Synthesis of Blue-Green Phosphors Sr4Si3O8Cl4:Eu2+ by Gel-Combustion Method and Their Luminescent Properties

Sr4Si3O8Cl4:Eu2+ blue-green phosphors were synthesized by the gel-combustion method. The as-synthesized phosphors were analyzed and characterized by X-ray diffraction and fluorescence spectrophotometer. The results indicate that orthorhombic phase Sr4Si3O8Cl4:Eu2+ has been formed after the precursor...

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Main Authors: Yong-Qing Zhai, Li-Li Wang, Juan Chen, Shi-Hua Feng
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/683404
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author Yong-Qing Zhai
Li-Li Wang
Juan Chen
Shi-Hua Feng
author_facet Yong-Qing Zhai
Li-Li Wang
Juan Chen
Shi-Hua Feng
author_sort Yong-Qing Zhai
collection DOAJ
description Sr4Si3O8Cl4:Eu2+ blue-green phosphors were synthesized by the gel-combustion method. The as-synthesized phosphors were analyzed and characterized by X-ray diffraction and fluorescence spectrophotometer. The results indicate that orthorhombic phase Sr4Si3O8Cl4:Eu2+ has been formed after the precursor calcined at 900°C reductive temperature. The excitation spectrum of Sr4Si3O8Cl4:Eu2+ is a broad band in the range of 250 ~ 450 nm and the main peak at 324 nm. The emission spectrum is also a broad band with the main emission peak at about 484 nm, which is ascribed to the typical 4f5d1 to 4f7 transition of Eu2+. Moreover, the effects of the concentration of Eu2+, the reductive temperature, and the doping amount of Mg2+ on luminescent properties were discussed.
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institution Kabale University
issn 2090-9063
2090-9071
language English
publishDate 2013-01-01
publisher Wiley
record_format Article
series Journal of Chemistry
spelling doaj-art-83b1a0b4c2cb43d5b3ca0764628233ad2025-08-20T03:37:37ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/683404683404Synthesis of Blue-Green Phosphors Sr4Si3O8Cl4:Eu2+ by Gel-Combustion Method and Their Luminescent PropertiesYong-Qing Zhai0Li-Li Wang1Juan Chen2Shi-Hua Feng3College of Chemistry and Environmental Science, Hebei University, Baoding, 071002, ChinaCollege of Chemistry and Environmental Science, Hebei University, Baoding, 071002, ChinaCollege of Chemistry and Environmental Science, Hebei University, Baoding, 071002, ChinaCollege of Chemistry and Environmental Science, Hebei University, Baoding, 071002, ChinaSr4Si3O8Cl4:Eu2+ blue-green phosphors were synthesized by the gel-combustion method. The as-synthesized phosphors were analyzed and characterized by X-ray diffraction and fluorescence spectrophotometer. The results indicate that orthorhombic phase Sr4Si3O8Cl4:Eu2+ has been formed after the precursor calcined at 900°C reductive temperature. The excitation spectrum of Sr4Si3O8Cl4:Eu2+ is a broad band in the range of 250 ~ 450 nm and the main peak at 324 nm. The emission spectrum is also a broad band with the main emission peak at about 484 nm, which is ascribed to the typical 4f5d1 to 4f7 transition of Eu2+. Moreover, the effects of the concentration of Eu2+, the reductive temperature, and the doping amount of Mg2+ on luminescent properties were discussed.http://dx.doi.org/10.1155/2013/683404
spellingShingle Yong-Qing Zhai
Li-Li Wang
Juan Chen
Shi-Hua Feng
Synthesis of Blue-Green Phosphors Sr4Si3O8Cl4:Eu2+ by Gel-Combustion Method and Their Luminescent Properties
Journal of Chemistry
title Synthesis of Blue-Green Phosphors Sr4Si3O8Cl4:Eu2+ by Gel-Combustion Method and Their Luminescent Properties
title_full Synthesis of Blue-Green Phosphors Sr4Si3O8Cl4:Eu2+ by Gel-Combustion Method and Their Luminescent Properties
title_fullStr Synthesis of Blue-Green Phosphors Sr4Si3O8Cl4:Eu2+ by Gel-Combustion Method and Their Luminescent Properties
title_full_unstemmed Synthesis of Blue-Green Phosphors Sr4Si3O8Cl4:Eu2+ by Gel-Combustion Method and Their Luminescent Properties
title_short Synthesis of Blue-Green Phosphors Sr4Si3O8Cl4:Eu2+ by Gel-Combustion Method and Their Luminescent Properties
title_sort synthesis of blue green phosphors sr4si3o8cl4 eu2 by gel combustion method and their luminescent properties
url http://dx.doi.org/10.1155/2013/683404
work_keys_str_mv AT yongqingzhai synthesisofbluegreenphosphorssr4si3o8cl4eu2bygelcombustionmethodandtheirluminescentproperties
AT liliwang synthesisofbluegreenphosphorssr4si3o8cl4eu2bygelcombustionmethodandtheirluminescentproperties
AT juanchen synthesisofbluegreenphosphorssr4si3o8cl4eu2bygelcombustionmethodandtheirluminescentproperties
AT shihuafeng synthesisofbluegreenphosphorssr4si3o8cl4eu2bygelcombustionmethodandtheirluminescentproperties