Examination of current adsorption models for Pb(II) and Cu(II) adsorption onto FeO@MgAl-NO Layered Double Hydroxide in aqueous solution

The adsorption of Pb(II) and Cu(II) onto Fe 3 O 4 @Mg 2 Al-NO 3 Layered Double Hydroxide (LDH) as a function of Fe 3 O 4 @Mg 2 Al-NO 3 LDH concentration was studied. An adsorbent concentration effect ( C s effect), namely adsorption isotherm declines as adsorbent concentration ( C s ) increases, was...

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Main Authors: Ling-Xi Zhao, Ming-Chao Jiang, Ling-Yu Luan, Qing Li, Jing Zhang
Format: Article
Language:English
Published: SAGE Publishing 2018-02-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/0263617417714166
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author Ling-Xi Zhao
Ming-Chao Jiang
Ling-Yu Luan
Qing Li
Jing Zhang
author_facet Ling-Xi Zhao
Ming-Chao Jiang
Ling-Yu Luan
Qing Li
Jing Zhang
author_sort Ling-Xi Zhao
collection DOAJ
description The adsorption of Pb(II) and Cu(II) onto Fe 3 O 4 @Mg 2 Al-NO 3 Layered Double Hydroxide (LDH) as a function of Fe 3 O 4 @Mg 2 Al-NO 3 LDH concentration was studied. An adsorbent concentration effect ( C s effect), namely adsorption isotherm declines as adsorbent concentration ( C s ) increases, was observed. The experimental data were fitted to the adsorption models including the classic Freundlich model, the metastable-equilibrium adsorption theory, the flocculation model, the power function model, and the surface component activity model. The results show that the Freundlich-type metastable-equilibrium adsorption equation, the power function model, and the Freundlich-surface component activity equation can adequately describe the C s effect observed in the batch adsorption tests as all the correlation coefficients ( R 2 ) of the nonlinear plots are higher than 0.96. In other words, their intrinsic parameters simulated from the experimental data are independent of C s value. It is considered that the Freundlich-surface component activity equation is the best model to describe the C s effect of the studied adsorption systems by Akaike Information Criterion evaluation criterion.
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institution Kabale University
issn 0263-6174
2048-4038
language English
publishDate 2018-02-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-8987a217887648d895abc359739fdb882025-01-03T01:23:07ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382018-02-013610.1177/0263617417714166Examination of current adsorption models for Pb(II) and Cu(II) adsorption onto FeO@MgAl-NO Layered Double Hydroxide in aqueous solutionLing-Xi ZhaoMing-Chao JiangLing-Yu LuanQing LiJing ZhangThe adsorption of Pb(II) and Cu(II) onto Fe 3 O 4 @Mg 2 Al-NO 3 Layered Double Hydroxide (LDH) as a function of Fe 3 O 4 @Mg 2 Al-NO 3 LDH concentration was studied. An adsorbent concentration effect ( C s effect), namely adsorption isotherm declines as adsorbent concentration ( C s ) increases, was observed. The experimental data were fitted to the adsorption models including the classic Freundlich model, the metastable-equilibrium adsorption theory, the flocculation model, the power function model, and the surface component activity model. The results show that the Freundlich-type metastable-equilibrium adsorption equation, the power function model, and the Freundlich-surface component activity equation can adequately describe the C s effect observed in the batch adsorption tests as all the correlation coefficients ( R 2 ) of the nonlinear plots are higher than 0.96. In other words, their intrinsic parameters simulated from the experimental data are independent of C s value. It is considered that the Freundlich-surface component activity equation is the best model to describe the C s effect of the studied adsorption systems by Akaike Information Criterion evaluation criterion.https://doi.org/10.1177/0263617417714166
spellingShingle Ling-Xi Zhao
Ming-Chao Jiang
Ling-Yu Luan
Qing Li
Jing Zhang
Examination of current adsorption models for Pb(II) and Cu(II) adsorption onto FeO@MgAl-NO Layered Double Hydroxide in aqueous solution
Adsorption Science & Technology
title Examination of current adsorption models for Pb(II) and Cu(II) adsorption onto FeO@MgAl-NO Layered Double Hydroxide in aqueous solution
title_full Examination of current adsorption models for Pb(II) and Cu(II) adsorption onto FeO@MgAl-NO Layered Double Hydroxide in aqueous solution
title_fullStr Examination of current adsorption models for Pb(II) and Cu(II) adsorption onto FeO@MgAl-NO Layered Double Hydroxide in aqueous solution
title_full_unstemmed Examination of current adsorption models for Pb(II) and Cu(II) adsorption onto FeO@MgAl-NO Layered Double Hydroxide in aqueous solution
title_short Examination of current adsorption models for Pb(II) and Cu(II) adsorption onto FeO@MgAl-NO Layered Double Hydroxide in aqueous solution
title_sort examination of current adsorption models for pb ii and cu ii adsorption onto feo mgal no layered double hydroxide in aqueous solution
url https://doi.org/10.1177/0263617417714166
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AT mingchaojiang examinationofcurrentadsorptionmodelsforpbiiandcuiiadsorptionontofeomgalnolayereddoublehydroxideinaqueoussolution
AT lingyuluan examinationofcurrentadsorptionmodelsforpbiiandcuiiadsorptionontofeomgalnolayereddoublehydroxideinaqueoussolution
AT qingli examinationofcurrentadsorptionmodelsforpbiiandcuiiadsorptionontofeomgalnolayereddoublehydroxideinaqueoussolution
AT jingzhang examinationofcurrentadsorptionmodelsforpbiiandcuiiadsorptionontofeomgalnolayereddoublehydroxideinaqueoussolution