The Permeability Alternation of Shale Fractures due to Sc-CO2 Soaking: Implications for Sc-CO2 Fracturing and Deep CO2 Sequestration in Shale Reservoirs

The shale fracture permeability is critical in determining gas production and deep CO2 sequestration performance. Moreover, how shale fracture permeability evolves after interactions with supercritical carbon dioxide (Sc-CO2) should be understood to constrain the shale reservoir permeability and eva...

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Main Authors: Zhaohui Lu, Yunzhong Jia, Jiankun Zhou, Pei He, Menglai Li, Zhengyang Song, Xin Cai
Format: Article
Language:English
Published: Wiley 2022-01-01
Series:Advances in Materials Science and Engineering
Online Access:http://dx.doi.org/10.1155/2022/7480361
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author Zhaohui Lu
Yunzhong Jia
Jiankun Zhou
Pei He
Menglai Li
Zhengyang Song
Xin Cai
author_facet Zhaohui Lu
Yunzhong Jia
Jiankun Zhou
Pei He
Menglai Li
Zhengyang Song
Xin Cai
author_sort Zhaohui Lu
collection DOAJ
description The shale fracture permeability is critical in determining gas production and deep CO2 sequestration performance. Moreover, how shale fracture permeability evolves after interactions with supercritical carbon dioxide (Sc-CO2) should be understood to constrain the shale reservoir permeability and evaluate the long-term sealing ability of shale formations. In this research, we conducted soaking experiments with shale fractures and Sc-CO2 at various times and then measured the shale fracture permeability and hydraulic aperture evolution under different stress states. Additionally, we quantify the chemical compositions, pore characteristics, fracture surface roughness alternation through X-ray diffraction, nuclear magnetic resonance, scanning electron microscope, and optical profilometry techniques. Our results indicate that soaking with Sc-CO2 will dramatically increase the shale fracture permeability and aperture due to the calcite and dolomite dissolution. This free-face dissolution process will remove the mineral particles in the fracture surface, resulting in larger pores, peaks, and valleys in the fracture surfaces. This process may last for seven days, and after that, chemical reactions may terminate, and the rock-Sc-CO2 system turns stable. Our results explain how Sc-CO2 alters the shale fracture permeability through the chemical dissolution of specific minerals from a microscale analysis.
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institution Kabale University
issn 1687-8442
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publishDate 2022-01-01
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series Advances in Materials Science and Engineering
spelling doaj-art-85df7a7a2cca457b9a4e3d5dc8b3c7a52025-08-20T03:38:03ZengWileyAdvances in Materials Science and Engineering1687-84422022-01-01202210.1155/2022/7480361The Permeability Alternation of Shale Fractures due to Sc-CO2 Soaking: Implications for Sc-CO2 Fracturing and Deep CO2 Sequestration in Shale ReservoirsZhaohui Lu0Yunzhong Jia1Jiankun Zhou2Pei He3Menglai Li4Zhengyang Song5Xin Cai6National and Local Joint Engineering Research Center of Shale Gas Exploration and DevelopmentNational and Local Joint Engineering Research Center of Shale Gas Exploration and DevelopmentNational and Local Joint Engineering Research Center of Shale Gas Exploration and DevelopmentNational and Local Joint Engineering Research Center of Shale Gas Exploration and DevelopmentNational and Local Joint Engineering Research Center of Shale Gas Exploration and DevelopmentDepartment of Civil EngineeringSchool of Resources and Safety EngineeringThe shale fracture permeability is critical in determining gas production and deep CO2 sequestration performance. Moreover, how shale fracture permeability evolves after interactions with supercritical carbon dioxide (Sc-CO2) should be understood to constrain the shale reservoir permeability and evaluate the long-term sealing ability of shale formations. In this research, we conducted soaking experiments with shale fractures and Sc-CO2 at various times and then measured the shale fracture permeability and hydraulic aperture evolution under different stress states. Additionally, we quantify the chemical compositions, pore characteristics, fracture surface roughness alternation through X-ray diffraction, nuclear magnetic resonance, scanning electron microscope, and optical profilometry techniques. Our results indicate that soaking with Sc-CO2 will dramatically increase the shale fracture permeability and aperture due to the calcite and dolomite dissolution. This free-face dissolution process will remove the mineral particles in the fracture surface, resulting in larger pores, peaks, and valleys in the fracture surfaces. This process may last for seven days, and after that, chemical reactions may terminate, and the rock-Sc-CO2 system turns stable. Our results explain how Sc-CO2 alters the shale fracture permeability through the chemical dissolution of specific minerals from a microscale analysis.http://dx.doi.org/10.1155/2022/7480361
spellingShingle Zhaohui Lu
Yunzhong Jia
Jiankun Zhou
Pei He
Menglai Li
Zhengyang Song
Xin Cai
The Permeability Alternation of Shale Fractures due to Sc-CO2 Soaking: Implications for Sc-CO2 Fracturing and Deep CO2 Sequestration in Shale Reservoirs
Advances in Materials Science and Engineering
title The Permeability Alternation of Shale Fractures due to Sc-CO2 Soaking: Implications for Sc-CO2 Fracturing and Deep CO2 Sequestration in Shale Reservoirs
title_full The Permeability Alternation of Shale Fractures due to Sc-CO2 Soaking: Implications for Sc-CO2 Fracturing and Deep CO2 Sequestration in Shale Reservoirs
title_fullStr The Permeability Alternation of Shale Fractures due to Sc-CO2 Soaking: Implications for Sc-CO2 Fracturing and Deep CO2 Sequestration in Shale Reservoirs
title_full_unstemmed The Permeability Alternation of Shale Fractures due to Sc-CO2 Soaking: Implications for Sc-CO2 Fracturing and Deep CO2 Sequestration in Shale Reservoirs
title_short The Permeability Alternation of Shale Fractures due to Sc-CO2 Soaking: Implications for Sc-CO2 Fracturing and Deep CO2 Sequestration in Shale Reservoirs
title_sort permeability alternation of shale fractures due to sc co2 soaking implications for sc co2 fracturing and deep co2 sequestration in shale reservoirs
url http://dx.doi.org/10.1155/2022/7480361
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