Spatial Distribution and Contamination Assessment of Heavy Metals in Surface Sediments of the Caofeidian Adjacent Sea after the Land Reclamation, Bohai Bay

Land reclamation can significantly influence spatial distribution of heavy metals in inshore sediments. In this study, the distribution and contamination of heavy metals (Cd, Cr, Cu, Ni, Pb, and Zn) in inshore sediments of Bohai Bay were investigated after the land reclamation of Caofeidian. The res...

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Main Authors: He Zhu, Haijian Bing, Huapeng Yi, Yanhong Wu, Zhigao Sun
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2018/2049353
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author He Zhu
Haijian Bing
Huapeng Yi
Yanhong Wu
Zhigao Sun
author_facet He Zhu
Haijian Bing
Huapeng Yi
Yanhong Wu
Zhigao Sun
author_sort He Zhu
collection DOAJ
description Land reclamation can significantly influence spatial distribution of heavy metals in inshore sediments. In this study, the distribution and contamination of heavy metals (Cd, Cr, Cu, Ni, Pb, and Zn) in inshore sediments of Bohai Bay were investigated after the land reclamation of Caofeidian. The results showed that the concentrations of Cd, Cr, Cu, Ni, Pb, and Zn in the sediments were 0.20–0.65, 27.16–115.70, 11.14–39.00, 17.37–65.90, 15.08–24.06, and 41.64–139.56 mg/kg, respectively. These metal concentrations were generally higher in the area of Caofeidian than in other Chinese bays and estuaries. Spatially, the concentrations of Cd, Cr, Cu, Ni, and Zn were markedly lower in the sediments close to Caofeidian compared with other regions, whereas the concentrations of Pb showed an opposite case. Hydrodynamic conditions after the land reclamation were the major factor influencing the distribution of heavy metals in the sediments. Grain sizes dominated the distribution of Cu and Zn, and organic matters and Fe/Mn oxides/hydroxides also determined the distribution of the heavy metals. Multiple contamination indices showed that the inshore sediments were moderately to highly contaminated by Cd and slightly contaminated by other heavy metals. Similarly, Cd showed a high potential ecorisk in the sediments, and other metals were in the low level. Chromium contributed to higher exposure toxicity than other metals by the toxicity unit and toxic risk index. The results of this study indicate that after the land reclamation of Caofeidian the contamination and ecorisk of heavy metals in the sediments markedly decreased in the stronger hydrodynamic areas.
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spelling doaj-art-863d8f9fc0ae43c1a01c35cf23cf62f82025-08-20T02:08:47ZengWileyJournal of Chemistry2090-90632090-90712018-01-01201810.1155/2018/20493532049353Spatial Distribution and Contamination Assessment of Heavy Metals in Surface Sediments of the Caofeidian Adjacent Sea after the Land Reclamation, Bohai BayHe Zhu0Haijian Bing1Huapeng Yi2Yanhong Wu3Zhigao Sun4Key Laboratory of Mountain Surface Processes and Ecological Regulation, Institute of Mountain Hazards and Environment, Chinese Academy of Sciences, Chengdu 610041, ChinaKey Laboratory of Mountain Surface Processes and Ecological Regulation, Institute of Mountain Hazards and Environment, Chinese Academy of Sciences, Chengdu 610041, ChinaSchool of Resources and Environmental Engineering, Ludong University, Yantai 264025, ChinaKey Laboratory of Mountain Surface Processes and Ecological Regulation, Institute of Mountain Hazards and Environment, Chinese Academy of Sciences, Chengdu 610041, ChinaKey Laboratory of Humid Subtropical Eco-Geographical Process (Fujian Normal University), Ministry of Education, Fuzhou 350007, ChinaLand reclamation can significantly influence spatial distribution of heavy metals in inshore sediments. In this study, the distribution and contamination of heavy metals (Cd, Cr, Cu, Ni, Pb, and Zn) in inshore sediments of Bohai Bay were investigated after the land reclamation of Caofeidian. The results showed that the concentrations of Cd, Cr, Cu, Ni, Pb, and Zn in the sediments were 0.20–0.65, 27.16–115.70, 11.14–39.00, 17.37–65.90, 15.08–24.06, and 41.64–139.56 mg/kg, respectively. These metal concentrations were generally higher in the area of Caofeidian than in other Chinese bays and estuaries. Spatially, the concentrations of Cd, Cr, Cu, Ni, and Zn were markedly lower in the sediments close to Caofeidian compared with other regions, whereas the concentrations of Pb showed an opposite case. Hydrodynamic conditions after the land reclamation were the major factor influencing the distribution of heavy metals in the sediments. Grain sizes dominated the distribution of Cu and Zn, and organic matters and Fe/Mn oxides/hydroxides also determined the distribution of the heavy metals. Multiple contamination indices showed that the inshore sediments were moderately to highly contaminated by Cd and slightly contaminated by other heavy metals. Similarly, Cd showed a high potential ecorisk in the sediments, and other metals were in the low level. Chromium contributed to higher exposure toxicity than other metals by the toxicity unit and toxic risk index. The results of this study indicate that after the land reclamation of Caofeidian the contamination and ecorisk of heavy metals in the sediments markedly decreased in the stronger hydrodynamic areas.http://dx.doi.org/10.1155/2018/2049353
spellingShingle He Zhu
Haijian Bing
Huapeng Yi
Yanhong Wu
Zhigao Sun
Spatial Distribution and Contamination Assessment of Heavy Metals in Surface Sediments of the Caofeidian Adjacent Sea after the Land Reclamation, Bohai Bay
Journal of Chemistry
title Spatial Distribution and Contamination Assessment of Heavy Metals in Surface Sediments of the Caofeidian Adjacent Sea after the Land Reclamation, Bohai Bay
title_full Spatial Distribution and Contamination Assessment of Heavy Metals in Surface Sediments of the Caofeidian Adjacent Sea after the Land Reclamation, Bohai Bay
title_fullStr Spatial Distribution and Contamination Assessment of Heavy Metals in Surface Sediments of the Caofeidian Adjacent Sea after the Land Reclamation, Bohai Bay
title_full_unstemmed Spatial Distribution and Contamination Assessment of Heavy Metals in Surface Sediments of the Caofeidian Adjacent Sea after the Land Reclamation, Bohai Bay
title_short Spatial Distribution and Contamination Assessment of Heavy Metals in Surface Sediments of the Caofeidian Adjacent Sea after the Land Reclamation, Bohai Bay
title_sort spatial distribution and contamination assessment of heavy metals in surface sediments of the caofeidian adjacent sea after the land reclamation bohai bay
url http://dx.doi.org/10.1155/2018/2049353
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