Macerals of Shengli Lignite in Inner Mongolia of China and Their Combustion Reactivity
The macerals, including fusinitic coal containing 72.20% inertinite and xyloid coal containing 91.43% huminite, were separated from Shengli lignite using an optical microscope, and their combustion reactivity was examined by thermogravimetric analysis. Several combustion parameters, including igniti...
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2016-01-01
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Series: | Journal of Chemistry |
Online Access: | http://dx.doi.org/10.1155/2016/2513275 |
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author | Ying Yue Teng Yu Zhe Liu Quan Sheng Liu Chang Qing Li |
author_facet | Ying Yue Teng Yu Zhe Liu Quan Sheng Liu Chang Qing Li |
author_sort | Ying Yue Teng |
collection | DOAJ |
description | The macerals, including fusinitic coal containing 72.20% inertinite and xyloid coal containing 91.43% huminite, were separated from Shengli lignite using an optical microscope, and their combustion reactivity was examined by thermogravimetric analysis. Several combustion parameters, including ignition and burnout indices, were analyzed, and the combustion kinetics of the samples were calculated by regression. Fusinitic coal presented a porous structure, while xyloid coal presented a compact structure. The specific surface area of fusinitic coal was 2.5 times larger than that of xyloid coal, and the light-off temperature of the former was higher than that of the latter. However, the overall combustion reactivity of fusinitic coal was better than that of xyloid coal. The combustion processes of fusinitic and xyloid coals can be accurately described by both the homogeneous model and the shrinking core model. The features of xyloid coal agree with the shrinking core model when its conversion rate is 10%–90%. The activation energy of fusinitic coal during combustion can be divided into three phases, with the middle phase featuring the highest energy. The activation energy of xyloid coal is lower than that of fusinitic coal in the light-off phase, which may explain the low light-off temperature of this coal. |
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institution | Kabale University |
issn | 2090-9063 2090-9071 |
language | English |
publishDate | 2016-01-01 |
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series | Journal of Chemistry |
spelling | doaj-art-83cef3dc668442bcb1d86274625e319d2025-02-03T05:51:32ZengWileyJournal of Chemistry2090-90632090-90712016-01-01201610.1155/2016/25132752513275Macerals of Shengli Lignite in Inner Mongolia of China and Their Combustion ReactivityYing Yue Teng0Yu Zhe Liu1Quan Sheng Liu2Chang Qing Li3College of Chemical Engineering, Inner Mongolia University of Technology, Inner Mongolia Key Laboratory of Industrial Catalysis, Huhhot, Inner Mongolia 010051, ChinaCollege of Chemical Engineering, Inner Mongolia University of Technology, Inner Mongolia Key Laboratory of Industrial Catalysis, Huhhot, Inner Mongolia 010051, ChinaCollege of Chemical Engineering, Inner Mongolia University of Technology, Inner Mongolia Key Laboratory of Industrial Catalysis, Huhhot, Inner Mongolia 010051, ChinaManagement College, Inner Mongolia University of Technology, Huhhot, Inner Mongolia 010051, ChinaThe macerals, including fusinitic coal containing 72.20% inertinite and xyloid coal containing 91.43% huminite, were separated from Shengli lignite using an optical microscope, and their combustion reactivity was examined by thermogravimetric analysis. Several combustion parameters, including ignition and burnout indices, were analyzed, and the combustion kinetics of the samples were calculated by regression. Fusinitic coal presented a porous structure, while xyloid coal presented a compact structure. The specific surface area of fusinitic coal was 2.5 times larger than that of xyloid coal, and the light-off temperature of the former was higher than that of the latter. However, the overall combustion reactivity of fusinitic coal was better than that of xyloid coal. The combustion processes of fusinitic and xyloid coals can be accurately described by both the homogeneous model and the shrinking core model. The features of xyloid coal agree with the shrinking core model when its conversion rate is 10%–90%. The activation energy of fusinitic coal during combustion can be divided into three phases, with the middle phase featuring the highest energy. The activation energy of xyloid coal is lower than that of fusinitic coal in the light-off phase, which may explain the low light-off temperature of this coal.http://dx.doi.org/10.1155/2016/2513275 |
spellingShingle | Ying Yue Teng Yu Zhe Liu Quan Sheng Liu Chang Qing Li Macerals of Shengli Lignite in Inner Mongolia of China and Their Combustion Reactivity Journal of Chemistry |
title | Macerals of Shengli Lignite in Inner Mongolia of China and Their Combustion Reactivity |
title_full | Macerals of Shengli Lignite in Inner Mongolia of China and Their Combustion Reactivity |
title_fullStr | Macerals of Shengli Lignite in Inner Mongolia of China and Their Combustion Reactivity |
title_full_unstemmed | Macerals of Shengli Lignite in Inner Mongolia of China and Their Combustion Reactivity |
title_short | Macerals of Shengli Lignite in Inner Mongolia of China and Their Combustion Reactivity |
title_sort | macerals of shengli lignite in inner mongolia of china and their combustion reactivity |
url | http://dx.doi.org/10.1155/2016/2513275 |
work_keys_str_mv | AT yingyueteng maceralsofshengliligniteininnermongoliaofchinaandtheircombustionreactivity AT yuzheliu maceralsofshengliligniteininnermongoliaofchinaandtheircombustionreactivity AT quanshengliu maceralsofshengliligniteininnermongoliaofchinaandtheircombustionreactivity AT changqingli maceralsofshengliligniteininnermongoliaofchinaandtheircombustionreactivity |