Thermal, dielectric, and electrochemical study of decanoic acid–tetrabutylammonium chloride deep eutectic solvent
A mixture based on decanoic acid (DA) and tetrabutylammonium chloride (TBACl) is a simple and prototypical deep eutectic solvent (DES) useful for extracting compounds that are poorly soluble in water or in electrochemical applications. The most widely studied composition is DA–TBACl with a molar rat...
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Académie des sciences
2025-02-01
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| Series: | Comptes Rendus. Chimie |
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| Online Access: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.368/ |
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| author | Kamar, Mohammad Nadim Paquin, Ludovic Limanton, Emmanuelle Lagrost, Corinne Morineau, Denis |
| author_facet | Kamar, Mohammad Nadim Paquin, Ludovic Limanton, Emmanuelle Lagrost, Corinne Morineau, Denis |
| author_sort | Kamar, Mohammad Nadim |
| collection | DOAJ |
| description | A mixture based on decanoic acid (DA) and tetrabutylammonium chloride (TBACl) is a simple and prototypical deep eutectic solvent (DES) useful for extracting compounds that are poorly soluble in water or in electrochemical applications. The most widely studied composition is DA–TBACl with a molar ratio equal to 2:1. The composition of DESs has a strong impact on their physicochemical properties. Herein, a comparative study of thermal, dielectric, and ionic conductivities and electrochemical properties of DA–TBACl is carried out with varying molar compositions 2:1, 1:1, and 1:2. All the molar compositions lead to a stable fluid whose properties depend on the composition, providing better understanding and further insights into the chemical interactions that prevail in those materials. |
| format | Article |
| id | doaj-art-87cf0800852c446b835ea18aeea7d8f1 |
| institution | Kabale University |
| issn | 1878-1543 |
| language | English |
| publishDate | 2025-02-01 |
| publisher | Académie des sciences |
| record_format | Article |
| series | Comptes Rendus. Chimie |
| spelling | doaj-art-87cf0800852c446b835ea18aeea7d8f12025-08-20T03:58:18ZengAcadémie des sciencesComptes Rendus. Chimie1878-15432025-02-0111010.5802/crchim.36810.5802/crchim.368Thermal, dielectric, and electrochemical study of decanoic acid–tetrabutylammonium chloride deep eutectic solventKamar, Mohammad Nadim0Paquin, Ludovic1https://orcid.org/0000-0001-8518-5363Limanton, Emmanuelle2https://orcid.org/0000-0003-2828-9937 Lagrost, Corinne3https://orcid.org/0000-0001-9601-8333Morineau, Denis4https://orcid.org/0000-0002-8784-3021Institut de Physique de Rennes, CNRS-Université de Rennes, UMR 6251, F-35042 Rennes, FranceInstitut des Sciences Chimiques de Rennes, CNRS-Université de Rennes, UMR 6226, F-35042 Rennes, FranceInstitut des Sciences Chimiques de Rennes, CNRS-Université de Rennes, UMR 6226, F-35042 Rennes, FranceInstitut des Sciences Chimiques de Rennes, CNRS-Université de Rennes, UMR 6226, F-35042 Rennes, FranceInstitut de Physique de Rennes, CNRS-Université de Rennes, UMR 6251, F-35042 Rennes, FranceA mixture based on decanoic acid (DA) and tetrabutylammonium chloride (TBACl) is a simple and prototypical deep eutectic solvent (DES) useful for extracting compounds that are poorly soluble in water or in electrochemical applications. The most widely studied composition is DA–TBACl with a molar ratio equal to 2:1. The composition of DESs has a strong impact on their physicochemical properties. Herein, a comparative study of thermal, dielectric, and ionic conductivities and electrochemical properties of DA–TBACl is carried out with varying molar compositions 2:1, 1:1, and 1:2. All the molar compositions lead to a stable fluid whose properties depend on the composition, providing better understanding and further insights into the chemical interactions that prevail in those materials.https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.368/Deep eutectic solventsDielectric spectroscopyElectrochemistry |
| spellingShingle | Kamar, Mohammad Nadim Paquin, Ludovic Limanton, Emmanuelle Lagrost, Corinne Morineau, Denis Thermal, dielectric, and electrochemical study of decanoic acid–tetrabutylammonium chloride deep eutectic solvent Comptes Rendus. Chimie Deep eutectic solvents Dielectric spectroscopy Electrochemistry |
| title | Thermal, dielectric, and electrochemical study of decanoic acid–tetrabutylammonium chloride deep eutectic solvent |
| title_full | Thermal, dielectric, and electrochemical study of decanoic acid–tetrabutylammonium chloride deep eutectic solvent |
| title_fullStr | Thermal, dielectric, and electrochemical study of decanoic acid–tetrabutylammonium chloride deep eutectic solvent |
| title_full_unstemmed | Thermal, dielectric, and electrochemical study of decanoic acid–tetrabutylammonium chloride deep eutectic solvent |
| title_short | Thermal, dielectric, and electrochemical study of decanoic acid–tetrabutylammonium chloride deep eutectic solvent |
| title_sort | thermal dielectric and electrochemical study of decanoic acid tetrabutylammonium chloride deep eutectic solvent |
| topic | Deep eutectic solvents Dielectric spectroscopy Electrochemistry |
| url | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.368/ |
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