Performance Evaluation of AOP/Biological Hybrid System for Treatment of Recalcitrant Organic Compounds
Process water from nuclear fuel recovery unit operations contains a variety of toxic organic compounds. The use of decontamination reagents such as CCl4 together with phenolic tar results in wastewater with a high content of chlorophenols. In this study, the extent of dehalogenation of toxic aromati...
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| Main Authors: | , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2010-01-01
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| Series: | International Journal of Chemical Engineering |
| Online Access: | http://dx.doi.org/10.1155/2010/590169 |
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| Summary: | Process water from nuclear fuel recovery unit operations contains a variety of toxic organic compounds. The use of decontamination reagents such as CCl4 together with phenolic tar results in wastewater with a high content of chlorophenols. In this study, the extent of dehalogenation of toxic aromatic compounds was evaluated using a photolytic advanced oxidation process (AOP) followed by biodegradation in the second stage. A hard-to-degrade toxic pollutant, 4-chlorophenol (4-CP), was used to represent a variety of recalcitrant aromatic pollutants in effluent from the nuclear industry. A UV-assisted AOP/bioreactor system demonstrated a great potential in treatment of nuclear process wastewater and this was indicated by high removal efficiency (>98%) under various 4-CP concentrations. Adding hydrogen peroxide (H2O2) as a liquid catalyst further improved biodegradation rate but the effect was limited by the scavenging of OH• radicals under high concentrations of H2O2. |
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| ISSN: | 1687-806X 1687-8078 |