Development of Homogeneous Carboxylation of Phenolates via Kolbe–Schmitt Reaction

Development of Homogeneous Carboxylation of Phenolates via Kolbe–Schmitt Reaction

In this study, the homogeneous carboxylation of potassium, sodium, and lithium phenolates in DMSO solution at 100 °C by the Kolbe–Schmitt reaction was investigated. The impact of water, phenolate concentration, and cation nature on the yield of products and reaction selectivity was demonstrated. Bas...

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Bibliographic Details
Main Authors: Dmitry A. Merzliakov, Michael S. Alexeev, Maxim A. Topchiy, Dmitry G. Yakhvarov, Nikolai Yu. Kuznetsov, Anton L. Maximov, Irina P. Beletskaya
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Molecules
Subjects:
carboxylation
CO<sub>2</sub>
phenolates
Kolbe–Schmitt
4-hydroxybenzoic acid
2-hydroxybenzoic acid
Online Access:https://www.mdpi.com/1420-3049/30/2/248
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