Effect of Maleated Compatibilizer on the Mechanical Properties of PLA/Mustard Waste Biocomposites
Natural fiber polymer composites of biodegradable poly(lactic acid) (PLA) and mustard waste were fabricated with the addition of various amounts (0.25-2.00 wt.%) of maleic anhydride grafted PLA (PLA-g-MA), which was used as a coupling agent to improve interfacial adhesion between the components and...
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AIDIC Servizi S.r.l.
2024-12-01
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| Series: | Chemical Engineering Transactions |
| Online Access: | https://www.cetjournal.it/index.php/cet/article/view/15035 |
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| author | László Lendvai Tej Singh Sándor Kálmán Jakab |
| author_facet | László Lendvai Tej Singh Sándor Kálmán Jakab |
| author_sort | László Lendvai |
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| description | Natural fiber polymer composites of biodegradable poly(lactic acid) (PLA) and mustard waste were fabricated with the addition of various amounts (0.25-2.00 wt.%) of maleic anhydride grafted PLA (PLA-g-MA), which was used as a coupling agent to improve interfacial adhesion between the components and thereby enhance the mechanical features of the biocomposite. PLA-g-MA was synthesized in-house by reactive melt grafting using dicumyl peroxide as a free grafting initiator. Preparation of the biocomposite samples was carried out using a twin screw extruder and an injection molding machine. The effect of PLA-g-MA concentration on the samples’ mechanical traits and surface hardness was investigated. Mechanical properties were determined using uniaxial tensile tests, flexural tests, and Charpy impact tests; additionally, the surface hardness was tested with a Shore D indenter. The tensile tests revealed that even the lowest amount (0.25 wt.%) of PLA-g-MA was sufficient to effectively improve the interfacial adhesion between PLA and mustard waste, as manifested in an increased tensile strength (34 to 39 MPa). Similarly, the flexural and the Charpy impact strength also exceeded that of neat PLA/mustard waste biocomposite by 31 % and 45 %, respectively. The addition of compatibilizer in higher concentrations than 0.25 wt.% did not improve the mechanical properties further, ascribed to the excess PLA-g-MA plasticizing the composite. Based on Shore D testing, the compatibilization did not affect the surface hardness of the biocomposites significantly. |
| format | Article |
| id | doaj-art-859b309056dc492fafe82b2c1de2f5d0 |
| institution | Kabale University |
| issn | 2283-9216 |
| language | English |
| publishDate | 2024-12-01 |
| publisher | AIDIC Servizi S.r.l. |
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| series | Chemical Engineering Transactions |
| spelling | doaj-art-859b309056dc492fafe82b2c1de2f5d02024-12-25T00:40:05ZengAIDIC Servizi S.r.l.Chemical Engineering Transactions2283-92162024-12-01114Effect of Maleated Compatibilizer on the Mechanical Properties of PLA/Mustard Waste BiocompositesLászló LendvaiTej SinghSándor Kálmán JakabNatural fiber polymer composites of biodegradable poly(lactic acid) (PLA) and mustard waste were fabricated with the addition of various amounts (0.25-2.00 wt.%) of maleic anhydride grafted PLA (PLA-g-MA), which was used as a coupling agent to improve interfacial adhesion between the components and thereby enhance the mechanical features of the biocomposite. PLA-g-MA was synthesized in-house by reactive melt grafting using dicumyl peroxide as a free grafting initiator. Preparation of the biocomposite samples was carried out using a twin screw extruder and an injection molding machine. The effect of PLA-g-MA concentration on the samples’ mechanical traits and surface hardness was investigated. Mechanical properties were determined using uniaxial tensile tests, flexural tests, and Charpy impact tests; additionally, the surface hardness was tested with a Shore D indenter. The tensile tests revealed that even the lowest amount (0.25 wt.%) of PLA-g-MA was sufficient to effectively improve the interfacial adhesion between PLA and mustard waste, as manifested in an increased tensile strength (34 to 39 MPa). Similarly, the flexural and the Charpy impact strength also exceeded that of neat PLA/mustard waste biocomposite by 31 % and 45 %, respectively. The addition of compatibilizer in higher concentrations than 0.25 wt.% did not improve the mechanical properties further, ascribed to the excess PLA-g-MA plasticizing the composite. Based on Shore D testing, the compatibilization did not affect the surface hardness of the biocomposites significantly.https://www.cetjournal.it/index.php/cet/article/view/15035 |
| spellingShingle | László Lendvai Tej Singh Sándor Kálmán Jakab Effect of Maleated Compatibilizer on the Mechanical Properties of PLA/Mustard Waste Biocomposites Chemical Engineering Transactions |
| title | Effect of Maleated Compatibilizer on the Mechanical Properties of PLA/Mustard Waste Biocomposites |
| title_full | Effect of Maleated Compatibilizer on the Mechanical Properties of PLA/Mustard Waste Biocomposites |
| title_fullStr | Effect of Maleated Compatibilizer on the Mechanical Properties of PLA/Mustard Waste Biocomposites |
| title_full_unstemmed | Effect of Maleated Compatibilizer on the Mechanical Properties of PLA/Mustard Waste Biocomposites |
| title_short | Effect of Maleated Compatibilizer on the Mechanical Properties of PLA/Mustard Waste Biocomposites |
| title_sort | effect of maleated compatibilizer on the mechanical properties of pla mustard waste biocomposites |
| url | https://www.cetjournal.it/index.php/cet/article/view/15035 |
| work_keys_str_mv | AT laszlolendvai effectofmaleatedcompatibilizeronthemechanicalpropertiesofplamustardwastebiocomposites AT tejsingh effectofmaleatedcompatibilizeronthemechanicalpropertiesofplamustardwastebiocomposites AT sandorkalmanjakab effectofmaleatedcompatibilizeronthemechanicalpropertiesofplamustardwastebiocomposites |