DETERMINATION OF POLYSORBATES BY SPECTROPHOTOMETRY IN DRUGS BASED ON RECOMBINANT PROTEINS

Method of determination of polysorbate 20 and polysorbate 80 in recombinant protein drugs based on spectrophotometry has been designed. Isolation of polysorbate from solution is carried out by solid phase extraction followed by elution of polysorbate with acetonitrile. Acetonitrile solution is evapo...

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Main Authors: A. D. Askretkov, P. M. Isaykina, S. A. Cherepushkin, N. V. Orlova
Format: Article
Language:Russian
Published: LLC Center of Pharmaceutical Analytics (LLC «CPHA») 2019-01-01
Series:Разработка и регистрация лекарственных средств
Subjects:
Online Access:https://www.pharmjournal.ru/jour/article/view/469
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author A. D. Askretkov
P. M. Isaykina
S. A. Cherepushkin
N. V. Orlova
author_facet A. D. Askretkov
P. M. Isaykina
S. A. Cherepushkin
N. V. Orlova
author_sort A. D. Askretkov
collection DOAJ
description Method of determination of polysorbate 20 and polysorbate 80 in recombinant protein drugs based on spectrophotometry has been designed. Isolation of polysorbate from solution is carried out by solid phase extraction followed by elution of polysorbate with acetonitrile. Acetonitrile solution is evaporated and then polysorbate is derivatized with ferrous-thiocyanate reagent. Obtained derivative is extracted into organic phase and optical density is measured. The most optimal conditions of derivatization, extraction into organic phase and measurment was chosen. The validation was performed: specificity, linearity, accuracy, precision, robustness, limit of quantification.
format Article
id doaj-art-841b8c3eb6fc4e55bb23675a9958b18f
institution Kabale University
issn 2305-2066
2658-5049
language Russian
publishDate 2019-01-01
publisher LLC Center of Pharmaceutical Analytics (LLC «CPHA»)
record_format Article
series Разработка и регистрация лекарственных средств
spelling doaj-art-841b8c3eb6fc4e55bb23675a9958b18f2025-08-20T03:59:20ZrusLLC Center of Pharmaceutical Analytics (LLC «CPHA»)Разработка и регистрация лекарственных средств2305-20662658-50492019-01-0103124129469DETERMINATION OF POLYSORBATES BY SPECTROPHOTOMETRY IN DRUGS BASED ON RECOMBINANT PROTEINSA. D. Askretkov0P. M. Isaykina1S. A. Cherepushkin2N. V. Orlova3Moscow Technological University (MITHT)Moscow Technological University (MITHT)Scientific Center of Russian Federation «Research Institute for Genetics and Selection of Industrial Microorganisms»Scientific Center of Russian Federation «Research Institute for Genetics and Selection of Industrial Microorganisms»Method of determination of polysorbate 20 and polysorbate 80 in recombinant protein drugs based on spectrophotometry has been designed. Isolation of polysorbate from solution is carried out by solid phase extraction followed by elution of polysorbate with acetonitrile. Acetonitrile solution is evaporated and then polysorbate is derivatized with ferrous-thiocyanate reagent. Obtained derivative is extracted into organic phase and optical density is measured. The most optimal conditions of derivatization, extraction into organic phase and measurment was chosen. The validation was performed: specificity, linearity, accuracy, precision, robustness, limit of quantification.https://www.pharmjournal.ru/jour/article/view/469validationrecombinant proteinspolysorbatesolid phase extractiontweeniron thiocyanate
spellingShingle A. D. Askretkov
P. M. Isaykina
S. A. Cherepushkin
N. V. Orlova
DETERMINATION OF POLYSORBATES BY SPECTROPHOTOMETRY IN DRUGS BASED ON RECOMBINANT PROTEINS
Разработка и регистрация лекарственных средств
validation
recombinant proteins
polysorbate
solid phase extraction
tween
iron thiocyanate
title DETERMINATION OF POLYSORBATES BY SPECTROPHOTOMETRY IN DRUGS BASED ON RECOMBINANT PROTEINS
title_full DETERMINATION OF POLYSORBATES BY SPECTROPHOTOMETRY IN DRUGS BASED ON RECOMBINANT PROTEINS
title_fullStr DETERMINATION OF POLYSORBATES BY SPECTROPHOTOMETRY IN DRUGS BASED ON RECOMBINANT PROTEINS
title_full_unstemmed DETERMINATION OF POLYSORBATES BY SPECTROPHOTOMETRY IN DRUGS BASED ON RECOMBINANT PROTEINS
title_short DETERMINATION OF POLYSORBATES BY SPECTROPHOTOMETRY IN DRUGS BASED ON RECOMBINANT PROTEINS
title_sort determination of polysorbates by spectrophotometry in drugs based on recombinant proteins
topic validation
recombinant proteins
polysorbate
solid phase extraction
tween
iron thiocyanate
url https://www.pharmjournal.ru/jour/article/view/469
work_keys_str_mv AT adaskretkov determinationofpolysorbatesbyspectrophotometryindrugsbasedonrecombinantproteins
AT pmisaykina determinationofpolysorbatesbyspectrophotometryindrugsbasedonrecombinantproteins
AT sacherepushkin determinationofpolysorbatesbyspectrophotometryindrugsbasedonrecombinantproteins
AT nvorlova determinationofpolysorbatesbyspectrophotometryindrugsbasedonrecombinantproteins