Synthesis of MnO2 Microfiber with Secondary Nanostructure by Cotton Template

Hierarchical MnO2 microfibers were prepared by using cotton as the template and KMnO4 as the precursor via an ultrasonic assistance route. The results of scanning electron microscope characterization showed that the concentration of KMnO4 had a significant effect on the morphology of MnO2 microfiber...

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Main Authors: Huan-qin Wang, Ming-bo Zheng, Jin-hua Chen, Guang-bin Ji, Jie-ming Cao
Format: Article
Language:English
Published: Wiley 2010-01-01
Series:Journal of Nanotechnology
Online Access:http://dx.doi.org/10.1155/2010/479172
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author Huan-qin Wang
Ming-bo Zheng
Jin-hua Chen
Guang-bin Ji
Jie-ming Cao
author_facet Huan-qin Wang
Ming-bo Zheng
Jin-hua Chen
Guang-bin Ji
Jie-ming Cao
author_sort Huan-qin Wang
collection DOAJ
description Hierarchical MnO2 microfibers were prepared by using cotton as the template and KMnO4 as the precursor via an ultrasonic assistance route. The results of scanning electron microscope characterization showed that the concentration of KMnO4 had a significant effect on the morphology of MnO2 microfiber. At low concentration of KMnO4, the microfiber was composed of MnO2 nanorods with single crystal structure. With increasing the concentration of KMnO4, the secondary nanostructure of MnO2 microfibers had a transformation from nanorod to nanoparticle. The results of N2 adsorption-desorption analysis indicated that MnO2 microfibers had BET surface area of about 25 m2/g. This synthesis provides a new way to control the secondary nanostructure of MnO2 microfiber by adjusting the concentration of precursor. Furthermore, the mechanism for the replication was proposed and discussed.
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institution Kabale University
issn 1687-9503
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language English
publishDate 2010-01-01
publisher Wiley
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series Journal of Nanotechnology
spelling doaj-art-83d8e056d8ef4247bb0a87c340200e942025-02-03T05:46:53ZengWileyJournal of Nanotechnology1687-95031687-95112010-01-01201010.1155/2010/479172479172Synthesis of MnO2 Microfiber with Secondary Nanostructure by Cotton TemplateHuan-qin Wang0Ming-bo Zheng1Jin-hua Chen2Guang-bin Ji3Jie-ming Cao4Nanomaterials Research Institute, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, ChinaNanomaterials Research Institute, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, ChinaNanomaterials Research Institute, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, ChinaNanomaterials Research Institute, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, ChinaNanomaterials Research Institute, College of Materials Science and Technology, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, ChinaHierarchical MnO2 microfibers were prepared by using cotton as the template and KMnO4 as the precursor via an ultrasonic assistance route. The results of scanning electron microscope characterization showed that the concentration of KMnO4 had a significant effect on the morphology of MnO2 microfiber. At low concentration of KMnO4, the microfiber was composed of MnO2 nanorods with single crystal structure. With increasing the concentration of KMnO4, the secondary nanostructure of MnO2 microfibers had a transformation from nanorod to nanoparticle. The results of N2 adsorption-desorption analysis indicated that MnO2 microfibers had BET surface area of about 25 m2/g. This synthesis provides a new way to control the secondary nanostructure of MnO2 microfiber by adjusting the concentration of precursor. Furthermore, the mechanism for the replication was proposed and discussed.http://dx.doi.org/10.1155/2010/479172
spellingShingle Huan-qin Wang
Ming-bo Zheng
Jin-hua Chen
Guang-bin Ji
Jie-ming Cao
Synthesis of MnO2 Microfiber with Secondary Nanostructure by Cotton Template
Journal of Nanotechnology
title Synthesis of MnO2 Microfiber with Secondary Nanostructure by Cotton Template
title_full Synthesis of MnO2 Microfiber with Secondary Nanostructure by Cotton Template
title_fullStr Synthesis of MnO2 Microfiber with Secondary Nanostructure by Cotton Template
title_full_unstemmed Synthesis of MnO2 Microfiber with Secondary Nanostructure by Cotton Template
title_short Synthesis of MnO2 Microfiber with Secondary Nanostructure by Cotton Template
title_sort synthesis of mno2 microfiber with secondary nanostructure by cotton template
url http://dx.doi.org/10.1155/2010/479172
work_keys_str_mv AT huanqinwang synthesisofmno2microfiberwithsecondarynanostructurebycottontemplate
AT mingbozheng synthesisofmno2microfiberwithsecondarynanostructurebycottontemplate
AT jinhuachen synthesisofmno2microfiberwithsecondarynanostructurebycottontemplate
AT guangbinji synthesisofmno2microfiberwithsecondarynanostructurebycottontemplate
AT jiemingcao synthesisofmno2microfiberwithsecondarynanostructurebycottontemplate