Comparative evaluation and economic analysis of metal- and carbon-based nanoadditives in low-viscous waste-derived biofuel blends for diesel engines

This study presents a comparative evaluation of two distinct nanoadditives: a metal-based additive (copper oxide, CuO) and a carbon-based additive (carbon nanotubes, CNTs), focusing on their effects on engine performance and emissions when blended with a biofuel derived from pomelo peel waste (PWB)...

Full description

Saved in:
Bibliographic Details
Main Authors: Xu Han, Ting Li, Guangchun Liu, Suresh Vellaiyan
Format: Article
Language:English
Published: Elsevier 2025-05-01
Series:Case Studies in Thermal Engineering
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2214157X2500317X
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1850182317908164608
author Xu Han
Ting Li
Guangchun Liu
Suresh Vellaiyan
author_facet Xu Han
Ting Li
Guangchun Liu
Suresh Vellaiyan
author_sort Xu Han
collection DOAJ
description This study presents a comparative evaluation of two distinct nanoadditives: a metal-based additive (copper oxide, CuO) and a carbon-based additive (carbon nanotubes, CNTs), focusing on their effects on engine performance and emissions when blended with a biofuel derived from pomelo peel waste (PWB) and conventional diesel fuel (CDF). The PWB bio-oil was extracted via thermal distillation, and a 30 % PWB + CDF blend (CDF30PWB) was further modified with 100 ppm of CuO and CNT nanoparticles. Characterization of CuO and CNT confirmed their catalytic potential for fuel enhancement. Results indicate that CDF30PWB improved brake thermal efficiency (BTE) by 6.09 % compared to CDF, while CNT and CuO further increased BTE by 1.63 % and 3.12 %, respectively. Brake-specific fuel consumption (BSFC) was reduced by 3.95 % for CDF30PWB, with CNT achieving an additional 3.69 % reduction and CuO lowering BSFC by 2.1 %. Emissions analysis showed that hydrocarbon (HC) and carbon monoxide (CO) emissions were reduced by 8.13 % and 2.61 %, respectively, for CDF30PWB, while CNT-enhanced fuel achieved further reductions of 14.59 % (HC) and 14.93 % (CO), and CuO reduced them by 4.29 % and 8.5 %, respectively. NOx emissions increased by 5.15 % with CDF30PWB, but CuO incorporation led to a 12.56 % reduction, and CNTs reduced NOx by 8.45 %. Smoke opacity was lowered by 9.88 % with CuO and 11.05 % with CNTs. Economic analysis highlighted that CuO achieved a 19 % potential cost reduction. This study concludes that CuO is more effective in NOx mitigation at a lower cost, while CNTs optimize engine performance and reduce HC and CO emissions.
format Article
id doaj-art-8832f2fbb9594ba3bc1bf152e94c98af
institution OA Journals
issn 2214-157X
language English
publishDate 2025-05-01
publisher Elsevier
record_format Article
series Case Studies in Thermal Engineering
spelling doaj-art-8832f2fbb9594ba3bc1bf152e94c98af2025-08-20T02:17:39ZengElsevierCase Studies in Thermal Engineering2214-157X2025-05-016910605710.1016/j.csite.2025.106057Comparative evaluation and economic analysis of metal- and carbon-based nanoadditives in low-viscous waste-derived biofuel blends for diesel enginesXu Han0Ting Li1Guangchun Liu2Suresh Vellaiyan3Liaoning Provincial Key Laboratory of Urban Pest Management and Ecological Safety, ShenYang University, ShenYang, 110044, ChinaGreen Island Institute of Environmental Resources, ShenYang City University, Shenyang, 110112, ChinaLiaoning Provincial Key Laboratory of Urban Pest Management and Ecological Safety, ShenYang University, ShenYang, 110044, China; Corresponding author.Department of Sustainable Engineering, Saveetha School of Engineering, Saveetha Institute of Medical and Technical Sciences, Chennai, Tamilnadu, India; Corresponding author. Department of Sustainable Engineering, Saveetha School of Engineering, SIMATS, Chennai, Tamilnadu, India.This