593
2686-7575
language Russian
publishDate 2011-10-01
publisher MIREA - Russian Technological University
record_format Article
series Тонкие химические технологии
spelling doaj-art-898c76a9d2fc4996b5d9d24a14a0fcb82025-08-20T03:56:24ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752011-10-0165140142796Regioselictivity in styrene oxide epoxide cycle cleavage by ethylenediamines in different solventsA. H. Mohammed0E. Ya. Borisova1V. V. Egorova2A. V. Krylov3N. Yu. Borisova4M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571M.V. Lomonosov Moscow State University of Fine Chemical Technologies, 86, Vernadskogo pr., Moscow 119571The results of styrene oxide epoxide cycle cleavage by diamines were summarized. The effect of solvent on regioselectivity in the reaction of N,N-diethylene diamine was studied. It was established that the ratio of products correlates well with polarity parameters ЕТ and АN of pure solvents.https://www.finechem-mirea.ru/jour/article/view/802synthesisdiamine alcoholsstyrene oxidesolventsregioselectivity
spellingShingle A. H. Mohammed
E. Ya. Borisova
V. V. Egorova
A. V. Krylov
N. Yu. Borisova
Regioselictivity in styrene oxide epoxide cycle cleavage by ethylenediamines in different solvents
Тонкие химические технологии
synthesis
diamine alcohols
styrene oxide
solvents
regioselectivity
title Regioselictivity in styrene oxide epoxide cycle cleavage by ethylenediamines in different solvents
title_full Regioselictivity in styrene oxide epoxide cycle cleavage by ethylenediamines in different solvents
title_fullStr Regioselictivity in styrene oxide epoxide cycle cleavage by ethylenediamines in different solvents
title_full_unstemmed Regioselictivity in styrene oxide epoxide cycle cleavage by ethylenediamines in different solvents
title_short Regioselictivity in styrene oxide epoxide cycle cleavage by ethylenediamines in different solvents
title_sort regioselictivity in styrene oxide epoxide cycle cleavage by ethylenediamines in different solvents
topic synthesis
diamine alcohols
styrene oxide
solvents
regioselectivity
url https://www.finechem-mirea.ru/jour/article/view/802
work_keys_str_mv AT ahmohammed regioselictivityinstyreneoxideepoxidecyclecleavagebyethylenediaminesindifferentsolvents
AT eyaborisova regioselictivityinstyreneoxideepoxidecyclecleavagebyethylenediaminesindifferentsolvents
AT vvegorova regioselictivityinstyreneoxideepoxidecyclecleavagebyethylenediaminesindifferentsolvents
AT avkrylov regioselictivityinstyreneoxideepoxidecyclecleavagebyethylenediaminesindifferentsolvents
AT nyuborisova regioselictivityinstyreneoxideepoxidecyclecleavagebyethylenediaminesindifferentsolvents