ThermOptCobra: Thermodynamically optimal construction and analysis of metabolic networks for reliable phenotype predictions

Summary: Reliable genome-scale metabolic models (GEMs) of metabolic processes are important for understanding cellular behavior. However, the presence of thermodynamically infeasible cycles (TICs) limits their predictive ability. We present ThermOptCOBRA, a comprehensive solution consisting of four...

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Main Authors: Pavan Kumar S, Nirav Pravinbhai Bhatt
Format: Article
Language:English
Published: Elsevier 2025-08-01
Series:iScience
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Online Access:http://www.sciencedirect.com/science/article/pii/S2589004225012660
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author Pavan Kumar S
Nirav Pravinbhai Bhatt
author_facet Pavan Kumar S
Nirav Pravinbhai Bhatt
author_sort Pavan Kumar S
collection DOAJ
description Summary: Reliable genome-scale metabolic models (GEMs) of metabolic processes are important for understanding cellular behavior. However, the presence of thermodynamically infeasible cycles (TICs) limits their predictive ability. We present ThermOptCOBRA, a comprehensive solution consisting of four algorithms for optimal model construction and analysis that integrate thermodynamic constraints to address TICs. By leveraging network topology, ThermOptCOBRA efficiently identifies TICs in 7,401 published models. It determines thermodynamically feasible flux directions, thereby detecting the blocked reactions, which yields more refined models with fewer TICs. Furthermore, it constructs thermodynamically consistent context-specific models that are compact in comparison to Fastcore in 80% of cases. ThermOptCOBRA also facilitates efficient loop detection and removal from flux distributions, improving predictive accuracy across flux analysis methods. Moreover, it enhances sampling algorithms by enabling loopless sample generation. In summary, ThermOptCOBRA significantly improves TIC handling in GEMs, advancing metabolic model quality for deeper insights into cellular metabolism.
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spelling doaj-art-84d8917165574880b26830b78aaa9f6f2025-08-20T02:47:25ZengElsevieriScience2589-00422025-08-0128811300510.1016/j.isci.2025.113005ThermOptCobra: Thermodynamically optimal construction and analysis of metabolic networks for reliable phenotype predictionsPavan Kumar S0Nirav Pravinbhai Bhatt1BioSystems Engineering and Control (BiSECt) Lab, Department of Biotechnology, Bhupat and Jyoti Mehta School of Biosciences, Indian Institute of Technology Madras, Chennai, Tamil Nadu, India; The Centre for Integrative Biology and Systems Medicine (IBSE), Indian Institute of Technology Madras, Chennai, Tamil Nadu, India; Department of Data Science and AI, Wadhwani School of Data Science and AI, Indian Institute of Technology Madras, Chennai, Tamil Nadu, IndiaBioSystems Engineering and Control (BiSECt) Lab, Department of Biotechnology, Bhupat and Jyoti Mehta School of Biosciences, Indian Institute of Technology Madras, Chennai, Tamil Nadu, India; The Centre for Integrative Biology and Systems Medicine (IBSE), Indian Institute of Technology Madras, Chennai, Tamil Nadu, India; Department of Data Science and AI, Wadhwani School of Data Science and AI, Indian Institute of Technology Madras, Chennai, Tamil Nadu, India; IIT Madras Zanzibar Campus, Zanzibar, Tanzania; Corresponding authorSummary: Reliable genome-scale metabolic models (GEMs) of metabolic processes are important for understanding cellular behavior. However, the presence of thermodynamically infeasible cycles (TICs) limits their predictive ability. We present ThermOptCOBRA, a comprehensive solution consisting of four algorithms for optimal model construction and analysis that integrate thermodynamic constraints to address TICs. By leveraging network topology, ThermOptCOBRA efficiently identifies TICs in 7,401 published models. It determines thermodynamically feasible flux directions, thereby detecting the blocked reactions, which yields more refined models with fewer TICs. Furthermore, it constructs thermodynamically consistent context-specific models that are compact in comparison to Fastcore in 80% of cases. ThermOptCOBRA also facilitates efficient loop detection and removal from flux distributions, improving predictive accuracy across flux analysis methods. Moreover, it enhances sampling algorithms by enabling loopless sample generation. In summary, ThermOptCOBRA significantly improves TIC handling in GEMs, advancing metabolic model quality for deeper insights into cellular metabolism.http://www.sciencedirect.com/science/article/pii/S2589004225012660Biological sciencesApplied computing
spellingShingle Pavan Kumar S
Nirav Pravinbhai Bhatt
ThermOptCobra: Thermodynamically optimal construction and analysis of metabolic networks for reliable phenotype predictions
iScience
Biological sciences
Applied computing
title ThermOptCobra: Thermodynamically optimal construction and analysis of metabolic networks for reliable phenotype predictions
title_full ThermOptCobra: Thermodynamically optimal construction and analysis of metabolic networks for reliable phenotype predictions
title_fullStr ThermOptCobra: Thermodynamically optimal construction and analysis of metabolic networks for reliable phenotype predictions
title_full_unstemmed ThermOptCobra: Thermodynamically optimal construction and analysis of metabolic networks for reliable phenotype predictions
title_short ThermOptCobra: Thermodynamically optimal construction and analysis of metabolic networks for reliable phenotype predictions
title_sort thermoptcobra thermodynamically optimal construction and analysis of metabolic networks for reliable phenotype predictions
topic Biological sciences
Applied computing
url http://www.sciencedirect.com/science/article/pii/S2589004225012660
work_keys_str_mv AT pavankumars thermoptcobrathermodynamicallyoptimalconstructionandanalysisofmetabolicnetworksforreliablephenotypepredictions
AT niravpravinbhaibhatt thermoptcobrathermodynamicallyoptimalconstructionandanalysisofmetabolicnetworksforreliablephenotypepredictions