Sixty Years of Kossel Isoelectronic Series—Arguments Derived from Photo-electron and Atomic Spectra
In spite of chemical shifts (in photo-electron spectra) and interatomic relaxation by condensation of gaseous samples, the difference ΔI between the ionization energies of the monatomic entities and the compounds in the oxidation state z tends to be proportional to z. The new parameter (ΔI/z) seems...
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| Format: | Article |
| Language: | deu |
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Swiss Chemical Society
1976-11-01
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| Series: | CHIMIA |
| Online Access: | https://www.chimia.ch/chimia/article/view/9327 |
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| _version_ | 1850140218340933632 |
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| author | Christian K. Jørgensen |
| author_facet | Christian K. Jørgensen |
| author_sort | Christian K. Jørgensen |
| collection | DOAJ |
| description |
In spite of chemical shifts (in photo-electron spectra) and interatomic relaxation by condensation of gaseous samples, the difference ΔI between the ionization energies of the monatomic entities and the compounds in the oxidation state z tends to be proportional to z. The new parameter (ΔI/z) seems to indicate a superposition of electrostatic interatomic effects and the screening of the inner shell by external electrons. It is suggested to call the number of electrons in a Kossel isoelectronic series K.
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| format | Article |
| id | doaj-art-83d65e30dbe44a0ab607f0dac5390a4c |
| institution | OA Journals |
| issn | 0009-4293 2673-2424 |
| language | deu |
| publishDate | 1976-11-01 |
| publisher | Swiss Chemical Society |
| record_format | Article |
| series | CHIMIA |
| spelling | doaj-art-83d65e30dbe44a0ab607f0dac5390a4c2025-08-20T02:29:54ZdeuSwiss Chemical SocietyCHIMIA0009-42932673-24241976-11-01301110.2533/chimia.1976.490Sixty Years of Kossel Isoelectronic Series—Arguments Derived from Photo-electron and Atomic SpectraChristian K. Jørgensen0Département de Chimie minérale, analytique et appliquée, Université de Genève In spite of chemical shifts (in photo-electron spectra) and interatomic relaxation by condensation of gaseous samples, the difference ΔI between the ionization energies of the monatomic entities and the compounds in the oxidation state z tends to be proportional to z. The new parameter (ΔI/z) seems to indicate a superposition of electrostatic interatomic effects and the screening of the inner shell by external electrons. It is suggested to call the number of electrons in a Kossel isoelectronic series K. https://www.chimia.ch/chimia/article/view/9327 |
| spellingShingle | Christian K. Jørgensen Sixty Years of Kossel Isoelectronic Series—Arguments Derived from Photo-electron and Atomic Spectra CHIMIA |
| title | Sixty Years of Kossel Isoelectronic Series—Arguments Derived from Photo-electron and Atomic Spectra |
| title_full | Sixty Years of Kossel Isoelectronic Series—Arguments Derived from Photo-electron and Atomic Spectra |
| title_fullStr | Sixty Years of Kossel Isoelectronic Series—Arguments Derived from Photo-electron and Atomic Spectra |
| title_full_unstemmed | Sixty Years of Kossel Isoelectronic Series—Arguments Derived from Photo-electron and Atomic Spectra |
| title_short | Sixty Years of Kossel Isoelectronic Series—Arguments Derived from Photo-electron and Atomic Spectra |
| title_sort | sixty years of kossel isoelectronic series arguments derived from photo electron and atomic spectra |
| url | https://www.chimia.ch/chimia/article/view/9327 |
| work_keys_str_mv | AT christiankjørgensen sixtyyearsofkosselisoelectronicseriesargumentsderivedfromphotoelectronandatomicspectra |