study presents a comparative evaluation of two distinct nanoadditives: a metal-based additive (copper oxide, CuO) and a carbon-based additive (carbon nanotubes, CNTs), focusing on their effects on engine performance and emissions when blended with a biofuel derived from pomelo peel waste (PWB) and conventional diesel fuel (CDF). The PWB bio-oil was extracted via thermal distillation, and a 30 % PWB + CDF blend (CDF30PWB) was further modified with 100 ppm of CuO and CNT nanoparticles. Characterization of CuO and CNT confirmed their catalytic potential for fuel enhancement. Results indicate that CDF30PWB improved brake thermal efficiency (BTE) by 6.09 % compared to CDF, while CNT and CuO further increased BTE by 1.63 % and 3.12 %, respectively. Brake-specific fuel consumption (BSFC) was reduced by 3.95 % for CDF30PWB, with CNT achieving an additional 3.69 % reduction and CuO lowering BSFC by 2.1 %. Emissions analysis showed that hydrocarbon (HC) and carbon monoxide (CO) emissions were reduced by 8.13 % and 2.61 %, respectively, for CDF30PWB, while CNT-enhanced fuel achieved further reductions of 14.59 % (HC) and 14.93 % (CO), and CuO reduced them by 4.29 % and 8.5 %, respectively. NOx emissions increased by 5.15 % with CDF30PWB, but CuO incorporation led to a 12.56 % reduction, and CNTs reduced NOx by 8.45 %. Smoke opacity was lowered by 9.88 % with CuO and 11.05 % with CNTs. Economic analysis highlighted that CuO achieved a 19 % potential cost reduction. This study concludes that CuO is more effective in NOx mitigation at a lower cost, while CNTs optimize engine performance and reduce HC and CO emissions.http://www.sciencedirect.com/science/article/pii/S2214157X2500317XSustainable energyPomelo peel biofuelCopper oxideCarbon nanotubesPerformance assessment
spellingShingle Xu Han
Ting Li
Guangchun Liu
Suresh Vellaiyan
Comparative evaluation and economic analysis of metal- and carbon-based nanoadditives in low-viscous waste-derived biofuel blends for diesel engines
Case Studies in Thermal Engineering
Sustainable energy
Pomelo peel biofuel
Copper oxide
Carbon nanotubes
Performance assessment
title Comparative evaluation and economic analysis of metal- and carbon-based nanoadditives in low-viscous waste-derived biofuel blends for diesel engines
title_full Comparative evaluation and economic analysis of metal- and carbon-based nanoadditives in low-viscous waste-derived biofuel blends for diesel engines
title_fullStr Comparative evaluation and economic analysis of metal- and carbon-based nanoadditives in low-viscous waste-derived biofuel blends for diesel engines
title_full_unstemmed Comparative evaluation and economic analysis of metal- and carbon-based nanoadditives in low-viscous waste-derived biofuel blends for diesel engines
title_short Comparative evaluation and economic analysis of metal- and carbon-based nanoadditives in low-viscous waste-derived biofuel blends for diesel engines
title_sort comparative evaluation and economic analysis of metal and carbon based nanoadditives in low viscous waste derived biofuel blends for diesel engines
topic Sustainable energy
Pomelo peel biofuel
Copper oxide
Carbon nanotubes
Performance assessment
url http://www.sciencedirect.com/science/article/pii/S2214157X2500317X
work_keys_str_mv AT xuhan comparativeevaluationandeconomicanalysisofmetalandcarbonbasednanoadditivesinlowviscouswastederivedbiofuelblendsfordieselengines
AT tingli comparativeevaluationandeconomicanalysisofmetalandcarbonbasednanoadditivesinlowviscouswastederivedbiofuelblendsfordieselengines
AT guangchunliu comparativeevaluationandeconomicanalysisofmetalandcarbonbasednanoadditivesinlowviscouswastederivedbiofuelblendsfordieselengines
AT sureshvellaiyan comparativeevaluationandeconomicanalysisofmetalandcarbonbasednanoadditivesinlowviscouswastederivedbiofuelblendsfordieselengines