Correlations of Free Thyroid Hormones Measured by Tandem Mass Spectrometry and Immunoassay in Dogs

Thyroid function is commonly assessed in dogs through serum measurements of free thyroxine (FT4) and thyroid-stimulating hormone (TSH). The accurate measurement of thyroid hormones is critical. In particular, the measurement of free thyroxine (FT4) is important for the diagnosis and management of th...

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Main Authors: Raffaella Sasso, Marcello Siniscalchi, Serenella d’Ingeo, Gianluca Ventriglia, Candida Bitetto, Angelo Quaranta
Format: Article
Language:English
Published: MDPI AG 2025-02-01
Series:Animals
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Online Access:https://www.mdpi.com/2076-2615/15/5/689
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author Raffaella Sasso
Marcello Siniscalchi
Serenella d’Ingeo
Gianluca Ventriglia
Candida Bitetto
Angelo Quaranta
author_facet Raffaella Sasso
Marcello Siniscalchi
Serenella d’Ingeo
Gianluca Ventriglia
Candida Bitetto
Angelo Quaranta
author_sort Raffaella Sasso
collection DOAJ
description Thyroid function is commonly assessed in dogs through serum measurements of free thyroxine (FT4) and thyroid-stimulating hormone (TSH). The accurate measurement of thyroid hormones is critical. In particular, the measurement of free thyroxine (FT4) is important for the diagnosis and management of thyroid disorders. Most laboratories measure FT4 using direct analog immunoassay methods. The reliability of the results obtained using these methods has often been questioned. Fifty-nine dogs for which the veterinarian had requested the evaluation of thyroid hormones were included in this study. FT4 and TSH were measured using chemiluminescence enzyme immunoassay (CLEIA). Furthermore, FT4 was also measured by liquid chromatography–tandem mass spectrometry (LC-MS/MS) preceded by ultrafiltration. Comparing FT4 with the two different methods, the results demonstrate that LC-MS/MS, preceded by ultrafiltration, provides more accurate and specific FT4 measurements, particularly in dogs with altered thyroid hormone values. Although CLEIA is cost-effective and widely used for screening, LC-MS/MS is recommended for the more precise assessment of thyroid function.
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spelling doaj-art-860190dea12a4bc2ae485c7b14dcdbfb2025-08-20T02:57:41ZengMDPI AGAnimals2076-26152025-02-0115568910.3390/ani15050689Correlations of Free Thyroid Hormones Measured by Tandem Mass Spectrometry and Immunoassay in DogsRaffaella Sasso0Marcello Siniscalchi1Serenella d’Ingeo2Gianluca Ventriglia3Candida Bitetto4Angelo Quaranta5Department of Veterinary Medicine, University of Bari Aldo Moro, 70121 Bari, ItalyDepartment of Veterinary Medicine, University of Bari Aldo Moro, 70121 Bari, ItalyDepartment of Veterinary Medicine, University of Bari Aldo Moro, 70121 Bari, ItalyDepartment of Veterinary Medicine, University of Bari Aldo Moro, 70121 Bari, ItalyACV Triggiano S.R.L., Triggiano, 70019 Bari, ItalyDepartment of Veterinary Medicine, University of Bari Aldo Moro, 70121 Bari, ItalyThyroid function is commonly assessed in dogs through serum measurements of free thyroxine (FT4) and thyroid-stimulating hormone (TSH). The accurate measurement of thyroid hormones is critical. In particular, the measurement of free thyroxine (FT4) is important for the diagnosis and management of thyroid disorders. Most laboratories measure FT4 using direct analog immunoassay methods. The reliability of the results obtained using these methods has often been questioned. Fifty-nine dogs for which the veterinarian had requested the evaluation of thyroid hormones were included in this study. FT4 and TSH were measured using chemiluminescence enzyme immunoassay (CLEIA). Furthermore, FT4 was also measured by liquid chromatography–tandem mass spectrometry (LC-MS/MS) preceded by ultrafiltration. Comparing FT4 with the two different methods, the results demonstrate that LC-MS/MS, preceded by ultrafiltration, provides more accurate and specific FT4 measurements, particularly in dogs with altered thyroid hormone values. Although CLEIA is cost-effective and widely used for screening, LC-MS/MS is recommended for the more precise assessment of thyroid function.https://www.mdpi.com/2076-2615/15/5/689dogphysiologyhypothyroidismfree thyroxine (FT4)thyroid-stimulating hormone (TSH)liquid chromatography–tandem mass spectrometry (LC-MS/MS)
spellingShingle Raffaella Sasso
Marcello Siniscalchi
Serenella d’Ingeo
Gianluca Ventriglia
Candida Bitetto
Angelo Quaranta
Correlations of Free Thyroid Hormones Measured by Tandem Mass Spectrometry and Immunoassay in Dogs
Animals
dog
physiology
hypothyroidism
free thyroxine (FT4)
thyroid-stimulating hormone (TSH)
liquid chromatography–tandem mass spectrometry (LC-MS/MS)
title Correlations of Free Thyroid Hormones Measured by Tandem Mass Spectrometry and Immunoassay in Dogs
title_full Correlations of Free Thyroid Hormones Measured by Tandem Mass Spectrometry and Immunoassay in Dogs
title_fullStr Correlations of Free Thyroid Hormones Measured by Tandem Mass Spectrometry and Immunoassay in Dogs
title_full_unstemmed Correlations of Free Thyroid Hormones Measured by Tandem Mass Spectrometry and Immunoassay in Dogs
title_short Correlations of Free Thyroid Hormones Measured by Tandem Mass Spectrometry and Immunoassay in Dogs
title_sort correlations of free thyroid hormones measured by tandem mass spectrometry and immunoassay in dogs
topic dog
physiology
hypothyroidism
free thyroxine (FT4)
thyroid-stimulating hormone (TSH)
liquid chromatography–tandem mass spectrometry (LC-MS/MS)
url https://www.mdpi.com/2076-2615/15/5/689
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