Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability
Random copolyesters were synthesized directly from respective diacids and diols with diphenylchlorophosphate (DPCP) as a polycondensation agent. These polymers were characterized by FT-IR and NMR spectrometry. Interestingly, they were observed to possess photocrosslinkability which was established u...
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| Format: | Article |
| Language: | English |
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Wiley
2012-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2012/656493 |
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| author | D. Roop Singh S. Vasanthi J. Arul Moli |
| author_facet | D. Roop Singh S. Vasanthi J. Arul Moli |
| author_sort | D. Roop Singh |
| collection | DOAJ |
| description | Random copolyesters were synthesized directly from respective diacids and diols with diphenylchlorophosphate (DPCP) as a polycondensation agent. These polymers were characterized by FT-IR and NMR spectrometry. Interestingly, they were observed to possess photocrosslinkability which was established using scanning electron microscopy by UV irradiation experiments. Photocrosslinkable polymers have significant applications in the field of non-linear optics, in the generation of photoresists and photorefractive materials. |
| format | Article |
| id | doaj-art-89358c8fc53346a6a42caa71ead783f1 |
| institution | OA Journals |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-89358c8fc53346a6a42caa71ead783f12025-08-20T02:09:38ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-019114514810.1155/2012/656493Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their PhotocrosslinkabilityD. Roop Singh0S. Vasanthi1J. Arul Moli2Post-Graduate and Research Department of Chemistry, Presidency College (Autonomous), Chennai-600 005, IndiaPost-Graduate and Research Department of Chemistry, Presidency College (Autonomous), Chennai-600 005, IndiaPost-Graduate and Research Department of Chemistry, Presidency College (Autonomous), Chennai-600 005, IndiaRandom copolyesters were synthesized directly from respective diacids and diols with diphenylchlorophosphate (DPCP) as a polycondensation agent. These polymers were characterized by FT-IR and NMR spectrometry. Interestingly, they were observed to possess photocrosslinkability which was established using scanning electron microscopy by UV irradiation experiments. Photocrosslinkable polymers have significant applications in the field of non-linear optics, in the generation of photoresists and photorefractive materials.http://dx.doi.org/10.1155/2012/656493 |
| spellingShingle | D. Roop Singh S. Vasanthi J. Arul Moli Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability E-Journal of Chemistry |
| title | Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability |
| title_full | Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability |
| title_fullStr | Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability |
| title_full_unstemmed | Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability |
| title_short | Synthesis of Certain Poly[bis(benzylidene)] Esters and Investigation on their Photocrosslinkability |
| title_sort | synthesis of certain poly bis benzylidene esters and investigation on their photocrosslinkability |
| url | http://dx.doi.org/10.1155/2012/656493 |
| work_keys_str_mv | AT droopsingh synthesisofcertainpolybisbenzylideneestersandinvestigationontheirphotocrosslinkability AT svasanthi synthesisofcertainpolybisbenzylideneestersandinvestigationontheirphotocrosslinkability AT jarulmoli synthesisofcertainpolybisbenzylideneestersandinvestigationontheirphotocrosslinkability |