Complements to the Theoretical Treatments of the Electron Collision with : An R-Matrix Approach

This paper presents new refined results from the theoretical treatment of electron collision with the Fe-peak element Co3+. We have investigated the relevance of relativistic effects on the accurate representation of the target electron wave functions within the Breit-Pauli R-matrix approach. The ca...

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Main Author: V. Stancalie
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Spectroscopy
Online Access:http://dx.doi.org/10.1155/2013/820635
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author V. Stancalie
author_facet V. Stancalie
author_sort V. Stancalie
collection DOAJ
description This paper presents new refined results from the theoretical treatment of electron collision with the Fe-peak element Co3+. We have investigated the relevance of relativistic effects on the accurate representation of the target electron wave functions within the Breit-Pauli R-matrix approach. The calculated values for fine-structure levels are compared with the available experimental data in Atomic Structure Database of the National Institute for Standards and Technology. The agreement between the calculated and the experimental data is reasonably good, the energy difference average percentage of the low-lying levels usually agreeing to within 3.6% of each other. For completeness, we summarize herein the existing theoretical R-matrix treatments intended specifically to explore the role of including configuration interaction wave functions both in the target-state expansion, and in the ()-electron quadratically integrable function expansion. To the best of our knowledge, the work reported herein describes for the first time a detailed calculation for this atomic system, and the results are relevant to the laboratory and astrophysical plasmas.
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spelling doaj-art-888159ffbd7a4f01b251123c4cd496e92025-02-03T06:10:48ZengWileyJournal of Spectroscopy2314-49202314-49392013-01-01201310.1155/2013/820635820635Complements to the Theoretical Treatments of the Electron Collision with : An R-Matrix ApproachV. Stancalie0National Institute for Laser, Plasma and Radiation Physics, Atomistilor 409, P. O. Box MG-36, Iflov, 077125 Magurele, RomaniaThis paper presents new refined results from the theoretical treatment of electron collision with the Fe-peak element Co3+. We have investigated the relevance of relativistic effects on the accurate representation of the target electron wave functions within the Breit-Pauli R-matrix approach. The calculated values for fine-structure levels are compared with the available experimental data in Atomic Structure Database of the National Institute for Standards and Technology. The agreement between the calculated and the experimental data is reasonably good, the energy difference average percentage of the low-lying levels usually agreeing to within 3.6% of each other. For completeness, we summarize herein the existing theoretical R-matrix treatments intended specifically to explore the role of including configuration interaction wave functions both in the target-state expansion, and in the ()-electron quadratically integrable function expansion. To the best of our knowledge, the work reported herein describes for the first time a detailed calculation for this atomic system, and the results are relevant to the laboratory and astrophysical plasmas.http://dx.doi.org/10.1155/2013/820635
spellingShingle V. Stancalie
Complements to the Theoretical Treatments of the Electron Collision with : An R-Matrix Approach
Journal of Spectroscopy
title Complements to the Theoretical Treatments of the Electron Collision with : An R-Matrix Approach
title_full Complements to the Theoretical Treatments of the Electron Collision with : An R-Matrix Approach
title_fullStr Complements to the Theoretical Treatments of the Electron Collision with : An R-Matrix Approach
title_full_unstemmed Complements to the Theoretical Treatments of the Electron Collision with : An R-Matrix Approach
title_short Complements to the Theoretical Treatments of the Electron Collision with : An R-Matrix Approach
title_sort complements to the theoretical treatments of the electron collision with an r matrix approach
url http://dx.doi.org/10.1155/2013/820635
work_keys_str_mv AT vstancalie complementstothetheoreticaltreatmentsoftheelectroncollisionwithanrmatrixapproach