SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES
The synthesis and spectroscopic studies (infrared and Mössbauer) of new hydrogenoxalato derivatives and adducts containing SnRn (R=Me, Ph; n=2, 3) residues are reported. Based on their spectroscopic data dimeric and polymeric structures containing hexacoordinated or pentacoordinated Sn are suggeste...
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| Format: | Article |
| Language: | English |
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Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
2020-06-01
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| Series: | Journal of Engineering Studies and Research |
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| Online Access: | https://jesr.ub.ro/index.php/1/article/view/172 |
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| author | MOUHAMADOU SEMBENE BOYE AMINATA DIASSE-SARR LIBASSE DIOP |
| author_facet | MOUHAMADOU SEMBENE BOYE AMINATA DIASSE-SARR LIBASSE DIOP |
| author_sort | MOUHAMADOU SEMBENE BOYE |
| collection | DOAJ |
| description |
The synthesis and spectroscopic studies (infrared and Mössbauer) of new hydrogenoxalato derivatives and adducts containing SnRn (R=Me, Ph; n=2, 3) residues are reported. Based on their spectroscopic data dimeric and polymeric structures containing hexacoordinated or pentacoordinated Sn are suggested, the hydrogenoxolate anion behaving as a monocoordinating or a monochelating ligand. In two studied adducts, supramolecular architectures may be obtained when extra hydrogen bonds involving the free NH groups are considered.
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| format | Article |
| id | doaj-art-87d7ac6e53354ab0b6924fa82bf23d2d |
| institution | Kabale University |
| issn | 2068-7559 2344-4932 |
| language | English |
| publishDate | 2020-06-01 |
| publisher | Alma Mater Publishing House "Vasile Alecsandri" University of Bacau |
| record_format | Article |
| series | Journal of Engineering Studies and Research |
| spelling | doaj-art-87d7ac6e53354ab0b6924fa82bf23d2d2025-02-09T11:37:38ZengAlma Mater Publishing House "Vasile Alecsandri" University of BacauJournal of Engineering Studies and Research2068-75592344-49322020-06-01262SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXESMOUHAMADOU SEMBENE BOYEAMINATA DIASSE-SARRLIBASSE DIOP The synthesis and spectroscopic studies (infrared and Mössbauer) of new hydrogenoxalato derivatives and adducts containing SnRn (R=Me, Ph; n=2, 3) residues are reported. Based on their spectroscopic data dimeric and polymeric structures containing hexacoordinated or pentacoordinated Sn are suggested, the hydrogenoxolate anion behaving as a monocoordinating or a monochelating ligand. In two studied adducts, supramolecular architectures may be obtained when extra hydrogen bonds involving the free NH groups are considered. https://jesr.ub.ro/index.php/1/article/view/172dimeric and polymeric structures, hydrogenoxalate, monochelating, monocoordinating, octahedral or trigonal bipyramidal environments, spectroscopy, supramolecular architectures. |
| spellingShingle | MOUHAMADOU SEMBENE BOYE AMINATA DIASSE-SARR LIBASSE DIOP SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES Journal of Engineering Studies and Research dimeric and polymeric structures, hydrogenoxalate, monochelating, monocoordinating, octahedral or trigonal bipyramidal environments, spectroscopy, supramolecular architectures. |
| title | SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES |
| title_full | SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES |
| title_fullStr | SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES |
| title_full_unstemmed | SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES |
| title_short | SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION OF SOME NEW HYDROGENOXALATO ORGANOTIN (IV) COMPLEXES |
| title_sort | synthesis and spectroscopic characterization of some new hydrogenoxalato organotin iv complexes |
| topic | dimeric and polymeric structures, hydrogenoxalate, monochelating, monocoordinating, octahedral or trigonal bipyramidal environments, spectroscopy, supramolecular architectures. |
| url | https://jesr.ub.ro/index.php/1/article/view/172 |
| work_keys_str_mv | AT mouhamadousembeneboye synthesisandspectroscopiccharacterizationofsomenewhydrogenoxalatoorganotinivcomplexes AT aminatadiassesarr synthesisandspectroscopiccharacterizationofsomenewhydrogenoxalatoorganotinivcomplexes AT libassediop synthesisandspectroscopiccharacterizationofsomenewhydrogenoxalatoorganotinivcomplexes |