Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarp

ABSTRACT The objectives of this study were to fit mathematical models to the experimental data of the drying of the pequi mesocarp, determine the effective diffusion coefficient, and to obtain activation energy and thermodynamic and nutritional properties in different drying conditions. The mesocarp...

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Main Authors: Jéssica L. F. Souza, Daniel E. C. Oliveira, Geovana R. Plácido, Mariana B. Egea, Márcio Caliari, Marco A. P. da Silva
Format: Article
Language:English
Published: Universidade Federal de Campina Grande
Series:Revista Brasileira de Engenharia Agrícola e Ambiental
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Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1415-43662019000900655&lng=en&tlng=en
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author Jéssica L. F. Souza
Daniel E. C. Oliveira
Geovana R. Plácido
Mariana B. Egea
Márcio Caliari
Marco A. P. da Silva
author_facet Jéssica L. F. Souza
Daniel E. C. Oliveira
Geovana R. Plácido
Mariana B. Egea
Márcio Caliari
Marco A. P. da Silva
author_sort Jéssica L. F. Souza
collection DOAJ
description ABSTRACT The objectives of this study were to fit mathematical models to the experimental data of the drying of the pequi mesocarp, determine the effective diffusion coefficient, and to obtain activation energy and thermodynamic and nutritional properties in different drying conditions. The mesocarp of pequi fruits, with an initial moisture content of 5.05 (decimal, dry basis), was dried in a forced ventilation oven at temperatures of 40, 50, 60 and 70 °C until the final moisture content of 0.15 ± 0.01 (decimal, dry basis). The mathematical models were adjusted by non-linear regression analysis using the Gauss-Newton method, considering the magnitude of the coefficient of determination (R2), the mean relative error (P) and the estimated mean error (SE). Among the models analyzed, the Midilli model presented the best fit. The effective diffusion coefficient increased with increase in temperature, and the activation energy on drying was 11.011 kJ mol-1. The enthalpy decreased with an increase in the drying temperature, while the entropy and Gibbs free energy increased with the drying temperature. The product obtained from drying has low lipid and high carbohydrate concentration, while temperatures above 70 °C could cause denaturation and/or protein complexation. The temperature of 60 °C is most suitable to obtain flour of pequi mesocarp, due to the shorter processing time while maintaining the nutritional quality.
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spelling doaj-art-839e70af96174fe5aef26bcdfca7d4462025-08-20T03:07:13ZengUniversidade Federal de Campina GrandeRevista Brasileira de Engenharia Agrícola e Ambiental1807-192923965566110.1590/1807-1929/agriambi.v23n9p655-661S1415-43662019000900655Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarpJéssica L. F. SouzaDaniel E. C. OliveiraGeovana R. PlácidoMariana B. EgeaMárcio CaliariMarco A. P. da SilvaABSTRACT The objectives of this study were to fit mathematical models to the experimental data of the drying of the pequi mesocarp, determine the effective diffusion coefficient, and to obtain activation energy and thermodynamic and nutritional properties in different drying conditions. The mesocarp of pequi fruits, with an initial moisture content of 5.05 (decimal, dry basis), was dried in a forced ventilation oven at temperatures of 40, 50, 60 and 70 °C until the final moisture content of 0.15 ± 0.01 (decimal, dry basis). The mathematical models were adjusted by non-linear regression analysis using the Gauss-Newton method, considering the magnitude of the coefficient of determination (R2), the mean relative error (P) and the estimated mean error (SE). Among the models analyzed, the Midilli model presented the best fit. The effective diffusion coefficient increased with increase in temperature, and the activation energy on drying was 11.011 kJ mol-1. The enthalpy decreased with an increase in the drying temperature, while the entropy and Gibbs free energy increased with the drying temperature. The product obtained from drying has low lipid and high carbohydrate concentration, while temperatures above 70 °C could cause denaturation and/or protein complexation. The temperature of 60 °C is most suitable to obtain flour of pequi mesocarp, due to the shorter processing time while maintaining the nutritional quality.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1415-43662019000900655&lng=en&tlng=enmodelagem matemáticaenergia de ativaçãomodelo de Midilliaproveitamento de subproduto
spellingShingle Jéssica L. F. Souza
Daniel E. C. Oliveira
Geovana R. Plácido
Mariana B. Egea
Márcio Caliari
Marco A. P. da Silva
Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarp
Revista Brasileira de Engenharia Agrícola e Ambiental
modelagem matemática
energia de ativação
modelo de Midilli
aproveitamento de subproduto
title Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarp
title_full Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarp
title_fullStr Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarp
title_full_unstemmed Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarp
title_short Thermodynamic and nutritional properties and drying kinetics of pequi (Caryocar brasiliense Cambess) mesocarp
title_sort thermodynamic and nutritional properties and drying kinetics of pequi caryocar brasiliense cambess mesocarp
topic modelagem matemática
energia de ativação
modelo de Midilli
aproveitamento de subproduto
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1415-43662019000900655&lng=en&tlng=en
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